In this study, we report the results of an investigation into the sintering temperature dependence of magnetic and transport properties for GdBaCo2O5 + δ synthesized through a sol-gel method. The lowering of sintering temperature leads to the increase of oxygen content and the reduction of grain size. The increase of oxygen content results in the enhancement of magnetic interactions and the weakening of Coulomb repulsion effect, while the reduction of grain size improves the magnetoresistance effect. Metal-insulator transition accompanied with spin-state transition is observed in all samples. 相似文献
The homogeneous incorporation of heteroatoms into two-dimensional C nanostructures, which leads to an increased chemical reactivity and electrical conductivity as well as enhanced synergistic catalysis as a conductive matrix to disperse and encapsulate active nanocatalysts, is highly attractive and quite challenging. In this study, by using the natural and cheap hydrotropic amino acid proline—which has remarkably high solubility in water and a desirable N content of ~12.2 wt.%—as a C precursor pyrolyzed in the presence of a cubic KCl template, we developed a facile protocol for the large-scale production of N-doped C nanosheets with a hierarchically porous structure in a homogeneous dispersion. With concomitantly encapsulated and evenly spread Fe2O3 nanoparticles surrounded by two protective ultrathin layers of inner Fe3C and outer onion-like C, the resulting N-doped graphitic C nanosheet hybrids (Fe2O3@Fe3C-NGCNs) exhibited a very high Li-storage capacity and excellent rate capability with a reliable and prolonged cycle life. A reversible capacity as high as 857 mAh•g–1 at a current density of 100 mA•g–1 was observed even after 100 cycles. The capacity retention at a current density 10 times higher—1,000 mA•g–1—reached 680 mAh•g–1, which is 79% of that at 100 mA•g–1, indicating that the hybrids are promising as anodes for advanced Li-ion batteries. The results highlight the importance of the heteroatomic dopant modification of the NGCNs host with tailored electronic and crystalline structures for competitive Li-storage features.
We consider the problem of revenue maximization on multi‐unit auctions where items are distinguished by their relative values; any pair of items has the same ratio of values to all buyers. As is common in the study of revenue maximizing problems, we assume that buyers' valuations are drawn from public known distributions and they have additive valuations for multiple items. Our problem is well motivated by sponsored search auctions, which made money for Google and Yahoo! in practice. In this auction, each advertiser bids an amount bi to compete for ad slots on a web page. The value of each ad slot corresponds to its click‐through‐rate, and each buyer has her own per‐click valuations, which is her private information. Obviously, a strategic bidder may bid an amount that is different with her true valuation to improve her utility. Our goal is to design truthful mechanisms avoiding this misreporting. We develop the optimal (with maximum revenue) truthful auction for a relaxed demand model (where each buyer i wants at most di items) and a sharp demand model (where buyer i wants exactly di items). We also find an auction that always guarantees at least half of the revenue of the optimal auction when the buyers are budget constrained. Moreover, all of the auctions we design can be computed efficiently, that is, in polynomial time. 相似文献
Multimedia Tools and Applications - In recent years there has been significant interest in reversible data hiding, and also in particular, reversible data hiding in encrypted images (RDH-EI). This... 相似文献
Structural and Multidisciplinary Optimization - The ubiquitous uncertainties presented in the input factors (e.g., material properties and loads) commonly lead to occasional failure of mechanical... 相似文献
According to the requirements of concurrent engineering, three interdependency relationships (uncoupled relationship, coupled relationship and decoupled relationship) between design activities are presented in this paper. And the coupled relationship plays an important role in concurrent product design process. To represent the precedence relationships among design activities, a directed graph is used to describe the design process. And the interdependency relationship between activities is illustrated by a Design Structure Matrix which is the transpose of the accessibility matrix of the corresponding graph. Using the DSM, an algorithm of recognizing the coupled activities during the design process is presented. Moreover, an algorithm to figure out the order levels of activities during the design process is proposed. And both algorithms are illustrated with a die design example. 相似文献
In this paper, we extend a previous work on a compact scheme for the steady Navier–Stokes equations [Li, Tang, and Fornberg (1995), Int. J. Numer. Methods Fluids, 20, 1137–1151] to the unsteady case. By exploiting the coupling relation between the streamfunction and vorticity equations, the Navier–Stokes equations are discretized in space within a 3×3 stencil such that a fourth order accuracy is achieved. The time derivatives are discretized in such a way as to maintain the compactness of the stencil. We explore several known time-stepping approaches including second-order BDF method, fourth-order BDF method and the Crank–Nicolson method. Numerical solutions are obtained for the driven cavity problem and are compared with solutions available in the literature. For large values of the Reynolds number, it is found that high-order time discretizations outperform the low-order ones. 相似文献