基于交流电桥的电容式水分检测电路的设计

在已有的在线水分含量检测方法中,电容法优势最为明显,可靠性和精度都较高.基于交流电桥原理设计了一种电容式传感器检测电路,并结合水分检测的具体要求,完成了对硬件电路的制作与调试,并通过实验验证了电路的可行性.     

Microstructure and mechanical properties of Cr3C2 particulate reinforced Al2O3 matrix composites

Al₂O₃ matrix with three grades of Cr₃C₂ particle size (0.5, 1.5 and 7.5 m) composites were fabricated by a hot-pressing technique. Fully dense compacts with Cr₃C₂ content up to 40 vol % can be acquired at 1400 °C under 30 MPa pressure for 1 h. The flexural strength increases from 595 to 785 Mpa for fine Cr₃C₂ particle (0.5 m) reinforced Al₂O₃ matrix composites. The fracture strength is significantly dependent on the fracture modes of matrix (intergranular or transgranular). The transgranular fracture with a compressive residual stress gives a high fracture strength of composites. At the same time, the fracture toughness increases from 5.2 MPa m^1/2 (10 vol % Cr₃C₂) to 8.0 MPa m^1/2 (30 vol % Cr₃C₂) for the coarse Cr₃C₂ particle (7.5 n) reinforced Al₂O₃ matrix composites. The toughening effects of incorporating Cr₃C₂ particles into Al₂O₃ matrix originate from crack bridging and deflection. The electrical conductivity and the possibility of electrical discharge machining of these composites were also investigated.     

HVDC送端交流系统故障暂态过电压评估指标

特高压直流输电系统直流闭锁故障及交流系统短路故障引起的暂态过电压,对系统稳定性造成严重冲击。量化评估交直流系统暂态性能指标,对确定交直流电力系统规划设计和调度运行具有指导意义。对交流系统暂态过电压机理进行分析,推导出基于无功补偿和短路比的暂态过电压计算方法,基于系统短路比与补偿电容和交流滤波器参数的比值定义了暂态电压评估指标R_r。研究表明,随着该暂态电压评估指标R_r减小,系统故障后送端换流母线暂态电压升高,受端也会发生不同程度的换相失败。最后,基于国际大电网会议直流标准测试系统,验证了所提指标的有效性。     

计及线路传输能力的新能源电力系统灵活性评估及优化调度方法

新能源大规模接入电网对电力系统灵活调节能力带来巨大挑战,针对目前电力系统灵活性评估及优化调度集中于供需匹配而缺乏对线路传输能力的考虑,提出了计及线路传输能力的新能源电力系统灵活性评估及优化调度方法。首先,分析线路传输能力对灵活性需求实现的影响,并计及新能源及负荷的波动性和不确定性,量化节点灵活性需求及其在线路上的分配。然后,从资源灵活性裕量和线路灵活性传输裕量两个角度提出系统灵活性不足量评估指标,多方面评估系统灵活性。将该评估指标作为机会约束条件,构建考虑资源-线路双重裕量的优化调度模型。采用线性化手段和基于拉丁超立方抽样的机会约束确定性转化方法将优化调度模型化简为混合整数线性规划模型以降低求解难度。最后,采用改进IEEE39节点系统和某实际电网进行仿真验证,结果表明所提方法能够减轻线路阻塞,减少切负荷量,提高新能源消纳。     

Molecular Adsorption-Induced Interfacial Solvation Regulation to Stabilize Graphite Anode in Ethylene Carbonate-Free Electrolytes

Many organic solvents have excellent solution properties, but fail to serve as lithium-ion batteries (LIBs) electrolyte solvents, due to their electrochemical incompatibility with graphite anodes. Herein, a new strategy is proposed to address this issue by introducing a surface-adsorbed molecular layer to regulate the interfacial solvation structure without the alteration of electrolyte composition and properties. As a proof-of-concept study, it is demonstrated for the first time that the intrinsically incompatible propylene carbonate (PC)-based electrolyte becomes completely compatible with graphite anodes by introducing a layer of adsorbed hexafluorobenzene (HFB) molecules to weaken the Li⁺-PC coordination strength and facilitate the interfacial desolvation process. As a consequence, the graphite/ NCM811 pouch cells using the PC-based electrolyte containing only 1 vol.% HFB demonstrate excellent long-term cycling stabilities over 1150 cycles. This strategy is also proved to be applicable to other ethylene carbonate (EC)–free electrolytes, thus providing a new avenue for developing advanced LIB electrolytes.     

