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71.
综述了堆内辐照对锆合金电化学性能影响的概况,浅析了堆内辐照损伤的机理,并重点探讨了主要的堆内辐照源——中子辐照对锆合金微观结构与氧化性能的影响。进一步阐述了堆外离子轰击模拟堆内中子辐照研究方法的进展概况,并就离子轰击实验参量的选择进行了较为深入的分析。 相似文献
72.
73.
提出抑制锌硫首先脱除石墨,铜铅混选及分离,锌硫化先浮选方案,获得了铅、锌、硫三种精矿产品,选矿指标较为理想。合理的利用了井下酸性水,降低了选矿成本和对环境的污染。 相似文献
74.
塑料在包装领域有着广泛的应用,其中聚酯(PET)性能优良,应用领域不断扩大。介绍了塑料包装不断通现的新技术,以及塑料包装环保问题的几点思路。 相似文献
75.
Jinpeng Zhang Hongfeng Gao Nini Yuan Qiang Wang Yuhua Wu Yanli Sun Hongcun Bai 《中国化学工程学报》1982,28(11):2771-2777
Understanding and modulating the interaction between various reactive molecules and oxygen carriers are the key issue to achieve process intensification of chemical looping technology. C1 chemical molecules play an important role in many reactions involved with chemical looping processes. However, up to now, there is still a lack of systematic and in-depth understanding of the adsorption mechanism of C1 molecules on the surface of oxygen carriers (OCs). In this work, the intrinsic interaction between a series of C1 molecules composed of CH4, CO, CO2, CH3OH, HCHO and HCOOH and surface of NiO OCs in the chemical looping process have been studied using density functional theory calculations. Various adsorption configurations of C1 molecules and also different adsorption sites of NiO have been considered. The structural features of stable configuration of C1 molecules on the surface of NiO OCs have been obtained. Further, the interacted sites, types and strengths of C1 molecules on the surface of NiO have been directly pictured by the independent gradient model methods. Also, the nature of the interaction between C1 molecule and NiO surface has been investigated with the aid of energy decomposition analysis from a quantitative view. 相似文献
76.
Rapid Reactive Synthesis and Sintering of Submicron TiC/SiC Composites through Spark Plasma Sintering 总被引:1,自引:0,他引:1
Lianjun Wang Wan Jiang Lidong Chen Shengqiang Bai 《Journal of the American Ceramic Society》2004,87(6):1157-1160
Submicrometer TiC/SiC composites were fabricated by a rapid reactive sintering process through spark plasma sintering (SPS) technique using the carbon, titanium, and nanosized-SiC powders without any additive. It was found that the composite could be sintered in a relatively short time (8 min at 1480°C) to 97.9% of theoretical density. After sintering, the phase constituents and microstructures of the samples were analyzed by X-ray diffraction techniques and observed by scanning electron microscopy. The effect of nanosized and microsized SiC additives on the microstructure of TiC/SiC composites was investigated. 相似文献
77.
Sodium-ion battery (SIB) is an ideal device that could replace lithium-ion battery (LIB) in grid-scale energy storage system for power because of the low cost and rich reserve of raw material. The key challenge lies in developing electrode materials enabling reversible Na+ insertion/desertion and fast reaction kinetics. Herein, a core-shell structure, FeS2 nanoparticles encapsulated in biphase TiO2 shell (FeS2@TiO2), is developed towards the improvement of sodium storage. The diphase TiO2 coating supplies abundant anatase/rutile interface and oxygen vacancies which will enhance the charge transfer, and avoid severe volume variation of FeS2 caused by the Na+ insertion. The FeS2 core will deliver high theoretical capacity through its conversion reaction mechanism. Consequently, the FeS2@TiO2 nanorods display notable performance as anode for SIBs including long-term cycling performance (637.8 mA·h·g-1 at 0.2 A·g-1 after 300 cycles, 374.9 mA·h·g-1 at 5.0 A·g-1 after 600 cycles) and outstanding rate capability (222.2 mA·h·g-1 at 10 A·g-1). Furthermore, the synthesized FeS2@TiO2 demonstrates significant pseudocapacitive behavior which accounts for 90.7% of the Na+ storage, and efficiently boosts the rate capability. This work provides a new pathway to fabricate anode material with an optimized structure and crystal phase for SIBs. 相似文献
78.
In the process of Li+ intercalation-deintercalation, electron removal is accompanied simultaneously. Oxygen was found to compensate electron removal both in theoretical calculations and practical experiments. Chlorine addition to LiNi0.7Co0.3O2 was expected to exchange electrons in that Cl− was easier to lose electrons than O2−. LiNi0.7Co0.3O2−xClx was identified as a pure hexagonal lattice of α-NaFeO2 type by X-ray diffraction. X-ray photoelectron spectroscopy was used to analyze the influence of chlorine substitution on the oxidation state of transition-metal ions. Charge-discharge experiments and cyclic voltammetry confirmed that chlorine addition was an effective way to improve reversible capacity and structural stability in cycles. 相似文献
79.
The precise forecasting of water consumption is the basis in water resources planning and management. However, predicting water consumption fluctuations is complicated, given their non-stationary and non-linear characteristics. In this paper, a multiple random forests model, integrated wavelet transform and random forests regression (W-RFR), is proposed for the prediction of daily urban water consumption in southwest of China. Raw time series were first decomposed into low- and high-frequency parts with discrete wavelet transformation (DWT). The random forests regression (RFR) method was then used for prediction using each subseries. In the process, the input and output constructions of the RFR model were proposed for each subseries on the basis of the delay times and the embedding dimension of the attractor reconstruction computed by the C-C method, respectively. The forecasting values of each subseries were summarized as the final results. Four performance criteria, i.e., correlation coefficient (R), mean absolute percentage error (MAPE), normalized root mean square error (NRMSE) and threshold static (TS), were used to evaluate the forecasting capacity of the W-RFR. The results indicated that the W-RFR can capture the basic dynamics of the daily urban water consumption. The forecasted performance of the proposed approach was also compared with those of models, i.e., the RFR and forward feed neural network (FFNN) models. The results indicated that among the models, the precision of the predictions of the proposed model was greater, which is attributed to good feature extractions from the multi-scale perspective and favorable feature learning performance using the decision trees. 相似文献
80.
樊云峰 《现代塑料加工应用》1992,4(4):59-61
对邻苯二甲酸酯类增塑剂的国内外现状作了评述,并对我国提高DOP和高分子量邻苯二甲酸酯类增塑剂的比例、降低DBP的比例、开发高性能的复合增塑剂提出了积极的建议。 相似文献