Analysis of the influence of binder properties on the mechanical response of bituminous mixtures

Asphalt mixtures are composed by a mass of aggregates (more than 90% of their total weight), which are bonded by a bituminous binder. Despite the fact that the binder is not the main component of these materials (around 5% of their total weight), it exerts a high influence on their mechanical response. In this sense, the service life of asphalt pavements will directly depend on the type of binder used, and thus an adequate choice is crucial to construct more durable roads. Because of this fact, it is necessary to know the characteristics of the bitumen in order to reduce the impact of different distresses that appear on roads. For this purpose, this paper studies the influence of the binder properties in the appearance of the main distresses that affect asphalt pavements around the world (stripping, fatigue cracking and plastic deformations). Five bitumens with different properties have been analysed during this research using diverse binder (UCL, multiple stress creep and recovery test and dynamic shear rheometer time sweep) and mixture (water sensitivity, wheel tracking and UGR-FACT) tests. The results obtained show that the properties of the binder influence the long-term performance of bituminous mixtures. In this sense, it can be said that flexible binders which are able to recover plastic deformations could extend the service life of the pavements.     

Characterisation of neutron fields around high-energy x-ray radiotherapy machines

Photoneutron spectra around the treatment bed of a Varian Clinac 2100C machine were measured using a Bonner sphere spectrometer. To overcome problems with pulse pile-up and detection of non-neutron-induced events, the active detector of thermal neutrons normally used at the centre of the spheres was replaced by a sandwich of four CR-39 track detectors interleaved with 10B radiators. Track densities measured for the CR-39 detectors in Bonner spheres were used for the unfolding of neutron spectra. Neutron fluence and ambient dose equivalent for the whole energy range and partial energy intervals were derived from the neutron spectra.     

MITOM: a new unfolding code based on a spectra model method applied to neutron spectrometry

The MITOM code was developed at UAB (Universitat Autònoma de Barcelona) for unfolding neutron spectrometric measurements with a Bonner spheres system (BSS). One of the main characteristics of this code is that an initial parameterisation of the neutron energy components (thermal, intermediate and fast) is needed. This code uses the Monte Carlo method and the Bayesian theorem to obtain a set of solutions achieving different criteria and conditions between calculated and measured count rates. The final solution is an average of the acceptable solutions. The MITOM code was tested for ISO sources and a good agreement was observed between the reference values and the unfolded ones for global magnitudes. The code was applied recently to characterise both thermal SIGMA and CANEL/T400 sources of the IRSN facilities. The results of these applications were very satisfactory as well.     

A priori vs. a posteriori normalisation of citation indicators. The case of journal ranking

Two paradigmatic approaches to the normalisation of citation-impact measures are discussed. The results of the mathematical manipulation of standard indicators such as citation means, notably journal Impact Factors, (called a posteriori normalisation) are compared with citation measures obtained from fractional citation counting (called a priori normalisation). The distributions of two subfields of the life sciences and mathematics are chosen for the analysis. It is shown that both methods provide indicators that are useful tools for the comparative assessment of journal citation impact.     

Degradation of alachlor and pyrimethanil by combined photo-Fenton and biological oxidation

Biodegradability of aqueous solutions of the herbicide alachlor and the fungicide pyrimethanil, partly treated by photo-Fenton, and the effect of photoreaction intermediates on growth and DOC removal kinetics of the bacteria Pseudomonas putida CECT 324 are demonstrated. Toxicity of 30–120 mg L⁻¹ alachlor and pyrimethanil has been assayed in P. putida. The biodegradability of photocatalytic intermediates found at different photo-treatment times was evaluated for each pesticide. At a selected time during batch-mode phototreatment, larger-scale biodegradation kinetics were analysed in a 12 L bubble column bioreactor. Both alachlor and pyrimethanil are non-toxic for P. putida CECT 324 at the test concentrations, but they are not biodegradable. A 100 min photo-Fenton pre-treatment was enough to enhance biodegradability, the biological oxidation response being dependent on the pesticide tested. The different alachlor and pyrimethanil respiration and carbon uptake rates in pre-treated solutions are related to change in the growth kinetics of P. putida. Reproducible results have shown that P. putida could be a suitable microorganism for determining photo-Fenton pre-treatment time.     

Electrical properties and chemical compatibility of PZT thick film on Ni substrates

The characteristics of Pb(Zr,Ti)O₃(PZT) thick films that were printed and fired on Ni substrates were studied. The dielectric characteristics of samples sintered at 850°C on Ni substrates could not be measured due to the formation of a NiO layer at the Ni/PZT interface. The scanning electron microscope and energy dispersive X-ray analysis of cross-sections of the PZT thick films on Ni substrates, and of a mixture of PZT and NiO powders, fired at 850°C, did not indicate the formation of secondary phases. However, the transmission electron microscopy showed around 8% solid solubility of NiO in the PZT. A new structure with a prefired, Au thick-film layer was designed in order to prevent the diffusion of the NiO to the PZT layer during sintering. The dielectric properties of the PZT layers printed and fired on the Ni substrates with the prefired Au electrode were significantly better than those of the layers on the uncoated substrate, the dielectric losses decreased from 0.23 to 0.05.     

Development Pathways of Large Housing Estates in Post-socialist Cities: An International Comparison

Large housing estates in former state-socialist countries had been hardly affected by social erosion before the political changes. However, the emergence of new, capitalist forms of housing after 1990 started to endanger the position of large housing estates on the local housing market. The question was repeatedly raised in the literature about whether large housing estates of post-socialist cities would experience physical decay and social downgrading similar to the West. This paper investigates the socio-economic differentiation of large housing estates in the former state-socialist countries using a case study approach. Housing satisfaction and mobility of residents in four post-socialist housing estates were analysed through a standardised household survey. Empirical data confirm that despite their similar physical appearance, the attitude of people towards large housing estates and their position on the local housing market vary significantly. The authors conclude that even though socialist large housing estates are affected by social downgrading, nevertheless they represent relative social stability and can offer affordable housing to people who are at the start of their housing career.     

North–South transfers vs biodiversity conservation: a trade differential game

Trade relationships connect developed and developing countries. The former produces a consumption good, using labor, capital, and an intermediate “natural” good which is produced in the developing countries using labor and natural species. A finite horizon differential game is settled out. The North decides about either the saving rate or the portion of its disposable income to transfer to the South or both variables jointly. The South selects the range of species used in the production of the intermediate “natural” good required in the North’s productive process. This is a measure of biodiversity loss. The aim of the paper is to study how transfers from North to South affect capital growth and biodiversity conservation.