α,β,γ,δ-四-(4-吡啶)卟啉分光光度法测定瓷餐具铜溶出量

本文提出用α，β，γ，δ-四-（4-吡啶）卟啉为显色剂，分光光度法测定瓷餐具铜的溶出量，该方法灵敏度高，选择性好，可以不经分离，直接对试样进行测定，操作简便，结果满意。     

SO_4~（2－）／ZrO_2固体超强酸的失活与再生

初步探索了ＳＯ_４~２－／ＺｒＯ２固体超强酸的失活机理．并着重研究了催化剂的两种再生方法：灼烧法和溶剂洗涤法。催化剂主要是因结焦而失活，高温灼烧能基本恢复催化剂原有活性．且再生效果与灼烧温度有关。溶剂洗涤法有一定的再生能力，但不显著．     

Contents Volume 10 (2003)

Volume Contents

Contents Volume 10 (2003)     

Study on polymerization of acrylonitrile with methylacrylate and itaconic acid in mixed solvent

Isothermal crystallization kinetics were investigated by differential scanning calorimetry (DSC) for poly(p-phenylene sulfide) (PPS) doped with amorphous carbon or crystalline graphite particles. Both types of carbon forms have been found to affect the crystallization behavior of PPS to different extents. The crystalline graphite particles have a more pronounced effect on the overall rate as well as mechanisms of PPS crystallization than do the amorphous carbon particles. Relative contributions and competition from crystallizations of two different crystals in the later-stage crystallization of PPS have been found to cause the phenomenon of deviation from linearity in the Avrami plots. A sequential crystallization model has been shown to describe well the crystallization behavior of the PPS doped with the particles. © 1995 John Wiley & Sons, Inc.     

Effects of hydrogen on the transition layers between diamond films and Zr, Hf substrates

Highly purified polycrystalline wafers of Zr and Hf were chosen as substrates for diamond deposition by means of the d.c. arc discharge plasma CVD method. Polycrystalline diamond films were formed on both substrates. Scanning electron microscopy and high resolution X-ray diffraction were used to investigate the surface morphology of the diamond films and the composition of the interface layers between the diamond films and substrates. The experiments showed that the transition layer between the diamond films and Zr substrates was ZrC, ZrH and ZrC_0.32H_1.2. For Hf substrates, in addition to HfC, it is supposed that there were also some hydrides or carbohydrides in the transition layer, because several X-ray reflections appeared which could not be assigned to Hf, HfC or diamond.     

电厂电气运行中常见故障分析及其应对措施探讨

为了保证电厂的生产效率,必须要分析电气的运行特征,确定电气故障发生的原因,综合考虑多方面因素,选择切实可行的措施解决问题。简要分析了电厂电气运行常见故障发生原因,并提出了相应的解决措施。     

混合物MH-81状态方程的研究——从无限稀释活度系数预测混合物汽液平衡

本文由无限稀释活度系数求取混合物MH-81状态方程的二元相互作用参数,预测了二元混合物的汽液平衡,获得了较满意的结果。     

Polymer miscibility in organic solvents and in plasticizers—a two-dimensional approach

From thermodynamic considerations based on associated solution models and from the Hansen's three-dimensional solubility parameter concept, it is found that the solvent power of an organic liquid for a given polymer can be characterized by two parameters, δ_h and χ_H, where δ_h is the hydrogen-bonding solubility parameter of the liquid, and χ_H is a term which takes account of the dispersion and polar interactions between the liquid and the polymer and of the effects due to temperature and molecular size of the liquid. It is also found that Hansen's solubility sphere for the polymer can be represented as a solubility circle in the proposed χ_H^?δ_h plane. The proposed approach is applied successfully to polymer–plasticizer systems.     

Model for the effects of water on the cationic UV-curing of cyclohexyl epoxides

The effect of relative humidity on the photoin-duced curing kinetics of cyclohexyl epoxide and epoxide/polyol coating formulations was investigated in real-time using FTIR spectroscopy. In total, five formulations were used in this study, including a cyclohexyl epoxide without polyol, and four with polyols. The polyol formulations were varied with respect to ratio of epoxide to polyol, and molar functionality of the hydroxyl group. The formulations were exposed to a maximum of seven different relative humidities (6, 16, 20, 30, 51, 62, 75 RH). The curing speed and overall conversion of the epoxy group passed through a maxima for all the formulations. The polyol had an effect on the hydrophilicity of the overall formulation. It was also found that water and polyols had a synergistic effect on the UV-curing kinetics, in effect lowering the relative humidity to achieve a maxima. A model for UV-curing mechanisms at low, medium, and high relative humidity was proposed for both systems with and without the polyols. Part of this work was done at the Polymers and Coatings Dept., North Dakota State University, Fargo, ND 58105. Presented at the 80th Annual Meeting of the Federation of Societies for Coatings Technology, Oct. 30–Nov. 1, 2002, in New Orelans, LA. Dept. of Polymer Engineering, Akron, OH 44325-0301.     

粉尘含碳球团还原方式及气氛对其还原挥发性能的影响

在1150℃和1250℃、0．1L／min和10L／min的气量下，对通人含不同CO2量的氮气影响粉尘含碳球团还原速度的实验研究表明：以滚动方式所造球团中，氧化物的还原完全以间接还原的方式进行，气氛中非还原气体流速（或流量）的增加对粉尘含碳球团氧化铁还原速度有显著的降低作用，但还原温度提高则对气量增加造成的氧化铁还原速度降低有显著的抵消作用．气氛对球团中锌的挥发速度影响很小，对铅的挥发速度几乎不产生影响．