油气润滑系统及其应用

介绍发油气润滑的原理、系统结构、特点及应用。推荐新建轧机及采用油脂润滑的轧机应采油气润滑。     

LiNbO3掺杂(Bi0.5Na0.5)TiO3-(Bi0.5K0.5)TiO3-BaTiO3无铅压电陶瓷的压电和铁电性能研究

用传统的固相反应法将LiNbO3(LN)加入(Bi0.5Na0.5)TiO3-(Bi0.5K0.5)TiO3-BaTiO3制得无铅压电陶瓷。研究了该复合体系的压电和铁电性能,着重研究加入LiNbO3对0.852BNT-0.110BKT-0.038BT这一组分的相结构和电性能影响。加LN形成的材料结构分析(XRD)表明,LiNbO3能完全固溶入钙钛矿结构。加入0.05LN导致弥散相变,材料由四方相和菱方相两相共存转变为伪立方相,电滞回线呈现顺电相的特征。加入0.02LN形成的四元系电性能最佳:压电常数d33=245pC/N,机电耦合系数kp=0.20,kt=0.495,室温介电常数εr=1502,剩余极化强度Pr=26μC/cm2。在此基础上,研究了复合LN对去极化温度Td的作用,结果表明,引入LN会降低这一体系的去极化温度。     

TC11及表面改性膜层在海水中的微动磨损研究

通过对TC11钛合金进行不同表面改性实验(微弧氧化、N+离子注入、DLC多层膜),得到不同表面改性膜层。利用扫描电子显微镜(SEM),X射线衍射(XRD)和Raman光谱研究表面改性层的相组成和微结构。在模拟海水环境下,采用SRV-IV微动磨损试验机评价TC11合金及不同表面改性膜层的微动磨损性能(摩擦系数、磨损量及磨损机制),并比较抗微动防护效果。结果表明,TC11经改性后摩擦系数呈现不同程度下降,磨损量的降低则非常明显,其中DLC多层膜抗微动防护效果最显著。海水介质中各摩擦系数显著比纯水中低。海水中钛合金的磨损量小于纯水中的数值,腐蚀与磨损呈"负交互作用"规律,而改性层磨损较纯水中略高。     

化学共沉淀法制备NiCuZn铁氧体及其性能研究

利用化学共沉淀法制备了NiCuZn铁氧体微粉,研究了反应温度、搅拌速率和盐溶液流速对前驱体粒径的影响。通过XRD、TEM、激光粒度仪（LPS）、精密阻抗分析仪、振动样品磁强计(VSM)等手段对最优条件下得到的样品进行表征。结果表明：当反应温度为70 ℃,盐溶液的流速为0.5 mL/min,搅拌速率为300 r/min时得到尖晶石相的粉体,粒度约为30 nm。将微粉体在500 ℃预烧,在900 ℃烧结后得到样品的相对密度为98%,起始磁导率μi约为200,品质因数Q约为150。截止频率约为70 MHZ     

Effect of graphite intercalation compounds in the interfacial zone on the mechanical and thermal properties of unidirectional carbon fiber reinforced spodumene composite

The interface in unidirectional carbon-fiber-reinforced β-spodumene matrix composite (UD-Cf/β-spodumene) significantly affected the thermal conductivity characteristics and mechanical properties due to the presence of a multi-layer interface. The mechanical and thermal properties of UD-Cf/β-spodumene composites with and without a multi-layer interface have been studied. The measured thermal conductivities, flexural strength and fracture toughness of composites with a multi-layer interface were much better than those composites with a clear interface. Interfacial layers with a multi-layer morphology originated from the diffusion of lithium from the β-spodumene matrix to the surface of the carbon fiber, which led to the formation of graphite intercalation compounds. The mechanical properties and thermal conductivity of UD-Cf/β-spodumene hot pressed at 1350 and 1400 °C were enhanced due to the textured interfacial microstructure and high thermal conductivity of graphite intercalation compounds. The textured interface decomposed at 1450 °C, resulting in the formation of a “strong” interface. Inevitably, the mechanical properties and thermal conductivity decreased.     

SPS烧结W-10Ti合金的组织和性能

采用放电等离子烧结(SPS)技术制备了W-10Ti合金。通过扫描电镜和能谱分析了合金的微观组织,利用Den Broeder方法计算了合金的互扩散系数,测试了合金的密度和显微硬度,并与真空烧结的合金进行了对比。结果表明:与真空烧结相比,SPS烧结的合金组织均匀,富钛相少且细小,W在富钛相中的固溶度和Ti在富钨相中的固溶度都有所增加,且Ti在富钨相中的固溶度增加得更多。W-Ti合金的互扩散系数与W的摩尔浓度有一定的依赖关系,随着W摩尔浓度的升高呈先减小后增大趋势,SPS烧结的合金互扩散系数比真空烧结高出2个数量级。SPS法制备的W-Ti合金相对密度为96.1%,显微硬度HV0.05为5.21 GPa。     

