Improved electric insulation ability and ferromagnetic property in Nb2O5 doped BiFeO3-based multiferroic ceramics

Journal of Electroceramics - 0.675BiFeO3-0.3BaTiO3-0.025LaFeO3-x mol% Nb2O5 (x?=?0–1.25) multiferroic lead- free ceramics, fabricated by conventional solid-state reaction, were...     

挤压铸造Al-5Cu合金的组织与性能

使用挤压铸造工艺制备出一种新开发的、高强韧Al-5Cu合金,在50 MPa挤压力下铸造成型后,进行T4和T5热处理.经固溶处理后其抗拉强度达472 MPa,伸长率达10.5%.并对热处理状态下的组织和性能进行了分析研究.     

冶金企业面临的严峻局面及今后工作重点

阐述了冶金企业在当前的严峻形势下，要求得生存必须转变传统观念。并提出“九五”期间的工作重点是：节能降耗、调整品种结构、提高生产率及加强决策管理。重点论述了实现节能降耗应抓好的四项工作：连铸坯一火成材与热装直轧，轧钢炉窑节能技术，轧机主传动交流调速技术及控制冷却技术。     

Biological analysis of woodpecker’s brain after impact experiments

Woodpeckers can withstand a fierce impact during pecking. Previous studies have focused on the biomechanical analysis of the pecking process, the properties of the beak and hyoid bone of woodpecker; however, the biological characteristics of the woodpecker brain are also important in resisting impact injuries. We employed impact experiments and biological analysis in normal and injured brains to reveal the impact-resistant biological characteristics of woodpecker brains, as well as the impact energy's biological effects on the woodpecker brain. The hoopoe, which has a similar size but only a slight pecking behavior, was selected as the control group to compare brain morphology and neuronal cells differences in normal brains between woodpecker and hoopoe by sectioning and staining. A loading device was designed to conduct a quantifiable impact energy to the woodpeckers' head. Four groups of woodpeckers were impacted with the same energy on the forehead, beak, tempus and occiput,respectively. Biological changes in the injured brains were evaluated by Nissl staining and enzyme-linked immunosorbent assay.The results showed that:(1) woodpeckers had a larger cerebellum and a higher density of Nissl bodies than hoopoe;(2) Nissl apoptosis appeared in the brain samples after the forehead and the occiput impact experiments, but no obvious Nissl body apoptosis was observed after impact on the tempus and the beak;(3) β-amyloid protein accumulated in the normal status woodpecker brain. This study reveals that: woodpecker brain morphology is well-adapted to impact, woodpecker heads display location-dependent protective performance, with beak and tempus regions having a better protective performance than the forehead and occiput, Nissl apoptosis appears in injured woodpecker brains, and that the accumulation of β-amyloid protein does not show a direct relationship with the injury state of woodpecker's brain tissue in our study.     

组织蛋白酶C特异性荧光底物的合成和血清学分析应用

组织蛋白酶C是溶酶体半胱氨酸蛋白酶,源于免疫颗粒细胞.组织蛋白酶C作为近年来的研究热点,在于其为颗粒细胞炎症性丝氨酸蛋白酶的上游活化酶,在生理和病理过程中有着重要作用.通过研究设计并合成基于香豆素的荧光底物(CatC-AFC)来评估血清组织蛋白酶C的活性.结果表明,在特异性底物CatC-AFC与组织蛋白酶C反应后,荧光强度在非常短的时间内显著增加.酶动力学研究显示组织蛋白酶C以稳健的,线性的和时间依赖性的方式水解CatC-AFC.通过梯度稀释方法验证基于血清中组织蛋白酶C的活性测定,并且没有观察到干扰或自发荧光.基于血清中组织蛋白酶C活性的方差系数表明了良好的重现性.     

