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821.
Kauzlarić D Pastewka L Meyer H Heldele R Schulz M Weber O Piotter V Hausselt J Greiner A Korvink JG 《Philosophical transactions. Series A, Mathematical, physical, and engineering sciences》2011,369(1944):2320-2328
We present the application of the smoothed particle hydrodynamics (SPH) discretization scheme to Phillips' model for shear-induced particle migration in concentrated suspensions. This model provides an evolution equation for the scalar mean volume fraction of idealized spherical solid particles of equal diameter which is discretized by the SPH formalism. In order to obtain a discrete evolution equation with exact conservation properties we treat in fact the occupied volume of the solid particles as the degree of freedom for the fluid particles. We present simulation results in two- and three-dimensional channel flow. The two-dimensional results serve as a verification by a comparison to analytic solutions. The three-dimensional results are used for a comparison with experimental measurements obtained from computer tomography of injection moulded ceramic microparts. We observe the best agreement of measurements with snapshots of the transient simulation for a ratio D(c)/D(η)=0.1 of the two model parameters. 相似文献
822.
Nikolay Zotov Jürgen Feydt Alan Savan Alfred Ludwig Johannes von Borany 《Advanced Engineering Materials》2011,13(6):475-479
Thermal annealing of Fe/Pt multilayers (ML) is reported to reduce significantly the formation temperature of FePt hard magnetic thin films. The transformation mechanisms of [Fe 1.38 nm/Pt 2.24 nm]50 ML, prepared by magnetron sputtering, is investigated in the present communication by high temperature X‐ray reflectivity using synchrotron radiation. Complete degradation of the ML periodic structure is observed at about 610 K. The variation with annealing temperature of the intensity of the first Bragg peak, the correlated vertical roughness, and the lateral correlation length of the ML show that the ML transform in two stages with a cross‐over temperature of about 515 ± 15 K. This behavior cannot be simply explained by the change in the measured interdiffusion coefficient below and above the cross‐over temperature, suggesting the formation of FePt nanograins along the interfaces. 相似文献
823.
Roessl E Brendel B Engel KJ Schlomka JP Thran A Proksa R 《IEEE transactions on medical imaging》2011,30(9):1678-1690
The feasibility of K-edge imaging using energy-resolved, photon-counting transmission measurements in X-ray computed tomography (CT) has been demonstrated by simulations and experiments. The method is based on probing the discontinuities of the attenuation coefficient of heavy elements above and below the K-edge energy by using energy-sensitive, photon counting X-ray detectors. In this paper, we investigate the dependence of the sensitivity of K-edge imaging on the atomic number Z of the contrast material, on the object diameter D , on the spectral response of the X-ray detector and on the X-ray tube voltage. We assume a photon-counting detector equipped with six adjustable energy thresholds. Physical effects leading to a degradation of the energy resolution of the detector are taken into account using the concept of a spectral response function R(E,U) for which we assume four different models. As a validation of our analytical considerations and in order to investigate the influence of elliptically shaped phantoms, we provide CT simulations of an anthropomorphic Forbild-Abdomen phantom containing a gold-contrast agent. The dependence on the values of the energy thresholds is taken into account by optimizing the achievable signal-to-noise ratios (SNR) with respect to the threshold values. We find that for a given X-ray spectrum and object size the SNR in the heavy element's basis material image peaks for a certain atomic number Z. The dependence of the SNR in the high- Z basis-material image on the object diameter is the natural, exponential decrease with particularly deteriorating effects in the case where the attenuation from the object itself causes a total signal loss below the K-edge. The influence of the energy-response of the detector is very important. We observed that the optimal SNR values obtained with an ideal detector and with a CdTe pixel detector whose response, showing significant tailing, has been determined at a synchrotron differ by factors of about two to three. The potentially very important impact of scattered X-ray radiation and pulse pile-up occurring at high photon rates on the sensitivity of the technique is qualitatively discussed. 相似文献
824.
Finke Kathrin; Schwarzkopf Wolfgang; Müller Ulrich; Frodl Thomas; Müller Hermann J.; Schneider Werner X.; Engel Rolf R.; Riedel Michael; M?ller Hans-Jürgen; Hennig-Fast Kristina 《Canadian Metallurgical Quarterly》2011,120(4):890
Attention deficit hyperactivity disorder (ADHD) persists frequently into adulthood. The decomposition of endophenotypes by means of experimental neuro-cognitive assessment has the potential to improve diagnostic assessment, evaluation of treatment response, and disentanglement of genetic and environmental influences. We assessed four parameters of attentional capacity and selectivity derived from simple psychophysical tasks (verbal report of briefly presented letter displays) and based on a “theory of visual attention.” These parameters are mathematically independent, quantitative measures, and previous studies have shown that they are highly sensitive for subtle attention deficits. Potential reductions of attentional capacity, that is, of perceptual processing speed and working memory storage capacity, were assessed with a whole report paradigm. Furthermore, possible pathologies of attentional selectivity, that is, selection of task-relevant information and bias in the spatial distribution of attention, were measured with a partial report paradigm. A group of 30 unmedicated adult ADHD patients and a group of 30 demographically matched healthy controls were tested. ADHD patients showed significant reductions of working memory storage capacity of a moderate to large effect size. Perceptual processing speed, task-based, and spatial selection were unaffected. The results imply a working memory deficit as an important source of behavioral impairments. The theory of visual attention parameter working memory storage capacity might constitute a quantifiable and testable endophenotype of ADHD. (PsycINFO Database Record (c) 2011 APA, all rights reserved) 相似文献
825.
