Inhibitory action of biodegradable modified vanillin on the corrosion of carbon steel in 1 M HCl

The effects of two biodegradable corrosion inhibitors derived from vanillin and aminophenol (Meta: VPAP and Para: VOAP) on the corrosion of carbon steel in 1 M HCl solution were examined. The efficiency of these inhibitors on carbon steel corrosion increased by increasing the concentration and decreased by increasing the temperature. The inhibitors adsorbed on carbon steel physically and obeyed the Langmuir isotherm. The potentiodynamic measurements showed mixed-type inhibitor. The geometry of the inhibitors showed that VPAP has slightly higher efficiency in corrosion inhibition than VOAP. The inhibitors showed good biodegradability in the environment within 28 days.     

LIQUEFACTION OF CELLULOSIC WASTE V. WATER FORMATION AND EVALUATION OF PYROLYTIC CHAR AS A BY —PRODUCT OF PYROLYSIS REACTION

ABSTRACT

Liquid hydrocarbon oil and water have been produced from the liquefaction of cellulosic matter present in municipal solid wastes (MSW). Gases and residual char have also been produced as by-products resulting from the pyrolysis reaction of cellulose. Quantities of water and pyrolytic char were estimated at different conditions of the process (temperature pressure of hydrogen, carrier oil medium and concentration of boric acid). From the results obtained, it was suggested that the formation of water seems to be sensitive to the operational conditions which enhance a water-gas shift reaction (in which water molecules are consumed to produce carbon dioxide and hydrogen). Decreasing of the undesired chary by-product could be achieved by increasing the concentration of boric acid that catalyzes the liquefaction reaction. Two petroleum distillates, namely gas oil and residual fuel oil, were used as carrier media of a solid refuse. It was found that fuel oil is more efficient as a buffering medium that prevents cellulose macromolecules from a rapid and complete charing during the liquefaction process. The pyrolytic char was characterized and evaluated by means of different analytical procedures and solvent extraction using petroleum ether 40–60°C and methanol. Calorific value of the pyrolytic char was found to be 4.6 Kcal g^?1 which is quite close to that of a brown coal. Dropping point test of the extracted material by petroleum ether indicated that the extract can be utilized for producing lubricating greases via saponificattion with a salt of sodium or calcium.     

Real-time rescheduling metaheuristic algorithms applied to FMS with routing flexibility

This paper presents the results of a simulation study of a typical flexible manufacturing system that consists of seven machining centres, a loading and an unloading area, and six different part types. Owing to the existence of identical machining centres, the part types have alternative routings (their number varies between two and eight). One of the objectives of this work is to show how the following metaheuristics: ant colony optimisation, genetic algorithms, simulated annealing, tabu search, particle swarm optimisation and electromagnetism-like method, are adapted for solving the alternative routing selection problem in real time in order to reduce the congestion in the system by selecting a routing for each part among its alternative routings. The other goal is to highlight the impact of the real-time rescheduling of parts contained in the loading station on system performances when these metaheuristics are applied. The simulation results jugged by the production rate, machines and material handling utilisation rate show that for an overloaded system, the real-time rescheduling outperforms the case without rescheduling, but it has a negative impact on the work in process.     

Design and safety optimization of ship-based small nuclear power reactors

Design and safety optimization of ship-based nuclear power reactors have been performed. The neutronic and thermo-hydraulic programs of the three-dimensional X–Y–Z geometry have been developed for the analysis of ship-based nuclear power plant. Quasi-static approach is adopted to treat seawater effect and quasi-static approach is also employed to treat neutronic aspect during safety analysis.

The reactors are loop type lead–bismuth-cooled fast reactors with nitride fuel and with relatively large coolant pipe above reactor core, the heat from primary coolant system is directly transferred to water–steam loop through steam generators. The power level is 100–200 MW th and excess reactivity is about 1$. Three types of core were investigated in the optimization process: balance, tall, and pancake with five values of Z–Y size ratio.

