Efficiency Breakthrough of Fluorescence OLEDs by the Strategic Management of “Hot Excitons” at Highly Lying Excitation Triplet Energy Levels

Aggregation-induced emission (AIE) and hybridized local and charge-transfer (HLCT) materials are two kinds of promising electroluminescence systems for the fabrication of high-efficiency organic light-emitting diodes (OLEDs) by harnessing “hot excitons” at the high-lying triplet exciton states (T_n, n ≥ 2). Nonetheless, the efficiency of the resulting OLEDs did not meet expectations due to the possible loss of T_n→T_n−1. Herein, experimental results and theoretical calculations demonstrate the “hot exciton” process between the high-lying triplet state T₃ and the lowest excited singlet state S₁ in an AIE material 4⁗-(diphenylamino)-2″,5″-diphenyl-[1,1″:4′,1″:4″,1′″:4′″,1⁗-quinquephenyl]-4-carbonitrile (TPB-PAPC) and it is found that the Förster resonance energy transfer (FRET) between two molecules can facilitate the “hot exciton” process and inhibit the T₃→T₂ loss by doping a blue fluorescent emitter in TPB-PAPC. Finally, the doped TPB-PAPC blue OLEDs achieve a maximum external quantum efficiency (EQE_max) of 9.0% with a small efficiency roll-off. Furthermore, doping the blue fluorescent emitter in a HLCT material 2-(4-(10-(3-(9H-carbazol-9-yl)phenyl)anthracen-9-yl)phenyl)-1-phenyl-1H-phenanthro[9,10-d] imidazole (PAC) is used as the emission layer, and the resulting blue OLEDs exhibit an EQE_max of 17.4%, realizing the efficiency breakthrough of blue fluorescence OLEDs. This work establishes a physical insight in the design of high-performance “hot exciton” molecules and the fabrication of high-performance blue fluorescence OLEDs.     

利用激光图像技术检测路基压实度

为了检测路基压实度,设计了路基压实度激光图像检测装置,并对该检测方法进行了研究。从特征图像中分别提取平均灰度级、标准方差、平滑度、三阶矩、一致性、熵、能量、对比度、相关性和均匀性等10个基于灰度共生矩和基于直方图的纹理特征参量,以及含水量参数;通过PCA(主成分分析)降维处理,从原始数据中优选出4个主成分因子参量;最后,利用BP神经网络预测密实度。实验结果表明:(1)BP神经网络经过11次学习后达到了要求的误差;(2)利用系统预测的密实度数值与环刀法检测值相比较,平均绝对和相对误差在2.1%左右。因此,该检测方法检测路基压实度是可行的。     

电力电缆变频谐振耐压试验分析

随着交联聚乙烯（XLPE）电力电缆在城市电网中的大量应用,直流耐压试验方法已经不再适用于XLPE电缆。但工频交流耐压试验设备笨重,不适合现场应用,近年来理论和实践都证明变频谐振试验是替代工频试验的最佳选择。本文从理论和应用方面探讨了变频谐振试验方法。     

弹道中段群目标平动补偿与分离方法

弹道微动群目标时频图是多目标多散射点微多普勒的叠加,以往针对单目标的补偿与分离方法不再适用。针对这一问题,该文首先分析了群目标及诱饵的微多普勒形式;利用弹道中段目标运动平稳,短时观测加速度近似为常数的特性,采用Radon变换检测微多普勒曲线的倾斜程度,用最小熵准则和高斯函数拟合的方法估计平动参数,进而完成平动补偿;对补偿后的群目标时频图利用Viterbi算法提取各条微多普勒曲线,依据同一目标各散射点微多普勒的周期相关性,完成群目标分离;最后仿真验证了以上方法的有效性。     

LIGA技术制作Fresnel波带片的研究

简要介绍了利用ＬＩＧＡ技术中同步辐射光刻、微电铸技术制作α粒子编码成像波带片的研究,讨论了编码波带片的结构和影响波带片的平面和层析分辨率的参数。根据实验要求设计和研制了一种α粒子编码成像波带片。     

横流CO2激光器的折叠式谐振腔研究

在横流ＣＯ２激光器中折叠式谐振腔,不仅能改善光束质量,而且有提高转换效率。文章地折叠式谐振腔的折数确定,转折镜的选择,谐振腔的总体结构进行了分析研究,并设计了一种七折光学折叠腔,在大功率横流激光器上取得了良好的实验效果,获得了千瓦级基模激光输出。     

Effects of annealing on the electric noise in semiconductor lasers

Thirty high-power quantum well semiconductor lasers of 808 nm wavelengths are aged at 18 ± 2 °C and 0.5 A. By measuring the variety of device noise before and after aging, it is found that the noise decreases after aging for 100 and 1000 h; moreover, the noise decreasing range of the failed device after aging is obviously higher than that of the good device. In addition, the noise characteristics of the failure device have some change, and the g–r noise occurs after aging. The investigation shows that it is due to the different behavior of the different kinds of defects during annealing.     

双材料 V 形切口应力强度因子计算及其在重力坝中的应用

本文用复势理论导出双材料Ｖ形切口的特征方程及切口顶端附近的应力和位移场，首次利用数值分析方法计算出了混凝土坝坝踵区的应力强度因子．典型算例表明，本文计算结果具有较高的计算精度．