Surface‐initiated atom transfer radical polymerization from Mg(OH)2 nanoparticles to prepare the well‐defined polymer‐Mg(OH)2 nanocomposites

Well‐defined polymer‐Mg(OH)₂ nanocomposites were prepared by atom transfer radical polymerization (ATRP). The ATRP initiators were covalently attached to the Mg(OH)₂ by esterification of 2‐chloropropionyl chloride with hydroxyl group. The amount of polymer grafted from Mg(OH)₂ can be controlled using a different catalyst system and adding a small amount of polar solvent. The well‐defined diblock copolymer, consisting of poly(styrene) (PS) and poly(methyl methacrylate) (PMMA) were synthesized. The products were characterized by nuclear magnetic resonance, Fourier transform infrared, differential scanning calorimetry, and thermal gravimetric analysis. The morphologies of PS/PMMA and PS/PMMA/Mg(OH)₂‐g‐PS‐b‐PMMA blends are compared by using a scanning electron microscope. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3680–3687, 2007     

宽带功率放大器PGSC建模方法及预失真研究

针对宽带功率放大器的强记忆效应特性,提出一种功放建模和数字预失真方法——PGSC模型。利用广义记忆多项式(GMP)、特定交叉项(SCT)及记忆时刻信号交叉项(CIMT)3个基函数来构造功放行为模型及数字预失真器,并搭建实际测试平台对模型的精度及线性化效果进行验证。测试结果表明,与PMEC方法相比,PGSC方法建模时的归一化均方误差减少了2.1 dB,数字预失真时输出信号的三阶邻信道功率比降低了4.94/2.03 dB;与GMP方法相比,PGSC方法仅利用73%的系数即可得到更高的模型精度和更好的线性化效果。     

原材料价格波动下钢铁生产库存多期优化模型

考虑钢铁企业钢材生产受钢材需求和生产变动成本波动的双重影响,在预测基础上,建立钢材生产库存多期动态优化模型。由于模型涉及多种钢材及多个时段,属于大规模问题,求解困难,且为了避免粒子群算法陷入局部最优,提出采用模拟退火与粒子群组合智能算法对模型进行求解。最后通过钢铁企业L的案例,结果表明算法具有较强的收敛性和适用性,模型可用于解决钢铁企业多期生产实际问题。     

一种林业手持式多功能测树仪设计

针对森林调查对便携式测量设备自动化和集成化的需求,设计了一种集测高器、角规和标准蓄积量计算功能于一体,具有测量、数据存储、计算等多种功能的手持式多功能电子测树仪GForest。该仪器通过采样控制算法实现对测高器防抖动设计,采用计数器存储并控制角规计数结果,提供USB接口同PC和移动智能终端设备进行数据共享,旨在解决目前森林地面调查数据采集硬件设备信息化与数据采集软件发展不同步的问题,大幅减少了外业调查中手工数据记录和录入的工作,提高了野外数据采集的效率。经实测验证:GForest测得的立木高度与实际值的平均误差为4%,与进口同类设备精度持平,同时还具有角规绕测计数与控制等实用功能,且具有明显的成本优势,适合在行业内推广应用。     

新型单组分聚氨酯防水涂料的研制

由异氰酸酯、聚醚多元醇和各种助剂制成不含焦油、不含溶剂的单组分湿固化聚氨酯(PU)防水涂料。讨论了聚醚配比、体系中水份及酸碱度等影响因素。该涂料具有性能优良、使用方便、对环境无污染等优点。经济效益和社会效益显著 ,具有广阔的发展前景     

Charge reduction and regeneration in K+, Na+, Mg2+, Ni2+ and Co2+-exchanged Wyoming Bentonite

Controlled calcination of ion-exchanged Wyoming Bentonite in the presence and absence of ammonia leads to layer charge reductions. Detailed chemical analyses of both unexchangeable and exchangeable species lead to the conclusion that in no case is there migration of the original interlamellar cations into the octahedral region of the layers although, in terms of ionic radius alone, Mg²⁺, Ni²⁺ and, possibly Co²⁺, might be expected to do so. The production of unexchangeable Mg, Ni or Co, is identified as resulting from high temperature hydrolysis leading to hydroxide or oxide formation.     

