Electron transmission through organized organic thin films

Low-energy electron photoemission spectroscopy (LEPS) allows the study of the electronic properties of organized organic thin films (OOTF) adsorbed on conducting surfaces by monitoring the energy and angular distribution of electrons emitted from the substrate and transmitted through the film. The transmission properties are explained by electronic band structure in the organic film. This band is an example of an electron resonance that is delocalized in the layer. It results from the two-dimensional nature of the layer. Other resonances in the transmission spectra are also discussed, as well as their experimental manifestation. The temperature dependence of the electron transmission efficiency is explained in terms of dependence of the transmission probability on the initial momentum of the electron and on the relative orientation of the electron velocity and the molecules in the film. Hence, despite the fact that the molecules in the OOTF are weakly interacting, when not charged, the electron transmission through the film is governed by cooperative effects. These effects must be taken into account when considering electronic properties of adsorbed layers.     

Wireless network design via 3-decompositions

We consider some network design problems with applications for wireless networks. The input for these problems is a metric space (X,d) and a finite subset UX of terminals. In the Steiner Tree with Minimum Number of Steiner Points (STMSP) problem, the goal is to find a minimum size set SX−U of points so that the unit-disc graph of S+U is connected. Let Δ be the smallest integer so that for any finite VX for which the unit-disc graph is connected, this graph contains a spanning tree with maximum degree Δ. The best known approximation ratio for STMSP was Δ−1 [I.I. Măndoiu, A.Z. Zelikovsky, A note on the MST heuristic for bounded edge-length Steiner trees with minimum number of Steiner points, Information Processing Letters 75 (4) (2000) 165–167]. We improve this ratio to (Δ+1)/2+1+ε.In the Minimum Power Spanning Tree (MPST) problem, V=X is finite, and the goal is to find a “range assignment” on the nodes so that the edge set contains a spanning tree, and ∑_vVp(v) is minimized. We consider a particular case {0,1}-MPST of MPST when the distances are in {0,1}; here the goal is to find a minimum size set SV of “active” nodes so that the graph (V,E₀+E₁(S)) is connected, where , and E₁(S) is the set the edges in with both endpoints in S. We will show that the (5/3+ε)-approximation scheme for MPST of [E. Althaus, G. Calinescu, I. Măndoiu, S. Prasad, N. Tchervenski, A. Zelikovsky, Power efficient range assignment for symmetric connectivity in static ad hoc wireless networks, Wireless Networks 12 (3) (2006) 287–299] achieves a ratio 3/2 for {0,1}-distances. This answers an open question posed in [E. Lloyd, R. Liu, S. Ravi, Approximating the minimum number of maximum power users in ad hoc networks, Mobile Networks and Applications 11 (2006) 129–142].     

Pericyclic Organometallic Reactions. Substituent Effects on Cycloadditions and Rearrangements of (η4-cycloheptatriene)Fe(CO)3 Derivatives

The mechanism of the reactions of (η⁴-cycloheptatrien-1-al)Fe(CO)₃ and its ethyleneglycol acetal with tetracyanoethylene (TCNE) was studied. The aldehyde undergoes a fast reversible 3+2 cycloaddition involving the free aldehyde-substituted double bond, and a slow irreversible 3+2 cycloaddition at the coordinated site. The latter, σ,π-allylic complex undergoes a slow interconversion with the corresponding 5 +2 isomer via the pericyclic [3,3]-sigmahaptotropic rearrangement. In contrast, the acetal reacts with TCNE at the free acetal-substituted double bond to give a single kinetic 3+2 adduct, which, under thermodynamic conditions, undergoes a [4,4]-sigmahaptotropic rearrangement to the 6 + 2 adduct. The reaction kinetics was followed by ¹H NMR. The effect of substituents on the reaction course is discussed, and the detailed mechanism of both the cycloadditions and rearrangements is described.     

Novel algorithms for the network lifetime problem in wireless settings

One of the major concerns in wireless ad-hoc networks design is energy efficiency. Wireless devices are typically equipped with a limited energy supply sufficient only for a limited amount of time which is reversely proportional to the transmission power of the device. The network lifetime is defined as the time the first device runs out of its initial energy charge. In this paper we study the maximum network lifetime problem for broadcast and data gathering in wireless settings. We provide polynomial time approximation algorithms, with guaranteed performance bounds while considering omnidirectional and unidirectional transmissions. We also consider an extended variant of the maximum lifetime problem, which simultaneously satisfies additional constraints, such as bounded hop-diameter and degree of the routing tree, and minimizing the total energy used in a single transmission. Finally, we evaluate the performance of some of our algorithms through simulations.     