Wolfgang Krauss Julia Lorenz Nils Holstein Jürgen Konys 《Fusion Engineering and Design》2011,86(9-11):1607-1610
Tungsten is considered in fusion technology as functional and structural material in the area of blanket and divertor for future application in DEMO. The KIT design of a He-cooled divertor includes joints between W and W-alloys as well as of W with Eurofer-steel. The main challenges range from expansion mismatch problem for tungsten/steel joints over metallurgical reactions with brittle phase formation to crack stopping ability and excellent surface wetting. These requirements were only met partly and insufficiently in the past e.g. by direct Cu-casting of tungsten onto steel.Both, the joining needs and the observed failure scenarios of conventionally joined components initiated the development of improved joining technologies based on electro-chemical processing routes. As electrolytes aqueous and aprotic, water free, system are integrated into this development line. In the first step principle requirements are presented to guarantee a reproducible and adherent deposition of scales based on Ni and Cu acting as inter layers and filler, respectively, to generate a real metallurgical bonding as demonstrate by 1100 °C joining tests. The development field aprotic systems based on ionic liquids is discussed with respect to enable development of refractory metal based fillers with focus high temperature W–W brazing. 相似文献
826.
827.
Jens Glatthar Jürgen J Heinisch Thomas Senn 《Journal of the science of food and agriculture》2005,85(4):647-654
The applicability of three selected triticale cultivars (Trinidad, Lamberto, Fidelio) for use as brewing adjuncts was investigated in comparison with wheat adjunct and barley malt. Fermentable substance, crude protein and arabinoxylan levels of starchy materials were determined as well as their native potencies (amylolytic, proteolytic, pentosolytic) to solubilise and degrade grain components during mashing. Laboratory‐scale experiments were performed to evaluate the influence of the adjuncts (composition, enzyme potency) on beer wort quality by mashing mixed (1:1) grists of malt and adjunct. Barley malt was rated as the superior raw material, possessing considerably higher enzyme activities and yielding the lowest wort viscosity. Among the triticale cultivars cv Trinidad was identified as the most suitable to serve as a brewing adjunct due to its improved starch solubilisation properties and its ability to generate low wort viscosities. Compared with the potent malt enzymes, the enzyme activities of unmalted triticale (such as amylases, pentosanases and proteases) had little affect on the composition of the sweet worts. In contrast, the contents of crude protein and fermentable substance of the triticale varieties greatly affected wort quality. Furthermore, the adjunct moiety determined the level of wort viscosity when mashing a combination of malt and triticale. In general, the brewing properties of triticale cv Trinidad were comparable with those of wheat. Copyright © 2004 Society of Chemical Industry 相似文献
828.
Jürgen K. P. Weder Udo Scharf 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1981,172(3):185-189
Summary Fingerprinting (thin-layer electrophoresis/chromatography) after tryptic or chymotryptic digestion of performic acid-oxidized monomeric, dimeric, and oligomeric ribonuclease isolated from heated ribonuclease and monomeric unheated ribonuclease demonstrates one additional peptide in all heated samples. Preparative ion-exchange chromatography of the tryptic digests results in the corresponding number of fractions, 15 and 14, respectively. Amino acid analysis andN-terminal amino acid determination relate most of these peptides to theoretical tryptic peptides, whilst some are formed by further fragmentation due to chymotryptic activity of the commercial TPCK-trypsin used. This is also true of the additional peptide found in heated samples. So no distinct crosslinking peptide could be demonstrated. Only favoured participation of theN-terminal region in crosslinking is indicated. The observed differences between heated and unheated samples must be due to differences in three-dimensional structure leading to differences in susceptibility for proteolytic enzymes. Demonstration of both isopeptides, aspartyllysine and glutamyllysine, in three out of five fractions from digests of ribonuclease dimer, indicating six different isopeptide crosslinks, confirms the assumption of a very unspecific formation of crosslinks during protein heating.
