High catalytic activity of PdOx/MnO2 for CO oxidation and importance of oxidation state of Mn

PdO_x/MnO₂ has been examined as a catalyst for CO oxidation using a conventional flow reactor at reaction temperatures between 50 and 150°C. In the reaction conditions of GHSV (gashourlyspacevelocity) of 1.22 × 10⁵/h and CO concentration of 2000 ppm, PdO_x/MnO₂ showed higher catalytic activity compared with PdO_x/Mn₂O₃, which had been previously reported as an effective catalyst due to the cooperative action of Pd and Mn₂O₃ for this reaction. The reason for higher activity of PdO_x/MnO₂ than PdO_x/Mn₂O₃ has been investigated using TPR (temperatureprogrammed reduction) and XPS studies. TPR showed that PdO_x/MnO₂ could be reduced by CO at much lower temperature than PdO_x/Mn₂O₃. During the experiment of reduction and oxidation, XPS showed that the valence of Mn in the PdO_x/MnO₂ was between 4+ and 3+, which is higher than that of Mn in the PdO_x/Mn₂O₃ catalyst of which the valence has been reported to be between 3+ and 2+. It is known that in this catalyst system the support supplies oxygen onto Pd, where the oxidation occurs with adsorbed CO, and the ability of the support to provide oxygen improves the performance of the catalyst. Therefore, it was concluded that the readiness of MnO₂ to be reduced with maintaining a higher oxidation state showed higher CO oxidation activity than Mn₂O₃ as support for PdO_x.     

Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

火焰原子吸收光谱法测定硅粉中的铜

介绍了用火焰原子吸收法测定工业硅粉中微量铜的具体方法和过程，同时也给出了最佳实验条件。实验中采用新的样品处理方法，得到了令人满意的结果。其中样品回收率为99．8％—104．0%，相对标准偏差为0．31％—0.38％。本方法在实际应用过程中，简单、快速、     

钛酸铝材料性能及合成工艺

着重介绍了钛酸铝（Al2TiO3）陶瓷的结构、性能和合成工艺，并对今后发展趋势提出了基本观点。     

AADL 测试模型的构造研究

目前,结构分析和设计语言AADL在任务关键嵌入式系统领域有着良好的应用.为了保障任务关键软件的质量,文章提出基于AADL测试模型对AADL设计模型进行测试,以发现设计模型中存在的错误.研究给出了体现系统拓扑结构的AADL测试模型的形式定义及由AADL构造该测试模型的算法,基于该测试模型可以对AADL设计模型中构件交互的输入、输出端口序列和连接的正确性进行测试,并以飞行控制系统的AADL设计模型为例,阐释了研究成果.     

Non-Fourier heat conduction in a thin gold film heated by an ultra-fast-laser

Based on the dual-phase-lagging(DPL)heat conduction model,the Cattaneo-Vernotte(CV)model and the improved CV model we investigate the one-dimensional heat conduction in gold films with nano-scale thickness exposed to an ultra-fast laser heating.The influence of system parameters on the temperature field is explored.We find that for all the non-Fourier heat conduction models considered in this work,a larger Knudsen number normally leads to a higher temperature.For the DPL model,the large ratio of the phase lag of temperature gradient to the phase lag of heat flux reduces the maximum temperature and shortens the time for the system to reach its steady state.The CV model and the improved CV model lead to the similar thermal wave behavior of the temperature field,but the thermal wave speeds for these two models are different,especially for large Knudsen numbers.When the phase lag of temperature gradient is smaller,the difference between the DPL model and the improved CV model is not significant,but for the large phase lag of temperature gradient the difference becomes quite significant,especially for the large Knudsen number.In addition,the effect of the surface accommodation coefficient,which is a parameter in the slip boundary condition,on the temperature field of the gold film heated by ultra-fast laser pulses is investigated based on the DPL model.     

双回转送进二辊冷轧管机凸轮设计研究

本文提出了双回转送进二辊冷轧管机凸轮理论轮廓曲线的新设计方法 ,其轮廓曲线加速度与跃度呈梯形 ,且跃度边界连续 ,给出了针对双回转送进二辊冷轧管机的两个过渡段具有等加速度和跃度的设计准则     

时效对接触线用Cu-Ag-Cr合金性能的影响

分析了固溶温度、时效及时效前冷变形量对Cu - 0 1 %Ag - 0 1 %Cr接触线用合金性能的影响 ,结果表明 :经 870℃固溶、 40 %～ 5 0 %冷变形及 480℃× 1 5h时效处理后 ,合金可获得良好的综合性能。     

Influencing factors on elastic-plastic deformation of multi-layered surfaces under sliding contact

Stress distribution in the gradient multi-layered surface under a sliding contact was investigated using finite element method(FEM). The main structure parameters of layered surface discussed are total layer thickness,layer number and elastic modulus ratio of layer to the substrate. A model of multi-layered surface contact with rough slider was studied. The effect of the surface structure parameters on the elastic-plastic deformation was analyzed.