全文获取类型
收费全文 | 127篇 |
免费 | 13篇 |
专业分类
电工技术 | 3篇 |
化学工业 | 30篇 |
金属工艺 | 2篇 |
机械仪表 | 3篇 |
建筑科学 | 4篇 |
能源动力 | 7篇 |
轻工业 | 39篇 |
无线电 | 5篇 |
一般工业技术 | 20篇 |
冶金工业 | 16篇 |
自动化技术 | 11篇 |
出版年
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 15篇 |
2017年 | 6篇 |
2016年 | 6篇 |
2015年 | 3篇 |
2014年 | 12篇 |
2013年 | 8篇 |
2012年 | 6篇 |
2011年 | 10篇 |
2010年 | 9篇 |
2009年 | 10篇 |
2008年 | 4篇 |
2007年 | 1篇 |
2006年 | 3篇 |
2005年 | 2篇 |
2004年 | 4篇 |
2003年 | 3篇 |
2002年 | 2篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1993年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有140条查询结果,搜索用时 15 毫秒
11.
12.
Abdelkarim Chaouiki Hassane Lgaz Saman Zehra Rachid Salghi Yasmina El Aoufir 《Journal of Adhesion Science and Technology》2019,33(9):921-944
A novel quinazoline derivative, 3-cyclopropyl-3,4-dihydroquinoline-2(1H)-One (CPHQ), was successfully designed and synthesized. Then, its corrosion inhibition behavior on carbon steel (CS) surface in 1.0?M HCl at different temperatures was investigated using chemical, electrochemical and theoretical techniques. The experiments confirmed that the studied inhibitor shows inhibition efficiency as high as 95% even at very low concentration of 5?×?10?3 M. To ascertain the nature of adsorption of CPHQ molecules on CS surface, Langmuir adsorption isotherm model was best fitted. From potentiodynamic polarization (PDP) calculations, it was concluded that the CPHQ acted as a mixed type corrosion inhibitor. Electrochemical impedance spectroscopy (EIS) studies revealed that increase in CPHQ concentration, resulted in an increase in the polarization resistance with a simultaneous decrease in the double-layer capacitance values. PDP tests were also performed to understand the corrosion behavior of CS as a function of temperature without and with varying concentrations of CPHQ, at temperatures 303, 313, 323, and 333?K. It can be concluded that the corrosion inhibition effect was dependent on the concentration of the inhibitor and the solution temperature. In order to understand the basic insights of the action mode of CPHQ molecules, Density Functional Theory (DFT) method, and Molecular Dynamic (MD) simulations were also employed on the optimized structure of CPHQ. 相似文献
13.
14.
Bio-/Environment-Friendly Cationic Gemini Surfactant as Novel Corrosion Inhibitor for Mild Steel in 1 M HCl Solution 下载免费PDF全文
Mohammad Mobin Ruby Aslam Saman Zehra Musheer Ahmad 《Journal of surfactants and detergents》2017,20(1):57-74
Bio-/environment-friendly cationic gemini surfactant, ethane-1,2-diyl bis(N,N-dimethyl-N-hexadecylammoniumacetoxy)dichloride, referred to as 16-E2-16, was synthesized and characterized. Corrosion inhibition effects of 16-E2-16 on mild steel (MS) surface in 1 M HCl solution at 30, 40, 50 and 60 °C were evaluated using gravimetric analysis, potentiodynamic polarisation and electrochemical impedance spectroscopy measurements. The nature of the protective inhibitor film formed on the MS surface was analysed by SEM, EDAX and FT-IR, while TGA was used to assure the thermal behaviour and stability of the film at high temperature. The formation of [inhibitor-Fe2+] on the surface of MS was confirmed by UV–visible spectroscopy. The inhibition efficiency of the studied inhibitor increased with increasing concentration and solution temperature. The compound behaved as a mixed type inhibitor and acted by blocking the electrode surface by means of adsorption obeying the Langmuir adsorption isotherm. Surface active properties and corrosion inhibition effects of 16-E2-16 in the presence of inorganic (NaI) and organic (NaSal) salts were also investigated and are discussed. Density functional theory calculations have been carried out to correlate the efficiency of the compound with its intrinsic molecular parameters. 相似文献
15.
We introduce a method that exploits the “active” nature of the force-sensing integrated readout and active tip (FIRAT), a recently introduced atomic force microscopy (AFM) probe, to control the interaction forces during individual tapping events in tapping mode (TM) AFM. In this method the probe tip is actively retracted if the tip–sample interaction force exceeds a user-specified force threshold during a single tap while the tip is still in contact with the surface. The active tip control (ATC) circuitry designed for this method makes it possible to control the repulsive forces and indentation into soft samples, limiting the repulsive forces during the scan while avoiding instability due to attractive forces. We demonstrate the accurate topographical imaging capability of this method on suitable samples that possess both soft and stiff features. 相似文献
16.
17.
Tamahkar Emel Özkahraman Bengi Özbaş Zehra İzbudak Burçin Yarimcan Filiz Boran Filiz Öztürk Ayça Bal 《Journal of Porous Materials》2021,28(3):741-750
Journal of Porous Materials - The antibacterial sponges with high macroporosity, high interconnectivity and high biocompatibility is a significant concern for wound healing applications. In this... 相似文献
18.
19.
Fuel cells are energy transformation technologies and they are clean, don't damage to environment, have high efficiency and provide uninterruptible energy generation. Research and development studies about fuel cells have been done increasingly. In the recent years, fuel cell technologies have performed in some sectors such as military, industrial, space, portable, residential, transportation and trading. 相似文献
20.
Abdulhadi Baykal Hüseyin Delig?z Hüseyin Sozeri Zehra Durmus Muhammet S. Toprak 《Journal of Superconductivity and Novel Magnetism》2012,25(6):1879-1892
We report on the synthesis and detailed composition, thermal, micro-structural, ac?Cdc conductivity performance and dielectric permittivity characterization of triethylene glycol (TREG) stabilized CoFe2O4 nanoparticles synthesized by polyol method. XRD analysis confirmed the inorganic phase as CoFe2O4 with high phase purity. Microstructure analysis with TEM revealed well separated, spherical nanoparticles in the order of 6?nm, which is also confirmed by X-ray line profile fitting. FT-IR analysis confirms that TREG is successfully coated on the surface of nanoparticles. Overall conductivity of nanocomposite is approximately two magnitudes lower than that of TREG with increase in temperature. The ac conductivity showed a temperature dependent behavior at low frequencies and temperature independent behavior at high frequencies which is an indication of ionic conductivity. The dc conductivity of the nanocomposites and pure TREG are found to obey the Arrhenius plot with dc activation energies of 0.258?eV and 0.132?eV, respectively. Analysis of dielectric permittivity functions suggests that ionic and polymer segmental motions are strongly coupled in the nanocomposite. TREG stabilized CoFe2O4 nanoparticles has lower ???? and ???? than that of pure TREG due to the doping of cobalt. As the temperature increases, the frequency at which (????) reaches a maximum shifted towards higher frequencies. On the other hand, the activation energy of TREG for relaxation process was found to be 0.952?eV which indicates the predominance of electronic conduction due to the chemical nature of TREG. Contrarily, no maximum peak of tan ?? was observed for the nanocomposite due to the being out of temperature and frequency range applied in the study. 相似文献