As the optimization results, the core outlet temperature distribution is changing with the elevation angle of the reactor system. The pancake core type has larger temperature distribution change as the elevation angle changes due to the sea wave. The natural circulation capability is good for safety. However, large driving head of natural circulation may cause large temperature fluctuation as the elevation angle changes.     

Environmental factors affecting the corrosion behavior of reinforcing steel III. Measurement of pitting corrosion currents of steel in Ca(OH)2 solutions under natural corrosion conditions

Using a simple electrolytic cell, the pitting corrosion current of reinforcing steel is measured in Ca(OH)₂ solutions in presence of chloride and sulfate as aggressive ions. Pitting corrosion current starts to flow after an induction period which depends on the concentration of both the aggressive and the passivating anions. The pitting corrosion current densities reach steady-state values which depend also on the type and concentration of the corrosive and passivating anions. The corrosive action of the aggressive species decreased in the order: SO₄²⁻ > Cl⁻. Corrosion of the steel is found to be governed by a single electron transfer reaction. Raising the temperature decreases the induction period associated with pit initiation and increases the corrosion current associated with pit propagation. From Arrhenius plots, the activation energies for both pit initiation and pit propagation in presence of chloride and sulfate ions are calculated.     

Effect of γ-irradiation on the frequency-independent parameters of an equivalent circuit for two-dimensional island platinum films

Four sets (A, B, C and D) of two-dimensional island platinum films [2D-I(Pt)Fs] were prepared by the thermal evaporation technique. The mass thicknesses for the films of such sets are 1, 5, 10 and 20 Å, respectively. The frequency-independent parameters of one of the equivalent circuit for island metal films in general are R _b, R _g and C _g where R _b is the resistance of the islands themselves while R _g is the resistance that accompanies the transfer of electrons across the gaps among islands and C _g is the capacitance that results from the separated metallic islands. The least-square values of R _b, R _g and C _g for our films were deduced via a computerized analysis. The stabilized films were exposed to γ-rays at doses 100, 200, 300, 500 and 700 Gy using ¹³⁷Cs (0.662 MeV) radiation source of dose rate 0.5 Gy/min. It was found that (1) For any particular mass thickness: (a) R _b and R _g decreases with the increase in the dose of γ-rays while C _g increases (b) the absolute value of the fractional change in R _b, R _g and C _g increases with the increase in dose. (2) For any particular dose the increase in the fractional change in R _b, R _g and C _g becomes more pronounced when the mass thickness increases. Qualitative interpretation for our results was given on the ground that γ-rays changed the island’s shape from spherical to prolate spheroid one and this has been checked experimentally via imaging the films by Atomic Force Microscope before and after γ-irradiations.     

Corrosion resistance of a new AL 6013-20 SiC(P) in salt spray chamber

Aluminum 6013 alloy (0.82Si, 0.95Mg, and 0.35Mn) is finding increasing usage in new aircraft designs, automotives, and structural applications due to its good stretch forming character in T4 temper (solution heat treated and naturally aged to a substantially stable conditions) compared to alloy 2024 (4.4Cu, 0.6Mn, 1.5Mg, and balance Al) and Al6061 (Si0.51 to 0.71, Fe0.35, Cu0.15, Mn0.85, Mg0.15, 0.25Cr, 0.15Zn, and balanced Al). The newly developed A1 6013 reinforced with 20 vol.% SiC(P) has a higher strength than its unreinforced counterpart. Whereas the corrosion behavior of A1 6013 has been reported in literature, there is no previous data on A1 6013 reinforced with SiC(P). A knowledge of the corrosion behavior of this alloy is crucial to its applications in aerospace, structural, and automotive industry. The first results of corrosion study of this alloy in 3.5 wt.% Na Cl in a salt spray chamber are presented. Three tempers F (as fabricated), O (annealed), and T4 (age hardened and stabilized at room temperature) of the alloy A1 6013-30 SiC(P) were exposed to environmental chamber in accordance with ASTM recommended practice. The corrosion rate of the alloy showed a decrease with increased exposure period and after 800 h of exposure no appreciable change in the rate of corrosion was observed. The lowest rate of corrosion (4.83 mdd) was shown by temper T4 followed by tempers F and O after 1200 h of exposure in the increasing order of corrosion rate. Fluctuations in the corrosion rate with time are related to the kinetics of growth and dissolution of Al(OH)₃ film, which was detected by fourier transformation infrared (FTIR) spectroscopy (FTIS). The film was composed of an inner compact layer and outer bulk layer dependent on the refreshment rate from the bulk solution. Micrograph examination by scanning electron microscopy (SEM) showed the presence of pits covered by aluminum hydroxide gel, which isolates the pit from the bulk solution. The acidic conditions of pits also cause intergranular attack. Pitting was observed to be less pronounced in temper T4 compared to F and O tempers, the former also showing the highest resistance to corrosion. The data generated predict promising application potential of this alloy in environment where resistance to corrosion is also a major consideration.     

