Catalytic oxidation of naphthalene using a Pt/Al2O3 catalyst

Polycylic aromatic hydrocarbons (PAHs) are listed as carcinogenic and mutagenic priority pollutants, belonging to the environmental endocrine disrupters. Most PAHs in the environment stem from the atmospheric deposition and diesel emission. Consequently, the elimination of PAHs in the off-gases is one of the priority and emerging challenges. Catalytic oxidation has been widely used in the destruction of organic compounds due to its high efficiency (or conversion of reactants), its economic benefits and good applicability.

This study investigates the application of the catalytic oxidation using Pt/γ-Al₂O₃ catalysts to decompose PAHs and taking naphthalene (the simplest and least toxic PAH) as a target compound. It studies the relationships between conversion, operating parameters and relevant factors such as treatment temperatures, catalyst sizes and space velocities. Also, a related reaction kinetic expression is proposed to provide a simplified expression of the relevant kinetic parameters.

The results indicate that the Pt/γ-Al₂O₃ catalyst used accelerates the reaction rate of the decomposition of naphthalene and decreases the reaction temperature. A high conversion (over 95%) can be achieved at a moderate reaction temperature of 480 K and space velocity below 35,000 h⁻¹. Non-catalytic (thermal) oxidation achieves the same conversion at a temperature beyond 1000 K. The results also indicate that Rideal–Eley mechanism and Arrhenius equation can be reasonably applied to describe the data by using the pseudo-first-order reaction kinetic equation with activation energy of 149.97 kJ/mol and frequency factor equal to 3.26 × 10¹⁷ s⁻¹.     

Identification of the minimum effective dose for right-censored survival data

In this paper, we consider identifying the minimum effective dose (MED) in a dose-response study when survival data are subject to random right-censorship, where the MED is defined to be the smallest dose level under study that has survival advantage over the zero-dose control. To this end, we suggest single-step-down testing procedures based on three different types of weighted logrank statistics, respectively. The comparative results of a Monte Carlo error rate and power/bias study for a variety of survival and censoring distributions are then presented and discussed. The application of the testing procedures for identifying the MED is finally illustrated by using a numerical example of prostate cancer data.     

Controlled Synthesis of Ag2S,Ag2Se,and Ag Nanofibers by Using a General Sacrificial Template and Their Application in Electronic Device Fabrication

Nanofiber bundles of Ag₂S, Ag₂Se, and Ag have been successfully synthesized by making use of Ag₂C₂O₄ template nanofiber bundles, utilizing both anion‐exchange and redox reactions. The obtained bundles were polycrystalline nanofibers composed of nanoparticles in which the precursor morphology was well‐preserved, indicating that Ag₂C₂O₄ nanofiber bundles acted as a general sacrificial template for the synthesis of silver‐based semiconductor and metal nanofibers. Dispersing media and transforming reactants were found to be key factors influencing the chemical transformation in the system. In particular, separate single‐crystalline Ag nanofibers were obtained via a nontemplate route when ascorbic acid was used as a relatively weak reductant. An electrical transfer and switching device was built with the obtained Ag₂S and Ag nanofiber bundles, utilizing the unique ion‐conductor nature of Ag₂S and revealing their potential applications in electronics.     

桉木硫酸盐浆不同漂白技术的评价

高白度漂白商品浆的白度已从通常的88%～90%提高到更高的水平,达到92%.这种高白度的要求导致了纸厂使用高价格光学漂白剂,以及过量使用这种添加剂的环境风险.     