High Rate,Long Lifespan LiV3O8 Nanorods as a Cathode Material for Lithium‐Ion Batteries

LiV₃O₈ nanorods with controlled size are successfully synthesized using a nonionic triblock surfactant Pluronic‐F127 as the structure directing agent. X‐ray diffraction, scanning electron microscopy, and transmission electron microscopy techniques are used to characterize the samples. It is observed that the nanorods with a length of 4–8 µm and diameter of 0.5–1.0 µm distribute uniformly. The resultant LiV₃O₈ nanorods show much better performance as cathode materials in lithium‐ion batteries than normal LiV₃O₈ nanoparticles, which is associated with the their unique micro–nano‐like structure that can not only facilitate fast lithium ion transport, but also withstand erosion from electrolytes. The high discharge capacity (292.0 mAh g^?1 at 100 mA g^?1), high rate capability (138.4 mAh g^?1 at 6.4 A g^?1), and long lifespan (capacity retention of 80.5% after 500 cycles) suggest the potential use of LiV₃O₈ nanorods as alternative cathode materials for high‐power and long‐life lithium ion batteries. In particular, the synthetic strategy may open new routes toward the facile fabrication of nanostructured vanadium‐based compounds for energy storage applications.     

Walnut-inspired microsized porous silicon/graphene core–shell composites for high-performance lithium-ion battery anodes

Silicon is considered an exceptionally promising alternative to the most commonly used material, graphite, as an anode for next-generation lithium-ion batteries, as it has high energy density owing to its high theoretical capacity and abundant storage. Here, microsized walnut-like porous silicon/reduced graphene oxide (P-Si/rGO) core–shell composites are successfully prepared via in situ reduction followed by a dealloying process. The composites show specific capacities of more than 2,100 mAh·g^?1 at a current density of 1,000 mA·g^?1, 1,600 mAh·g^?1 at 2,000 mA·g^?1, 1,500 mAh·g^?1 at 3,000 mA·g^?1, 1,200 mAh·g^?1 at 4,000 mA·g^?1, and 950 mAh·g^?1 at 5,000 mA·g^?1, and maintain a value of 1,258 mAh·g^?1 after 300 cycles at a current density of 1,000 mA·g^?1. Their excellent rate performance and cycling stability can be attributed to the unique structural design: 1) The graphene shell dramatically improves the conductivity and stabilizes the solid–electrolyte interface layers; 2) the inner porous structure supplies sufficient space for silicon expansion; 3) the nanostructure of silicon can prevent the pulverization resulting from volume expansion stress. Notably, this in situ reduction method can be applied as a universal formula to coat graphene on almost all types of metals and alloys of various sizes, shapes, and compositions without adding any reagents to afford energy storage materials, graphene-based catalytic materials, graphene-enhanced composites, etc.

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Effects of Cu on Microstructures,Mechanical, and Magnetic Properties of Fe–Ni–P Alloys Fabricated by Liquid Phase Sintering

The Fe–Ni–P–Cu alloys with different copper content (0, 0.5, 1, and 2 wt%) are fabricated by liquid phase sintering (LPS) at 950 °C. The nano‐Cu powder is mechanically mixed for 90 min with Fe–Ni–P composite powder using the ethanol as the medium. The microstructure, microhardness and compressive properties of Fe–Ni–P–Cu alloys are investigated. The results indicate that the copper is beneficial to improve the mechanical properties of sintered specimens. The sample contains a small amount of γ‐(Fe, Ni) phase when the copper content is 1 wt%, which results in its the highest compressive yield strength (948.1 MPa). The highest microhardness of 371 HV is accessible in Fe–Ni–P–Cu alloy with 2 wt% Cu. The fracture surface analysis indicates that sintered specimens with Cu addition exhibit a typical intergranular mode.     

多元随机回归系数和参数的线性估计可容许的几个结果

在两种矩阵损失函数下讨论随机效应多元线性模型中回归系数和参数的线性估计的可容许性,并且在齐次和非齐次线性估计类中分别得到了可容许估计的充要条件。