We thank the Deutsche Forschungsgemeinschaft for supporting this work and Mrs. Anneliese Mödl and Mrs. Angelika Langwieser for performing the amino acid analyses 相似文献
Modelluntersuchungen über das Erhitzen von Lebensmittelproteinen —Oligomerisierung von Ribonuclease beim ErhitzenIII. Über die Lokalisierung säurelabiler Brückenpeptide
Zusammenfassung Durch zweidimensionale Dünnschichtelektrophorese/-chromatographie nach tryptischer oder chymotryptischer Spaltung perameisensäureoxidierter monomerer, dimerer und oligomerer Ribonuclease aus erhitzter Ribonuclease sowie monomerer unerhitzter Ribonuclease wurde ein zusätzliches Peptid in allen erhitzten Proben nachgewiesen. Durch präparative Ionenaustauscherchromatographie tryptischer Hydrolysate wurden dementsprechend 15 bzw. 14 Fraktionen erhalten. Durch Aminosäureanalyse und Bestimmung derN-terminalen Aminosäuren konnten die meisten Peptide theoretischen tryptischen Spaltpeptiden zugeordnet werden, während einige durch weitergehende Spaltung aufgrund chymotryptischer Nebenaktivitäten im verwendeten TPCK-Trypsinpräparat gebildet werden. Dies gilt auch für das in erhitzten Proben zusätzlich gefundene Peptid, so daß kein spezifisches Brückenpeptid nachgewiesen werden konnte. Lediglich eine bevorzugte Beteiligung desN-terminalen Bereiches an Quervernetzungsreaktionen ist erkennbar. Die beobachteten Unterschiede zwischen erhitzten und unerhitzten Proben beruhen auf unterschiedlicher räumlicher Anordnung, die zu Unterschieden in der Zugänglichkeit für proteolytische Enzyme führt. In drei von fünf untersuchten Fraktionen tryptisch gespaltener dimerer Ribonuclease konnten jeweils beide Isopeptide, Aspartyl-lysin und Glutamyl-lysin, also insgesamt sechs verschiedene Isopeptidbrücken nachgewiesen werden. Damit wird die Annahme einer sehr unspezifischen Brückenbildung während der Proteinerhitzung bestätigt.
We thank the Deutsche Forschungsgemeinschaft for supporting this work and Mrs. Anneliese Mödl and Mrs. Angelika Langwieser for performing the amino acid analyses 相似文献
829.
Jürgen Koch und Karl Figge 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1971,147(1):8-10
Zusammenfassung Das Ausmaß der Migration von Organozinnverbindungen aus PVC-Flaschen, die mit 1,13% Di-n-octylzinn-bis(thioglykolsäure-2-äthylhexylester) stabilisiert waren, in Bier wurde untersucht. Nach achtwöchiger Lagerung bei 20°C enthielt das Bier 0,0017 mg/l Zinn (entsprechend 0,01 mg/l des verwendeten Stabilisators) und lag damit weit unter dem von der American Food und Drug Administration gesetzten Limit von 1 mg/l Stabilisator (entsprechend 0,16 mg/l Zinn).
Migration of tin-stabilizers from PVC-bottles into beer
Summary The extent of migration of organotin compounds from PVC-bottles into beer was determined. Beer which had been stored at 20° C for 8 weeks in bottles stabilized with 1.13% di-n-octyltin-bis(2-ethyl hexyl thioglycolate) showed to contain 0.0017 mg/l of tin which equals 0.01 mg/l of the used stabilizer. This is far below the limit of 1 mg/l of stabilizer (0.16 mg/l of tin) permitted by the American Food and Drug Administration.相似文献
830.
Sabine?HeumannEmail author Horst?Ringe Jürgen?B?ttcher 《Nutrient Cycling in Agroecosystems》2011,91(3):339-350
Avoiding surplus N fertilization without reducing crop yields could be accomplished by accounting for current net N mineralization
in N fertilizer recommendations. N simulation models would allow a quantitative consideration of important factors and could
be based upon digitally mapped data. Soil-specific temperature and water functions that were derived in part I of the paper
needed a differentiation between only three soil groups and the two allocating criteria were taken from digital soil maps.
Here, the objectives were to experimentally determine pedotransfer functions (PTFs) for the pool sizes of two organic N pools
(Nfast, Nslow) that could be calculated via digitally available data and need a minimum set of easily accessible management data. Interestingly,
most important input data for the PTFs of both pool sizes were mean clay contents of the texture class (German soil classification
system). However, the underlying mechanisms might be different, as Nslow could be positively influenced by clay-associated mineralizable SOM, whereas Nfast could be positively related to clay content due to higher yield potential and thus more residues on finer-textured soils.
For Nslow including the humus class improved the accuracy of the PTF (r2 = 0.60; P < 0.050). For Nfast it was important to include a negative influence of the mean fall temperature of the preceding year (r2 = 0.42; P < 0.010), probably due to its influence on residue degradation before winter. Surprisingly, easily accessible management
data, e.g. previous crop, did not improve the predictions in this study. Field studies with plant cover will have to further
prove the applicability of the derived PTFs. 相似文献