Epoxy-functional spontaneous gradient copolymers of glycidyl methacrylate (G) and n-butyl acrylate (B) were synthesized via atom transfer radical polymerization (ATRP). The copolymerization reactions were carried out in toluene solution at 70 °C, using methyl 2-bromopropionate (MBrP) as initiator and copper chloride with N,N,N′,N′′,N′′-pentamethyldiethylenetriamine (PMDETA) as the catalyst system. The kinetic behaviour of the statistical copolymerizations was studied in a wide composition interval with molar fractions of G ranging from 0.10 to 0.75. The synthesized copolymers were characterized by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. 1H NMR was employed to determine the copolymer composition, demonstrating the gradient character of the copolymers along the main chain in the whole monomer conversion interval. Apart from this, the sequence distribution and stereoregularity were analyzed. These microstructural experimental data agreed well with those calculated from Mayo-Lewis terminal model (MLTM) and a Bernoullian statistic with an isotacticity parameter of σG = 0.28 and a coisotacticity parameter of σ = 0.30. 相似文献
This letter presents a novel approach for organizing computational resources into groups within H.264/AVC motion estimation architectures, leading to reductions of up to 75% in the equivalent gate count with respect to state‐of‐the‐art designs. 相似文献
Home storage is the final step of the frozen foods distribution chain, and little is known on how it affects the products quality. The present research describes frozen green beans (Phaseolus vulgaris, L.) quality retention profile during the recommended ‘star marking’ system dates, at the storage temperatures of +5, −6, −12 and −18 °C (along 1, 4, 14 and 60 days, respectively).
The quality profile was assessed by a simulation system. Simulations were set by a response surface methodology to access the effect of different packaging materials (thermal conductivities and thickness), surface heat transfer coefficient, and refrigerator dynamics (effect of refrigeration cycles at the different storage temperatures) on the average retentions of Ascorbic Acid, total vitamin C, colour and flavour.
Green beans quality losses along frozen storage are significantly influenced by temperature, refrigerator dynamics and kinetic properties. Quality is also highly dependent on packaging materials thermal insulation (e.g. at temperatures above the melting point). Temperature cycles inside frozen chambers have a long term effect, and at the higher storage temperatures (e.g. T>−6 °C) are detrimental to frozen green beans quality after shorter periods. 相似文献
Time series solutions for spectral analysis in missing data problems use reconstruction of the missing data, or a maximum likelihood approach that analyzes only the available measured data. Maximum likelihood estimation yields the most accurate spectra. An approximate maximum likelihood algorithm is presented that uses only previous observations falling in a finite interval to compute the likelihood, instead of all previous observations. The resulting nonlinear estimation algorithm requires no user-provided initial solution, is suited for order selection, and can give very accurate spectra even if less than 10% of the data remains. 相似文献
The cost of order selection is defined as the loss in model quality due to selection. It is the difference between the quality of the best of all available candidate models that have been estimated from a finite sample of N observations and the quality of the model that is actually selected. The order selection criterion itself has an influence on the cost because of the penalty factor for each additionally selected parameter. Also, the number of competitive candidate models for the selection is important. The number of candidates is, of itself, small for the nested and hierarchical autoregressive/moving average (ARMA) models. However, intentionally reducing the number of selection candidates can be beneficial in combined ARMA(p,q) models, where two separate model orders are involved: the AR order p and the MA order q. The selection cost can be diminished by creating a nested sequence of ARMA(r,r-1) models. Moreover, not evaluating every combination (p,q) of the orders considerably reduces the required computation time. The disadvantage may be that the true ARMA(p,q) model is no longer among the nested candidate models. However, in finite samples, this disadvantage is largely compensated for by the reduction in the cost of order selection by considering fewer candidates. Thus, the quality of the selected model remains acceptable with only hierarchically nested ARMA(r,r-1) models as candidates. 相似文献
The present studies demonstrated the moderation of self-construal orientation on mimicry. Recent research has indicated that an interdependent self-construal is associated with assimilation of the other to the self whereas an independent self-construal is associated with minimizing the influence of others on the self (H. R. Markus & S. Kitayama, 1991; D. Stapel & W. Koomen, 2001). Therefore, the authors hypothesized that an interdependent self-construal would be associated with more mimicry than an independent self-construal. When self-construal orientations were experimentally primed. as in Studies 1 and 2, independent self-construals produced less nonconscious mimicry than interdependent self-construals. When self-construals were examined as cultural differences with either a chronically dominant independent (Americans) or interdependent (Japanese) construal of the self, these results were replicated. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
A new model for the critical shear stress and the transport of graded sediment is presented. The model is based on the size distribution of the bed surface and can be used to compute sediment transport rates in numerical simulations with an active layer model. This model makes a distinction between unimodal and bimodal sediments. It is assumed that all size fractions of unimodal sediments have the same critical shear stress while there is selective transport for the gravel fractions of bimodal sediments. A recently published laboratory transport data set is used to calibrate our model. 相似文献
BACKGROUND: Hypertension and hypercholesterolemia are frequently associated with this leading to considerable cardiovascular risk. METHODS: An open parallel randomized study was performed in which the effects of doxazosin, an alpha-adrenergic blocker and enalapril, an inhibitor of the angiotensin converting enzyme were compared in 70 patients with essential high blood pressure and plasma cholesterol levels greater than 240 mg/dl. Following 2-4 weeks of placebo administration the patients were randomly treated with one of the two drugs. When required doses were increased and hydrochlorothiazide added until blood pressure lower than 160/95 mmHg was achieved. After this period the patients were observed for a minimum of 8 weeks. The mean length of the study was of 22 weeks. RESULTS: Both drugs significantly reduced blood pressure without modifying cardiac frequency. Doxazosin tended to favorably modify the lipid profile of the plasma while enalapril significantly reduced the levels of cholesterol, lipids and high density lipoproteins (HDL). Upon termination of the study the total HDL/cholesterol index increased 8.6% in those treated with doxazosin and decreased 5.5% in those receiving enalapril (p < 0.05). CONCLUSIONS: Although doxazosin and enalapril are potent antihypertensive drugs, the effects on plasma lipid obtained with doxazosin indicate that a reduction in cardiovascular risk was achieved with this drug in the patients included in this study. 相似文献