2-（4-氯苯氨基）甲基苯酚降解的动力学研究

采用高效液相色谱技术,开展了Fenton试剂对2-（4-氯苯氨基）甲基苯酚（CMP）的氧化降解动力学的研究。考察了初始双氧水摩尔浓度、亚铁离子摩尔浓度和温度等因素对CMP降解速率的影响,结果表明,当双氧水摩尔浓度、亚铁离子摩尔浓度增大和温度升高时,CMP的氧化速率明显加快。在30~45℃的温度范围内,其氧化降解符合假一级反应动力学模型,反应的表观活化能Ea为102.90kJ/mol。     

嵌入式消毒柜门内衬板拉深模具设计

通过对嵌入式消毒柜门内衬板工艺分析，确定其模具加工方案，同时对试模过程中存在的问题作进一步的剖析。     

Electrochemical and microstructural characterization of cyclic redox behaviour of SOFC anodes

The oxidation of Ni to NiO in solid oxide fuel cell (SOFC) anode will result in large bulk volume change, which may change the interfaces of the two phases in the anode cermet and thus may cause significant performance degradation. The reduction and oxidation (redox) of the Ni/YSZ cermet were studied at 800 ℃. Anodic polarization measurements were performed before and after redox cycles. The anode current density at an overpotential of 100 mV kept decreasing during the whole redox treatment. It decreased from 19.11 to 7.95 mA·cm-2 after two redox cycles. Anode supported unit cell was assembled for cell's discharge measurements. Cell performance declined after each redox cycle. The maximum power density decreased from 126.28 to 40.32 mW·cm-2 . The microstructural changes after redox cycling were recorded using scanning electron microscopy (SEM). The results reveal that after re-oxidation, the Ni gets coarse and has a higher porosity; the nickel network structure turns to be desultory.     

THE FLOW STRESS OF ALLOY STRUCTURAL STEELS AT HIGH TEMPERATURE AND HIGH STRAIN RATE

采用恒应变速率凸轮式压缩试验机对8种合金结构钢的流动应力进行了实验研究。其变形温度(T)、应变速率((?))及变形程度(ε％)分别为850—1150℃,5—80s~(-1)及5—69％。分析了变形温度、变形程度及应变速率对流动应力(σ)的影响。通过对变形温度影响项具有两种表达式的流动应力数学模型的非线性回归分析及比较,提出了拟合精度较高的8个合金结构钢流动应力的数学模型,并给出了数学模型的回归系数值。     

熟料烧结过程中氧化铁反应行为的热力学分析

通过对Fe2O3与碳酸钠、氧化钙以及硅酸钙反应的热力学分析,明确Fe2O3在铝土矿炉料烧结过程中的热力学反应规律。热力学计算、分析结果表明:Fe2O3在正常烧结温度范围内能与Na2CO3或CaO发生反应,但更易与CaO反应形成2CaO.Fe2O3或CaO.Fe2O3,Fe2O3和Na2O.Fe2O3能使2CaO.SiO2和3CaO.2SiO2转变为CaO.SiO2,CaO.SiO2进一步与Na2O.Al2O3或Na2O.Fe2O3反应生成不溶的三元化合物而造成烧结法生产氧化铝过程中Na2O和Al2O3的损失。4CaO.Al2O3.Fe2O3不能由铁酸钙和铝酸钠相互反应产生,而可能是CaO、Al2O3和Fe2O3三者直接反应的产物,且在烧结条件下Na2O.Fe2O3可分解4CaO.Al2O3.Fe2O3。     

金属材料屈服强度的应变率效应和热激活理论

对４种金属材料进行了应变率为１０＾－４－１０＾３ｓ＾－１的拉伸试验，结果表明，屈服中度随应变率的升高分两阶段线性升高，提出了位错线热振动对加载频率的响应的热激活作用机理，依据该机理计算所得Ⅰ，Ⅱ区临界应变εｃ与实测值相符，并在此基础上将应变率对掘强度影响的机制图重新划分为：Ｉ区，富热激活区；Ⅱ区，贫热激活区。     

PATTERN RECOGNITION APLLIED TO STABILITY OF FILLED Ti_2Ni PHASES

Pattern recognition method is used for the investigation of stability,region of filled Ti_2Niphases in multi-dimensional bond-parameter space.The filling of C,N and O atoms intoT_6 octahedra consisting of atoms of earhy-transition elements makes the expansion of thestability region of Ti_2Ni phase,and the relative stability of AI_2Cu and MoSi_2 type com-pounds decreases after the introduction of non-metallic elements such as C,N and O.     

机械零件刚度的模糊可靠性设计

介绍了机械零件刚度模糊可靠性设计变形分布参数和刚度隶属函数的确定,导出了零件刚度模糊可靠度的计算公式,并通过机床主轴模糊可靠性设计实例说明机械零件模糊可靠性的计算方法.     

小方坯粘结漏钢的检验与分析

粘结漏钢严重影响铸机生产率提高.对粘结漏钢残留坯壳进行检验分析,发现其具有外表面振痕紊乱、坯壳厚度从上向下逐渐变薄等特点.分析原因,制定相应的解决措施,取得了较好的效果.     

(Short communication) Degradation of corrosion resistance of Zircaloy-4 in LiOH aqueous solution

To investigate the degradation of corrosion resistance of Zircaloy-4 in LiOH aqueous solution, SIMS (secondary ion mass spectrometry) analysis was performed to examine the profiles of Li~ , K~ , and OH~- in oxide layers formed in the same concentration (0.1 mol/L) LiOH and KOH solutions. Even though the oxide layers have an equal thickness, the penetration depth of K~ is shallower than that of Li~ , and the penetration depth of OH~- corroded in KOH solution is also shallower than that corroded in LiOH solution. It shows that the diffusion of OH~- into oxide layer is accompanied by the corresponding cation. The difference of degradation effect of LiOH and KOH solutions on the corrosion resistance of Zircaloy-4 was discussed.