Stability studies on methyl and ethyl fatty acid esters of sunflowerseed oil

Fatty acid esters, high in linoleic acid, were prepared and stored for long-term engine tests. Storage tests with these esters were undertaken to obtain more information on optimal storage requirements and general stability characteristics. Samples were kept at three temperature levels (20 C, 30 C and fluctuating around 50 C) for a 90-day period and were removed at regular intervals for chemical and physical analysis. The influence of air, temperature, light, TBHQ and contact with mild steel was evaluated by comparing the free fatty acid, peroxide, anisidine, ultraviolet absorption, viscosity and induction periods. A statistical model was used to evaluate the data and to reduce the large number of data points to comparable curves. Storage of esters in contact with air, especially at a temperature above 30 C, resulted in significant increases in peroxide, ultraviolet absorption, free fatty acid, viscosity and anisidine values. Exclusion of air retarded oxidation at all temperature levels. A direct relationship between viscosity increases and oxidation parameters was evident. Exposure to light caused a small increase in the oxidation parameters of esters stored at the highest temperature level. Addition of TBHQ prevented oxidation of samples stored under moderate conditions. Under unfavorable storage conditions the anti-oxidant was no longer effective. Mild steel had very little effect on the oxidation parameters. Only the anisidine values of samples stored at the highest temperature level were slightly increased. Methyl esters performed slightly better than ethyl esters during the storage test. The following practical guidelines for storage of fatty acid ester fuels are: (i) airtight containers should be used; (ii) the storage temperature should be <30 C; (iii) mild steel (rust free) containers may be used, and (iv) TBHQ has a beneficial effect on oxidation stability.     

连轧机用人字轮齿轴断裂失效分析

用宏观断口分析、化学检验、力学性能测定、低倍检查、金相组织及夹杂物评定鉴别、受力分析及强度寿命定量估算的方法，对人字轮被动齿轴端断裂失效原因进行分析，并提出改进措施。     

Implementation of secure digital communication by hyperchaoticsynchronisation

By active-passive-decomposition synchronisation, the application of the one-way coupled ring map lattice hyperchaotic system in secure digital speech communication is demonstrated. Synchronisation guarantees strong security and recovery without error     

NH_4Cl水溶液在成膜过程中的致孔作用

本文以ＮＨ４Ｃｌ饱和水溶液做添加剂，对ＰＶＤＦ／ＮＭＰ体系在成膜过程中的致孔作用做了研究。铸膜液中随ＮＨ４Ｃｌ水溶液加入量的改变，膜孔径也发生变化，并出现最大值。通过Ｘ－射线衍射扫描发现制膜液中存在无机盐时膜中无定形态结构增加，表明无机盐的加入有助于膜孔形成     

在柔性变焦系统中的压力变焦镜

从理论上和实验上对水冷镜的镜面曲率半径随压力变化的规律作了研究。对压力变形后镜面相对于球面作了波像差分析，分析表明压力变焦镜用于中红外激光系统是合适的     

Li2O在保护渣中的作用

采用在不同玻璃性的两种基渣中加入Ｌｉ２Ｏ为研究Ｌｉ２Ｏ对保护渣粘度，熔化温度及玻璃性能的影响，并对Ｌｉ２Ｏ改善保护渣玻璃性的机理进行了探讨，提出了寻找高速连铸保护渣中Ｌｉ２Ｏ的代用物的一种方法。     

落地煤量微机计算系统的开发与研究

本系统对现场观测的煤堆导线观测数值直接进行处理，算了出落地测量，减少了手工计算的中间环节，提高了煤量计算的精度和速度。     

基于STEP的零件加工工艺计划模型

为了满足ＣＩＭＳ环境下工艺系统与其它系统集成的需要，建立了标准工艺计划模型具十分重要的意义。本文描述了一个基于ＳＴＥＰ的零件加工工艺计划模型，介绍了建立这一模型的关键技术，给出了参照ＳＴＥＰ建立工艺计划模型的方法。     

MS—Windows3.1下应用程序间数据交换方法及其选用策略

本文分析讨论了在ＭＳ－Ｗｉｎｄｏｗｓ操作系统下的应用程序间的数据交换的概念及方法，并给出了这些方法的选用策略。这些方法包括裁剪板，动态数据交换（ＤＤＥ），对象的连接及嵌入（ＯＬＥ），动态连接库（ＤＬＬ）。