Mechanochemical reactions between structural defects in magnetic fields

An influence of steady, pulse and microwave magnetic fields on mechanochemical reactions between structural defects in doped ionic crystals has been studied. The effects of dislocation depinning, dislocation mobility increase, macroplastic unhardening and magnetoresonant softening in magnetic fields have been revealed. It is shown that the magnetosensitive spin-dependent reactions between structural defects is the reason of magnetoplastic effects in nonmagnetic crystals. It means that the electron and nuclear spin states of the paramagnetic defects play an important role in the formation of mechanical properties of crystals in magnetic fields and without them.     

Fine Purification of Monoisotopic Silanes 28SiH4 , 29SiH4 , and 30SiH4 via Distillation

High-purity isotopically enriched (99.98% ²⁸Si, 99.57% ²⁹Si, and 99.83% ³⁰Si) silane samples are prepared for the first time. The total hydrocarbon content of the samples is no higher than 0.1–0.3 ppm. The concentration of electroactive impurities in the silicon prepared from the purified monoisotopic silane is below 10¹⁵ cm^–3.     

Preparation and Properties of Er- and Yb-Activated TeO2–WO3 Glasses

TeO₂–WO₃ glasses coactivated with Er³⁺ and Yb³⁺ are prepared. The effect of Yb content on the efficiency of Er photoluminescence (PL) in the visible and IR spectral regions is studied. The highest PL efficiency is achieved at an Er : Yb atomic ratio of 1 : 1. The PL lifetime for the Er^{3+ 4} I _13/2 level is determined to be 7–9 ms.     

High-strain-rate superplasticity of nanocrystalline aluminum alloy 1570

The structure and mechanical properties of nanocrystalline aluminum alloy 1570 obtained by means of severe plastic deformation have been studied. Being tested in a temperature range from 300 to 400°C, the alloy exhibits high-strain-rate superplasticity. At 400°C, the superplasticity is manifested in a very broad range of strain rates, extending from 5 × 10^?3 to 1 s^?1.     

Studying chaotic microwave oscillations in a TWO with depressed collector

Broadband chaotic oscillations were monitored in a depressed potential collector of a traveling-wave oscillator (TWO). This signal appears due to the oscillations of a virtual cathode, which is formed in the spent electron beam under the action of retarding fields existing in the multistage depressed collector.     

Optical properties of strain-compensated InAs/InGaAsN/GaAsN superlattices

The optical properties of heterostructures comprising InAs/InGaAsN quantum wells in strain-compensated GaAsN/InGaAsN superlattices have been studied. It is demonstrated that, using such superlattices of various design and thickness and with additional InAs monolayer spacers, it is possible to control the wavelength of room-temperature emission from InGaAsN quantum wells within 1.3–1.6 μm without deteriorating the output radiation characteristics, which opens additional prospects for the development of lasers on GaAs substrates for telecommunication applications.     

Properties of gasars-metallic materials with pores formed by released hydrogen

We developed a new type of porous materials with anisotropic structure based on a large number of metals. It is shown that these material, called gasars, have properties different from the properties of the other porous materials. Thus, the strength of gasars is much higher than the strength of powder materials with the same porosity and their impact toughness is readily regulated by the sizes of the pores. The internal structures of gasars and possible versions of the types of pores in these materials are strongly diversified, which makes the spectrum of their possible applications very wide. We discuss some specific directions of the potential applications of gasars. The results of measurements of the thermal conductivity of gasars and monolithic specimens are presented. It is shown that, for a certain level of porosity, the specific thermal conductivity of gasars is higher than for monolithic materials. We also make some basic conclusions concerning the characteristics of new porous materials. __________ Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 5, pp. 125–127, September–October, 2007.     

Vibratory drier for the chemical industry

Modern designs are examined, and technical data presented for vibratory electric and convection driers, driers with infra-red sources, and steam driers.     

Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopic studies on the ferroelectric behavior of poly(vinylidene fluoride–trifluoroethylene) ultrathin films

Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopy was used to characterize the ferroelectric behavior of a thin poly(vinylidene fluoride–trifluoroethylene) P(VDF–TrFE) copolymer. The lab-built GIRA-FTIR apparatus allowed the heating and corona poling process to be carried out whilst collecting the GIRA spectra of the thin polymer film. The Curie transition from the ferroelectric to paraelectric phase was confirmed from the abrupt change in intensity of the 849 cm⁻¹ band in the RA-FTIR spectrum. It was found that the Curie temperature dropped dramatically when the film thickness was lowered to below a certain critical value of approximately 100 nm. The switching of the CF₂ dipoles in the ferroelectric crystals after applying the external electric field could be determined by monitoring the change in the 849 cm⁻¹ band intensity. For the 600 nm thick P(VDF–TrFE) film, the switching of the dipoles appears to occur almost instantaneously, while the kinetics of dipole switching of the 75 nm thick film were significantly retarded. The repeated switchability of the CF₂ dipoles upon the application of a bipolar cyclic electric field was also confirmed. The bistability of the film due to remnant polarization was also confirmed from the absorbance of the 849 cm⁻¹ band after removing the applied voltage during corona poling.