Geometric superresolution by code division multiplexing

In many highly resolved optical systems the resolution is limited not by the optics but by the CCD's nonzero pixel size. As a result, overall resolution is decreased. Here we propose a novel approach to enhancing resolution beyond the limit set by the CCD's pixels. This method does not involve additional mechanical elements, such as those used for microscans. In this scheme neither the CCD nor additional elements are moved. The geometric superresolving procedure is based on code-division multiplexing, with all its inherent benefits, such as relative noise immunity to single-tone interference. A setup is proposed for coherent and incoherent illumination, with slight modifications for the latter. A theoretical analysis of the setup is presented and compared with empirical results. This scheme is shown to enhance one-dimensional image resolution with the use of only a simple mask that doubles image resolution. This method can easily be expanded to two-dimensional images and to resolution-enhancement factors greater than 2.     

Ortho Effects. I. The Mechanisms of the H3O and CH3O2 Elimination from the Molecular Ion of N-Methyl Ortho-Nitro-Para-Toluidine

The molecular ion of the N-methyl ortho-nitro-para-toluidine (I) readily eliminates H₃O. The sources of the H atoms lost were proved by deuterium labeling to be an HNCH₃ group as well as, probably, the C-methyl group of the aromatic ring. The interaction between the N-methyl and nitro groups in I also leads to the expulsion of CH₃O₂ from the molecular ion.     

Concurrent Formation of Metallic Glass During Laser Forward Transfer 3D Printing

In recent years, bulk metallic glasses (BMGs) have drawn much research attention and are shown to be of industrial interest due to their superior mechanical properties and resistance to corrosion. In spite of the interest in harnessing MG for microelectromechanical systems devices, there are limitations in manufacturing such micrometer‐scale structures. A novel approach for the fabrication of 3D MG structures using laser‐induced forward transfer (LIFT) is demonstrated. Inherent tremendous cooling rates associated with the metal LIFT process (≈10¹⁰ k s^?1) make the formation of a variety of BMGs accessible, including also various binary compositions. In this work, it is demonstrated that LIFT printing of ZrPd‐based metallic glass microstructures can also be performed under ambient conditions. X‐ray diffraction analysis of the printed structures reveals > 95% of amorphous metal phase. Taking advantage of the properties of BMG, high quality printing of high aspect ratio BMG pillars, and microbridges are demonstrated. It is also shown how a composite, amorphous‐crystalline metal structure with a required configuration can be fabricated using multimaterial LIFT printing. The inherent high resolution of the method combined with the noncontact and multimaterial printing capacity makes LIFT a valuable additive manufacturing technique to produce metallic glass‐based devices.     

Using Fourier/Mellin-based correlators and their fractional versions in navigational tasks

The navigational tasks of computing time to impact and controlling movements in specific range are addressed here. We show how time to impact can be obtained via the Mellin-based correlator, and we introduce the concept of fractional based correlators. The fractional Fourier/Mellin based correlators can be used in detecting or controlling specific range of movements. Also, both the conventional and the fractional-based correlators can be easily implemented optically in lenses, thus providing correlation images directly at image acquisition time. Lenses are considered cost-effective and therefore, the optical correlators are optimal in both senses, speed and cost.     

Image data compression based on non-negative incoherent imaging systems

Channel and memory capacities are limited and expensive resources in optical communication. In this work we propose several approaches to reduce the required capacity by using the a priori knowledge about the optical system used to capture the spatial information. The a priori knowledge is related to the triangularlike shape of the optical transfer function and to its spectral symmetry. In our work we will demonstrate a reduction in memory capacity required for the same image quality or a resolution enhancement for the same physical memory capacity. We will also present a nearly all-optical implementation of these techniques.     

Resolution improvement by single-exposure superresolved interferometric microscopy with a monochrome sensor

Single-exposure superresolved interferometric microscopy (SESRIM) by RGB multiplexing has recently been proposed as a way to achieve one-dimensional superresolved imaging in digital holographic microscopy by a single-color CCD snapshot [Opt. Lett. 36, 885 (2011)]. Here we provide the mathematical basis for the operating principle of SESRIM, while we also present a different experimental configuration where the color CCD camera is replaced by a monochrome (B&W) CCD camera. To maintain the single-exposure working principle, the object field of view (FOV) is restricted and the holographic recording is based on image-plane wavelength-dispersion spatial multiplexing to separately record the three bandpass images. Moreover, a two-dimensional extension is presented by considering two options: time multiplexing and selective angular multiplexing. And as an additional implementation, the FOV restriction is eliminated by varying the angle between the three reference beams in the interferometric recording. Experimental results are reported for all of the above-mentioned cases.