Effect of Thickness of the p-AlGaN Electron Blocking Layer on the Improvement of ESD Characteristics in GaN-Based LEDs

The following letter presents a study regarding GaN-based light-emitting diodes (LEDs) with p-type AlGaN electron blocking layers (EBLs) of different thicknesses. The study revealed that the LEDs could endure higher electrostatic discharge (ESD) levels as the thickness of the AlGaN EBL increased. The observed improvement in the ESD endurance ability could be attributed to the fact that the thickened p-AlGaN EBL may partly fill the dislocation-related pits that occur on the surface of the InGaN-GaN multiple-quantum well (MQW) and that are due to the strain and the low-temperature-growth process. If these dislocation-related pits are not partly suppressed, they will eventually result in numerous surface pits associated with threading dislocations that intersect the InGaN-GaN (MQW), thereby reducing the ESD endurance ability. The results of the experiment show that the ESD endurance voltages could increase from 1500 to 6000 V when the thickness of the p-AlGaN EBL in the GaN LEDs is increased from 32.5 to 130 nm, while the forward voltages and light output powers remained almost the same.     

烧结成品运输自动控制系统的改进

对烧结成品运输自控系统不稳定性因素进行了分析，提出了采取优化硬件外围工作环境，完善软件保护程序等改进措施。改进后的自控系统稳定性明显提高。     

Technology for testing nondeterministic client/server database applications

The execution of a client/server application involving database access requires a sequence of database transaction events (or, T-events), called a transaction sequence (or, T-sequence). A client/server database application may have nondeterministic behavior in that multiple executions thereof with the same input may produce different T-sequences. We present a framework for testing all possible T-sequences of a client/server database application. We first show how to define a T-sequence in order to provide sufficient information to detect race conditions between T-events. Second, we design algorithms to change the outcomes of race conditions in order to derive race variants, which are prefixes of other T-sequences. Third, we develop a prefix-based replay technique for race variants derived from T-sequences. We prove that our framework can derive all the possible T-sequences in cases where every execution of the application terminates. A formal proof and an analysis of the proposed framework are given. We describe a prototype implementation of the framework and present experimental results obtained from it.     

Blends of nylon 6 with an ethylene-based multifunctional polymer. I. Rheology–structure relationships

An experimental study was conducted to investigate the rheological behavior of a heterogeneous polymer blend system consisting of nylon 6 and an ethylene-based multifunctional polymer (CXA 3101, DuPont Co.). For comparison purposes, we also investigated the rheological behavior of two additional blend systems, namely blends of nylon 6 with a chemically modified polyolefin (Plexar 3, Chemplex Co.) and blends of nylon 6 with ethylene–vinyl acetate copolymer (EVA). We have investigated the thermal and thermomechanical behavior of the blend systems, using differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). Also, we have attempted to identify the chemical structure of the functional groups present in the CXA 3101 and Plexar 3 resins, using infrared (IR) spectroscopy. This information has enabled us to interpret the observed rheological behavior. Furthermore, we have used both optical and scanning electron microscopies to investigate the state of dispersion of the constituent components in each of the blend systems. We have concluded that, during melt blending, chemical reactions have taken place between carboxyl or anhydride groups present in the CXA 3101 resin and the amino end groups of the nylon 6, forming a graft copolymer which then acted as an “interfacial agent.”     

Effect of deformation route on microstructural development in aluminum processed by equal channel angular extrusion

Aluminum has been deformed by equal channel angular extrusion (ECAE) to obtain submicron-grained structures under different deformation routes. The deformation routes were varied by rotating billets through 0, 90, and 180 deg between each extrusion pass, and were designated as route A, B_C, and C, respectively. Based on quantitative microstructural analysis, the effectiveness of the deformation route is shown to depend upon the different definition used. The order of effectiveness is (a) A > B_C > C for both 90 and 120 deg dies, in terms of the generation of high-angle grain boundaries (HAGBs); (b) B_C > C > A for both 90 and 120 deg dies, in terms of the formation of equiaxed shape of grains; and (c) B_C > A > C for 90 deg die and B_C ∼ A > C for 120 die, in terms of reducing grain size. It is suggested that the generation of HAGBs can be related to the accumulation of nonredundant strain, while the shape and orientation of grains may be linked to the shearing patterns of the deformation route.