SODIUM LIGNIN SULFONATE TO STABILIZE HEAVY CRUDE OIL-IN-WATER EMULSIONS FOR PIPELINE TRANSPORTATION

The efficiency of sodium lignin sulfonate (SLS) as an anionic surfactant derived from waste wood pulping industry in stabilizing an Egyptian heavy crude oil (Geisum)-in-water emulsions for pipeline transportation has been investigated. The stability and rheology of the emulsions stabilized by SLS or with a nonionic surfactant nonyl phenol diethylenetriamine formaldehyde ethoxylate (NDFE) individually or in a mixture have been studied. It has been found that the dynamic shear viscosity of the crude oil decreases substantially when it is emulsified with water in the form of an oil-in-water type of emulsion. The stability of the oil-in-water emulsion increases as the surfactant concentration increases. Potable water and saline water containing different molar concentrations of NaCI have been used to study the effect of aqueous phase salinity on the stability and viscosity of the emulsion. Surfactant dissolved in saline water has been utilized to find out the possibility of injecting the surfactant into a well bore to effect emulsification in the pump or tubing for enhancing the production of heavy crude oils as oil-in-water emulsion. The study revealed that, the viscosity of the emulsion containing potable water is always less than that containing saline water and the viscosity increases as the salt content increased.     

Output-Only Dynamic Testing of Rameses II Colossus by Singular Value Decomposition

The oldest statue on earth—the 3,300-year-old colossus—of Rameses II is going to be transported from a major square in downtown Cairo to a new more-preserving home approximately 30?km away. The process of moving the huge granite sculpture is very complicated and has to be thoroughly investigated and carefully planned in order to avoid damage to such a valuable piece of cultural heritage. Determination of the vibration properties of the colossus is of major importance in order to evaluate the effect of the expected excitations from the forthcoming processes. To this end, the application of the advanced modal testing technique serves the process in detecting and assessing the weaker critical regions of the old colossus. This study is the first step in an intended comprehensive modal testing program. The study provides understanding of the distinctions in the basic modal behavior of the historic colossus. It also gives an assessment for the level of vibration this invaluable colossus is currently exposed to. A three-dimensional (3D) finite-element model was built based on accurately surveyed geometry from the site. The solid modeling capabilities of the ANSYS software helped in modeling the complex 3D geometry. Model updating was performed based on the results determined from ambient vibration tests and observations from the site. The updated model correlated well with the vibration test results. It showed the existence of weak areas close to the feet and to the head-to-abdomen conjunction. It also pointed out the degrading of the granite material properties.     

Application of SrRuO3 Nanoparticles Supported with Reduced Graphene Oxide for Degradation of Thiophene Under Visible Light Irradiation

Journal of Inorganic and Organometallic Polymers and Materials - The existence of thiophene (TP) in fuel processing technology is considered a real threat to the environment. So the development of...