Prelaunch calibration and primary results from in-orbit calibration of the atmospheric correction microwave radiometer (ACMR) on the HY-2A satellite of China

The atmospheric correction microwave radiometer (ACMR) is one of the main payloads for correcting atmospheric path delay in the radar altimeter on the Haiyang-2A (HY-2A) satellite. The ACMR is a three-band microwave radiometer operating at 18.7, 23.8, and 37.0 GHz. Calibration of the ACMR is important for applying its measurements to correct for atmospheric effects on the HY-2A altimeter signal transmission in the air. Therefore, a detailed introduction to the principles and specifications of the ACMR system is given first. The thermal vacuum calibration method of the ACMR is discussed and analysed, and the microwave transfer functions and related coefficients are given, especially the nonlinear coefficients derived from a test for correcting nonlinear responses between the input of antenna temperature and the output of voltage at each channel of the ACMR. Furthermore, antenna pattern correction algorithms for removing the effects of side lobe and cross-polarization are derived and their coefficients are used for in-orbit data processing. Primary calibration results are given by comparing with the similar spaceborne Jason microwave radiometer (JMR) on the Jason-1 satellite and with the advanced microwave radiometer (AMR) on Jason-2. The results of this comparison show that the data from the ACMR match well to those from the JMR and AMR.     

A study on carbon coating to silicon and electrochemical characteristics of Si-C/Li cells

The aim of this paper is to study the electrochemical behavior of Si-C material synthesized by heating a mixture of silicon and polyvinylidene fluoride (PVDF) in the ratios of 5, 20, and 50 wt%. The particle size of the synthesized material was found to be increased with increase in the PVDF ratio. The coexistence of silicon with carbon was confirmed from the XRD analysis. A field emission scanning electron microscope (FESEM) study performed with the material proved the improvement in coating efficiency with increase in the PVDF ratio. Coin cells of the type 2025 were made by using the synthesized material, and the electrochemical properties were studied. An electrode was prepared by using the developed Si-C material. Si-C|Li cells were made with this electrode. A charge|discharge test was performed for 20 cycles at 0.1 C hour rate. Initial charge and discharge capacities of Si-C material derived from 20 wt% of PVDF was found to be 1,830 and 526 mAh|g, respectively. Initial charge/discharge characteristics of the electrode were analyzed. The level of reversible specific capacity was about 216mAh/g at Si-C material derived from 20 wt% of PVDF, initial intercalation efficiency (IIE), intercalation efficiency at initial charge/discharge, was 68%. Surface irreversible specific capacity was 31 mAh/g, and average specific resistance was 2.6 ohm * g.     

潮汐双向流条件下丁坝水流特性研究

以长江口南支河段为原型,概化并建立水槽数学模型,研究径潮双向流条件下丁坝附近的水流结构。研究表明:丁坝一侧河岸,丁坝下游潮差远大于上游,在丁坝上游潮差小于对岸侧,下游潮差大于对岸侧;落潮时,丁坝回流区与壅水区长度大于涨潮,转流时刻,丁坝坝头附近流速相对较大;河床底部剪切应力变化在涨落急时刻最大,且落潮大于涨潮,转流时刻坝头及坝身迎水侧剪切应力增加明显。     

环氧大豆油的生产技术及其在PVC中的应用

介绍了聚氯乙烯增塑荆环氧大豆油的性质和生产原理，提出了国内环氧大豆油工业生产存在的问题；结合国外先进的环氧化技术提出了相应的改进方法，并介绍了所用的催化剂、工艺条件及稳定荆。同时阐述了环氧大豆油的卫生性及加工性。