微波消解-石墨炉原子吸收光谱技术测定螺旋藻中铁、锌、镁、钙、钾、钠、铜、锰等微量元素

用微波消解技术对螺旋藻试样进行预处理,针对样品高蛋白特性,优化较佳的微波消解条件与参数,建立了用微波消解-石墨炉原子吸收法测定螺旋藻中铁、锌、镁、钙、钾、钠、铜、锰等微量元素的测定方法。该方法可减少样品预处理过程的损失,具有准确、快捷、方便的特点,回收率达96．4％-101．2％;RSD为0．8%-2．5％。     

甲醛生产工艺自动化控制方案

文章通过分析甲醇氧化制备甲醛生产的工艺特点及其固有的危险、有害因素,分析和讨论其工艺系统的安全参数控制要求和需重点监控的参数,提出甲醇氧化制备甲醛生产工艺过程的自动化控制方案,供同类企业进行自动化改造时参考。     

Microwave catalytic NOx and SO2 removal using FeCu/zeolite as catalyst

Non-thermal plasma technology is a promising process for flue gas treatment. Microwave catalytic NO_x and SO₂ removal simultaneously has been investigated using FeCu/zeolite as catalyst. The experimental results showed that a microwave reactor with FeCu/zeolite only could be used to microwave catalytic oxidative 91.7% NO_x to nitrates and 79.6% SO₂ to sulfate; the reaction efficiencies of microwave catalytic reduction of NO_x and SO₂ in a microwave reactor with FeCu/zeolite and ammonium bicarbonate (NH₄HCO₃) as a reducing agent could be up to 95.8% and 93.4% respectively. Microwave irradiation accentuates catalytic reduction of SO₂ and NO_x treatment, and microwave addition can increases SO₂ removal efficiency from 14.5% to 18.7%, and NO_x removal efficiency from 13.4% to 18.7%, separately. FeCu/zeolite catalyst was characterized by X-ray diffraction (XRD), X-ray photoelectron spectrum analysis (XPS), scanning electron microscopy (SEM) and the Brunauer Emmett Teller (BET) method. Microwave catalytic NO_x and SO₂ removal follows Langmuir-Hinshelwood (L-H) kinetics.     

氟改性羟基丙烯酸乳液的研究

以丙烯酸全氟烷基酯(Zonyl TM)为功能单体,阴离子、非离子乳化剂为复合乳化剂,采用预乳化半连续乳液聚合法合成了氟改性羟基丙烯酸乳液,并将合成的乳液与氨基树脂制得性能优异的丙烯酸氨基清漆.系统地研究了氟单体、交联单体、丙烯酸含量及苯乙烯和甲基丙烯酸甲酯的配比等因素对涂膜性能的影响,对影响清漆的混容性及贮存稳定性的各...     

褐煤干燥提质技术浅谈

介绍褐煤的基本性质和几种褐煤的干燥提质技术,如管式干燥技术、蒸汽流化床干燥技术(DWT法)、热脱水工艺和LFC褐煤干燥等,简单分析各工艺,展望褐煤干燥提质的前景.     

深圳某小区节水技术探索

介绍了深圳某小区所采用的中水回用技术和雨水资源化技术,并对其节水效果进行了探讨。处理后的生活污水和雨水可以作为中水回用,实现了污水零排放和雨水资源化。     

微波技术在环境治理中的应用

文章对微波技术在环境治理领域的应用和研究状况进行了综述,着重介绍了微波技术在除垢、油污回收、污水处理及减少SO2和NOx排放等方面的应用.并展望了微波技术在环境治理领域的应用前景.     

某铁路车辆厂含油废水混凝预处理试验研究

西北某车辆厂含油废水为达到回用水要求,需对其进行深度处理。混凝作为预处理,其效果好坏直接影响气浮及精细过滤,为此进行了影响混凝效果因素的正交试验。通过研究确定出适合该厂水质的混凝预处理控制条件为：混凝剂种类为PAC（I）,投加量为30 mg/L,搅拌速度250 r/min,搅拌时间90 s,助凝剂用量为0.4 mg/L。使混凝后出水浊度、COD、油分别在4.5 NTU、55 mg/L、6.0 mg/L左右,与原来混凝后出水浊度10~26 NTU、COD60~92 mg/L、油7.4~10.6 mg/L相比有较大提高,为后续处理作了稳定可靠地保。     

Electrospun poly(L‐lactide)/poly(ε‐caprolactone) blend fibers and their cellular response to adipose‐derived stem cells

Polymer blending is one of the most effective methods for providing new, desirable biocomposites for tissue‐engineering applications. In this study, electrospun poly(L ‐lactide)/poly(ε‐caprolactone) (PLLA/PCL) blend fibrous membranes with defect‐free morphology and uniform diameter were optimally prepared by a 1 : 1 ratio of PLLA/PCL blend under a solution concentration of 10 wt %, an applied voltage of 20 kV, and a tip‐to‐collector distance of 15 cm. The fibrous membranes also showed a porous structure and high ductility. Because of the rapid solidification of polymer solution during electrospinning, the crystallinity of electrospun PLLA/PCL blend fibers was much lower than that of the PLLA/PCL blend cast film. To obtain an initial understanding of biocompatibility, adipose‐derived stem cells (ADSCs) were used as seed cells to assess the cellular response, including morphology, proliferation, viability, attachment, and multilineage differentiation on the PLLA/PCL blend fibrous scaffold. Because of the good biocompatibility and nontoxic effect on ADSCs, the PLLA/PCL blend electrospun fibrous membrane provided a high‐performance scaffold for feasible application in tissue engineering using ADSCs. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Dynamic rheology and morphology of polylactide/organic montmorillonite nanocomposites

The effects of organic montmorillonite (OMMT) on the rheological behaviors and phase morphology of polylactide (PLA) were investigated. The rheological behaviors of nanocomposites showed mainly dependence on both temperature and OMMT content. At low OMMT loading (1 wt %), the complex viscosities showed a Newtonian plateau in low frequency region at low temperatures and converted to a shear‐thinning behaviors with increasing temperature. In comparison, at high OMMT loadings (above 5 wt %), strong shear‐thinning behaviors were observed in the full range of frequencies and temperatures. The results demonstrated rheology of PLA/OMMT is highly sensitive to the nanofillers filled materials. A pseudo‐solid‐like behavior at long scale time in the hybrids with OMMT loading was higher than 5 wt %, this response was related to the formation of a network structure across the polymer matrix due to strong interactions of PLA and OMMT that confined the relaxation process of the macromolecules. X‐ray diffraction and transmission electron microscopy indicated the nanocomposites at low OMMT loading were mainly exfoliated and intercalated nanocomposites were gradually formed with increasing OMMT loading. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011