Effect of sulfate on Cu(Ⅱ) sorption to polymer-supported nano-hydrated ferric oxides: Experimental and modeling studies

Incorporating of hydrous ferric oxide(HFO) inside porous supports with large sizes has become an effective way to decontaminate the water from heavy metals. Ubiquitous anions like sulfate are usually present in high concentrations in water, and might greatly affect adsorption behavior of hybrid HFO. Here, a polymer-based HFO-CPS was fabricated by encapsulating nano-HFO inside a chloromethylated polystyrene polymer(CPS) and the reactivity of HFO-CPS with Cu(Ⅱ) was evaluated in the presence of sulfate ions.Surface complexation theory was firstly employed to describe the effect of sulfate on Cu(Ⅱ) adsorption edges of hybrid HFO-CPS, where constant capacitance model(CCM) was adopted. The available weak adsorption site Fe_((2))OH of hybrid HFO-CPS was found to decrease from 20% Fe to 5% Fe, which might be caused by the pore plugging effect after HFO encapsulation. With the assumption that a ternary complex was formed, the effect of sulfate on Cu(Ⅱ) adsorption by HFO-CPS were successfully described by CCM using the optimized Fe_((2))OH site under different sulfate concentrations(1 or 10 mmol·L~(-1)) and Cu/Fe ratios(0.0042 or 0.0252). It is confirmed that the formation of Fe OHCu SO_4 ternary surface complexes played an important role in enhancing Cu(Ⅱ) adsorption on HFO-CPS in the presence of sulfate.     

电场耦合取能技术的仿真与试验研究

为给输电线路的监测器件提供稳定、便利的电源,基于电磁感应的原理设计了无线电容取电装置,可以最大化利用空间能量,对支撑输电线路的运行状态监测具有重要意义。首先,分析了电容取电的结构,以此得到取能装置输出功率与高压杂散电容、低压杂散电容、负载电阻等参数的计算关系,发现合理增加感应电极面积、减小感应电极电容值和增加负载电阻值可以有效提升取能装置输出功率;其次,利用多物理场仿真软件模拟了电容取电的影响因素,最后,通过Matlab软件设计了高压实验装置,对实际情况进行模拟与实验。实验结果表明,当电源电压为10 k V、耦合电容为14 p F时,1 MΩ的负载可以得到0.12 m W功率。     

一种新型无线智能雷电计数仪的研发与技术应用

高压输电系统接闪雷击次数是高压输电系统雷电防护能力评价的重要指标之一,也是雷击防御整改的重要依据.针对高压输电线路运行的复杂环境和特殊气候,按照输电线路雷电防护要求,基于电力物联网架构和无线传感技术原理研制出一种低能耗、高可靠和智能化的雷击计数仪,可有效提升高压输电网的雷电防御能力,确保高压输电线路的运行安全.     

离子色谱法测定镀液中的六价铬离子

建立了用单柱阴离子色谱测定镀液中六价铬离子的方法.采用HPIC-CS5阴离子交换柱,以5.0 mmol/L碳酸钠和1.0 mmol/L碳酸氢钠的混合溶液作为流动相,电导检测器在20 min内完成镀液中六价铬的测定.该法具有良好的线性(相关系数约为0.996)和重复性(相对标准偏差小于5％),回收率在93％ ～107％的范围内.     

PAN/FPU Composite Nanofiber Membrane with Superhydrophobic and Superoleophobic Surface as a Filter Element for High-Efficiency Protective Masks

Recently, because of the outbreak of COVID-19, the demand for various types of filter elements in protective materials has increased globally. Furthermore, new requirements for the filtration performance of PM2.5 liquid (oil) particles have been put forward. In this work, Superhydrophobic and superoleophobic composite nanofibers with excellent filtration capacity for oil and salt particles are developed through the modification of polyacrylonitrile (PAN) by fluoro-polyurethane (FPU) doping. The results show that the PAN/FPU composite nanofibers doped with 9 wt% FPU has a uniform fiber morphology with a diameter of 240 ± 30 nm. Compared to the pure PAN nanofibers, the water-based contact angle of PAN/FPU increases from 90 ± 5° to 151 ± 5°, and the oil-based contact angle increases from 58 ± 2° to 152 ± 3°. Importantly, at a high flow rate of 95 L min⁻¹, the filtration efficiency of the PAN/FPU nanofiber membrane for 0.3 µm oil particles increases from 92 ± 1% to 99.2 ± 0.1%. After cyclic loading, the filtration efficiency of 0.3 µm oil particles remains above 98%. Meanwhile, the filtration efficiency for 0.3 µm salt particles remains at 98.23 ± 0.1%. The PAN/FPU nanofiber membrane developed in this work is effective in applications and has good market prospects as a protective filtration material.