BGA焊点界面化合物纳米压痕力学行为

利用纳米压痕法对BGA焊点(Cu,Ni)₆Sn₅,Cu₆Sn₅,Cu₃Sn界面化合物(IMC)进行了压痕试验.基于Oliver-Pharr法确定了(Cu,Ni)₆Sn₅,Cu₆Sn₅,Cu₃Sn的弹性模量和压痕硬度,研究了加载速率对IMC纳米压痕力学行为的影响及其变化规律.结果表明,锯齿流变效应与加载速率的大小是相关的.在加载速率较小的情况下(Cu,Ni)₆Sn₅,Cu₆Sn₅,Cu₃Sn都具有锯齿流变效应,但程度不同;在加载速率较大的情况下(Cu,Ni)₆Sn₅,Cu₃Sn锯齿流变效应不明显,而Cu₆Sn₅的锯齿流变效应相对明显.(Cu,Ni)₆Sn₅,Cu₆Sn₅,Cu₃Sn界面IMC的弹性模量分别为126,118,135 GPa;压痕硬度分别为6.5,6.3,5.8 GPa;含镍的(Cu,Ni)₆Sn₅化合物弹性模量和压痕硬度均比Cu₆Sn₅的值要高.     

Al_(0.5)CrCoFeNi高熵合金高温氧化的研究

采用真空电弧炉在氩气保护下熔炼Al0.5Cr Co Fe Ni高熵合金,在不同温度(800~1100℃)下进行100 h的高温氧化实验,测定其氧化动力曲线,采用X射线衍射仪和扫描电镜等方法分析氧化层结构和形貌。结果表明:Al0.5Cr Co Fe Ni高熵合金在800和900℃形成的氧化膜较完整且致密,具有较为优异的抗氧化性能。在1000和1100℃形成的氧化膜较厚,膜内有大量裂纹与孔洞,抗氧化性能较差。氧化初期,界面反应起主导作用,随着氧化膜的生长,扩散过程发挥越来越重要的作用,成为继续氧化的控制因素,以致一种或多种合金元素氧化物在表面析出,形成尖晶石类内层氧化物Ni Cr2O4、Co Cr2O4、Fe(Cr,Al)2O4内氧化层。在高温氧化过程中,N2会参与反应,与Al发生较强反应,生成Al N颗粒,进一步的氧化过程使Al N再次氧化,N2逃逸,留下具有Al N外形的空洞。     

Inclusion behavior and microstructure of weld metal with Ce in twin wire high heat input submerged-arc welding

In this study,the welding thermal cycle curve exhibited two temperature peaks in high heat-input twin-wire separate-pool submerged-arc welding and coarse-grained heat affected zone existed in the welded joint. The inclusions of primary weld metal and coarse-grained heat affected zone of Ce-added SAW should be Al_2O_3,MnO,SiO_2,TiO,Ce_2S_3,CeS,Ce_2O_2S and Ce_2O_3. Under the effect of welding thermal cycle,oxy-sulfides inclusions of Ce,the diameter of which was less than 2. 0 μm,slightly grew larger,but the composition and type of the inclusions didn't change. The microstructure of the large heat input weld metal had acicular ferrite that Ce oxide sulphide particles induced nucleation and proeutectoid ferrite. In the coarse-grained heat affected zone of weld metal,home-position precipitation of acicular ferrite and sympathetic acicular ferrite were both observed. It was supposed that previous crystal cells of acicular ferrite in austenite grain promoted home-position precipitation of acicular ferrite. Meanwhile,sympathetic acicular ferrite tended to nucleate at the primary acicular ferrite grain boundaries,where high dislocation density was located,and grew inside the neighboring carbon-depleted austenitic regions. The granular bainite nucleated in the austenitic zone with high carbon content close to acicular ferrite and sympathetic acicular ferrite.     

Cr18Ni30Mo2Al3Nb合金的高温抗氧化性能

采用称重法测得Cr18Ni30Mo2Al3Nb合金在不同温度下的高温氧化动力学曲线。结果表明,该合金的氧化曲线遵循抛物线氧化规律,具有优良的抗氧化性能。利用扫描电镜、X射线衍射的方法对氧化膜表面形貌及结构进行研究,该合金在3个温度下氧化膜完整致密,700℃氧化膜主要由Fe和Cr的混合氧化物(Fe0.6Cr0.4)2O3和少量Al的氧化物组成;800℃氧化膜主要是Al和Cr的混合氧化物(Al0.9Cr0.1)2O3和少量Al2O3及少量Fe的氧化物;900℃氧化膜主要是(Al0.9Cr0.1)2O3和Al的氧化物,还含有少量Fe(Cr,Al)2O4和MnFe2O4。