The flame‐retardant properties and mechanisms of poly(ethylene terephthalate)/hexakis (para‐allyloxyphenoxy) cyclotriphosphazene systems

Para‐allyl ether phenol derivative of cyclophosphazene (PACP) was prepared and used as a filler to modify the flame‐retardant properties of poly(ethylene terephthalate) (PET) by melting‐blending. The mechanism of flame‐retardant was discussed and the influences of flame‐retardant contents to the mechanical properties were studied. The results revealed that the incorporation of only 5 phpp PACP (0.37 wt % phosphorus containing) into PET matrix can distinctly increase the flame retardancy of PET/PACP composition, and it has a little effect on the mechanical properties of PET. The high flame‐retardant performance of PET/PACP composite was attributed to the combination of condensed‐phase flame retardant and gas‐phase flame retardant. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42711.     

Simultaneous detection and removal of metal ions based on a chemosensor composed of a rhodamine derivative and cyclodextrin-modified magnetic nanoparticles

A variety of chemosensors have been reported for detection of metal ions. However, the metal ions could not be separated and removed at the same time for the goal of water purification. This paper presents to detect and remove metal ions from aqueous solution simultaneously by a fluorescence chemosensor and functional magnetic nanoparticles. A novel probe adamantyl (AD)–maleic anhydride (MAH)–rhodamine B (RhB) was designed and synthesized from RhB, ethylene diamine, MAH, and AD. AD–MAH–RhB showed high selectivity and sensitivity to metal ions in aqueous solution. The sensing mechanism was explored by FTIR and mass spectra. The results suggested that AD–MAH–RhB could conjugate with metal ions and form the binding complexes with various stoichiometries of probe and metal ions. Moreover, β-cyclodextrin-modified magnetic nanoparticles (CD-MNP) were fabricated and used as host materials to form inclusion complex of CD-MNP and AD–MAH–RhB-metal ions. Then, the metal ions could be removed by an outer magnet, which were confirmed by fluorescent spectrum. The probe and CD-MNP had the great potential application for sewage treatment.     

自旋转移力矩磁隧道结的建模与仿真

自旋转移力矩磁隧道结(STT-MTJ)是一种新兴的非易失性存储单元.因为有着掉电后数据不丢失、无限的写次数、与CMOS工艺兼容、不会增加器件面积以及良好的可缩放性等诸如多优点而得到了广泛的研究.但是由于目前的工艺厂商尚未推出相应的模型,研究者难以先期使用该技术进行电路设计.文章介绍了STT-MTJ的工作原理,详细研究了使用Verilog-A对STT-MTJ建模的思路,并在HSPICE中进行了仿真验证,为后续的STT-MTJ研究奠定了基础.     

省间交易合约转让（置换）交易机制研究

合约转让与置换交易作为是一种电力金融交易模式,可以为市场主体提供更灵活的交易模式,有效应对电力供需波动带来的市场风险,对中长期物理交易合约形成有益的补充。本文在对西电东送电源结构特点和框架协议执行情况总结的基础上,对西电东送合约转让与置换交易的必要性和可行性进行了论证,提出了基于不同电力供需形势的三种交易模型,进行了算例验证,并对具体交易组织和实施方案提出了设想,对开展相关工作具有一定指导意义。