Adsorption characteristics of hexadecyl ammonium with different numbers of carbon chains in montmorillonite and the structure of the prepared composites

Journal of Porous Materials - The dynamics and thermodynamics of adsorption of hexadecyl ammonium with different numbers of carbon chains in montmorillonite (Mt) with different layer charge density...     

Synthesis,characterization, and thermal properties of phosphorus‐containing,wholly aromatic thermotropic copolyesters

A series of phosphorus‐containing, wholly aromatic thermotropic copolyesters from acetylated 2‐(6‐oxide‐6H‐dibenz〈c,e〉〈1,2〉oxa phosphorin‐6‐yl)‐1,4‐dihydroxy phenylene, p‐acetoxybenzoic acid, terephthalic acid, and isophthalic acid were prepared by melting polycondensation. The structure and basic properties of the polymers, such as the glass‐transition temperature (T_g), melting temperature (T_m), thermal stability, crystallinity, and liquid crystallinity, were investigated with Fourier transform infrared, elemental analysis, differential scanning calorimetry (DSC), thermogravimetric analysis, wide‐angle X‐ray diffraction, and hot‐stage polarizing optical microscopy. The copolyesters had relatively high T_g values ranging from 183 to 192°C. The T_m values obtained from DSC curves for samples P‐20 and P‐25 were 290 and 287°C, respectively (where the number in the sample name indicates the molar fraction of the phosphorus‐containing monomer in the reactants). The initial flow temperatures of other samples observed with hot‐stage polarizing microscopy were 271–290°C. The 5% degradation temperatures in nitrogen ranged from 431 to 462°C, and the char yields at 640°C were 41–52%. All the copolyesters, except P‐40, were thermotropic and nematic. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1278–1284, 2002     

反相高效液相色谱法测定meso-四苯基卟啉钴的纯度

采用反相高效液相色谱法测定合成meso-四苯基卟啉钴的纯度;以甲醇乙腈二氯甲烷(体积比为55∶35∶10)为流动相,ShimpackCLCODS柱(150mm×6.0mmi.d,5μm)为分离柱,流速为1.5mL/min,检测波长420nm;meso四苯基卟啉钴的测定在1.0～10μg/mL时线性关系良好(相关系数r=0.9993),加标回收率为97.03%～101.42%,重复进样的相对标准偏差RSD为0.64%～2.92%(n=5)。方法的准确度高,精密度好,实际应用效果好。     

充气压力对充气工况载重斜交轮胎影响的有限元分析

进行了充气压力对充气工况载重斜交轮胎影响的有限元分析.结果表明,充气工况下,充气压力对斜交轮胎外形轮廓尺寸影响明显,其外直径、断面宽度均随充气压力的增大而增加;充气压力的大小对胎圈接触应力分布影响很小,但胎圈最大接触应力随充气压力的增加而增大.     

安全本质的再认识与当代安全问题

从现代科学的角度揭示和分析安全的本质含义。安全本质应该包括：一是预知、预测、分析危险；二是限制、控制、消除危险。当人们讲到危险的时候，实际上是在研究危险。安全的含义随着人类社会经济的发展而变化。当代事故的灾害性、社会性、突发性是由于事故过程的技术密集性和物质高能性引起的。本文从现代科学技术和社会经济发展的基本经济规律出发，分析当代事故的本质特性。     

加压下二氧化碳在二甲基甲酰胺中的溶解度研究

本文报道了二氧化碳在二甲基甲酰胺中的溶解度,实验温度分别为15、20、25、30、35、40、45℃,实验压力为207.21—1684.02kPa.并且提出一个考虑了过量熵的、用溶度参数表示的活度系数方程.     

Dynamic response of Ti3SiC2 under shock compression up to 112 GPa

Ti₃SiC₂ is of interest due to its unique dual nature reminiscent of both brittle ceramics and ductile metals at ambient conditions. In this work, plate-impact experiments have been performed to study the dynamic behavior of Ti₃SiC₂ under shock compression up to 112 GPa by using laser velocity interferometer and electric pin techniques. Hugoniot elastic limits (HEL), spall strength, and Hugoniot equations of state have been obtained based on measured particle velocity profiles and shock wave velocities. The ratio of spall strength to HEL for Ti₃SiC₂ is larger than brittle ceramics but smaller than metals. This result indicates that the dual nature of Ti₃SiC₂ remains at least up to 10 GPa. On the other hand, the linearity of the Hugoniot equation of state, $D=6.9\text{0}1(22)+1.153(53)u_{\text{p}}$, suggests that the initial structure of Ti₃SiC₂ should be stable up to 112 GPa, in contrast to the result reported by Jordan et al. [J. Appl. Phys., 93 (2003) 9639].     

Decentralized weighted control for a class of large‐scale systems with multi‐modes

In this paper, the control synthesis problem for a class of large‐scale systems with multi‐modes that are called large‐scale switched systems is addressed. By introducing the concept of decentralized switching signal and the relevant decentralized average dwell time, the asymptotic stability and weighted ?₂ gain performance are investigated. It should be noted that the decentralized switching covers general switching cases for large‐scale switched systems, namely, it admits both time‐dependent switching signal and arbitrary switching signal blended in the decentralized switching. Then, on the basis of the analysis results, the decentralized weighted control scheme including state feedback controller gains and switching signals is studied. Several design algorithms are proposed to meet different controller design problems. Finally, numerical examples are provided to illustrate theoretical findings within this paper. Copyright © 2013 John Wiley & Sons, Ltd.