A facile synthesis of supported amorphous iron oxide with high performance for Cr(Ⅵ) removal from aqueous solution under visible light irradiation

A series of supported iron oxide nanoparticles were prepared by impregnation with Fe(NO_3)_3 supported on TiO_2,followed by low-temperature calcination. Scanning electron microscopy(SEM), X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), UV–vis diffuse reflectance spectra and BET have been used to characterize the samples. These iron oxide-impregnated TiO_2 were examined for photocatalytic reduction of Cr(Ⅵ). The experiments demonstrated that Cr(Ⅵ) in aqueous solution was more efficiently reduced using Fe_2O_3/TiO_2 heterogeneous photocatalysts than either pure Fe_2O_3 or TiO_2 under visible light irradiation. All TiO_2 supported samples were somewhat active for visible light photoreduction. With an optimal mole ratio of 0.05-Fe/Ti, the highest rate of Cr(Ⅵ) reduction was achieved under the experimental conditions. We also compared the photoreactivity of TiO_2 supported iron oxide samples with that supported on Al_2O_3 and ZrO_2. It can be noted that iron oxide nanoparticles deposited on high surface area supports to increase the solid-liquid contact area renders it considerably more active. Noticeably,iron oxide cluster size and dispersion are important parameters in synthesizing active, supported Iron oxide nanoparticles. In addition, the interaction between iron oxide and TiO_2 was proposed as the source of photoactivity for Cr(Ⅵ) reduction.     

Physics-Informed Multistage Machine Learning Strategy for the Nanomachining-Induced Plastic Deformation Behavior

The evolution of the dislocation density induced by the nanomachining process dominates the plastic deformation behaviors of materials, thus affecting the mechanical properties significantly. However, a challenging topic related to how to establish an accurate model for predicting the dislocation density based on the limited simulations and experiments arises due to the complicated thermal–mechanical coupling mechanism during the machining process. Herein, a multistage method integrating machine learning, physics, and high-throughput atomic simulation is proposed to investigate the effect of cutting speed on the dislocation behavior in polycrystal copper. Compared with the traditional one-step machine learning method, the constraint of physical features effectively improves the accuracy and generalization ability of the model. The results indicate that the dislocation behaviors depend on the competition between the cutting force and temperature. In the low-cutting speed, the predominated role of the cutting temperature leads to a rapid decline of the dislocation density. In contrast, the dislocation density tends to be stable under a high-speed cutting process due to the dynamic balance between the effects of the cutting force and temperature. Notably, the proposed strategy provides a new and universal framework to design the machining parameters to obtain high-quality products.     

Modified HSS iteration methods for a class of complex symmetric linear systems

In this paper, we introduce and analyze a modification of the Hermitian and skew-Hermitian splitting iteration method for solving a broad class of complex symmetric linear systems. We show that the modified Hermitian and skew-Hermitian splitting (MHSS) iteration method is unconditionally convergent. Each iteration of this method requires the solution of two linear systems with real symmetric positive definite coefficient matrices. These two systems can be solved inexactly. We consider acceleration of the MHSS iteration by Krylov subspace methods. Numerical experiments on a few model problems are used to illustrate the performance of the new method.     

一种安全有效的基于身份的门限签密方案

签密是一种将加密和数字签名技术结合在一起的思想,它比采用先签名后加密的方法具有更高的效率.基于双线性对技术,提出了一种新的基于身份的门限签密方案.它利用决策双线性Diffie-Hellman(DBDH)问题的困难性在随机预言模型下给出了方案的语义安全性证明,并利用计算Diffie-Hellman(CDH)问题的困难性证明了方案的不可伪造性,同时指出方案具有较高的效率.     

基于LDA模型的新闻话题的演化

新闻话题及演化的研究可以帮助人们快速了解和获取新闻内容。提出了一种挖掘新闻话题随时间变化的方法,通过话题抽取和话题关联实现话题的演化。首先应用LDA(Latent Dirichlet Allocation Model)对不同时间段的文集进行话题的自动抽取,话题数目在不同时间段是可变的;计算相邻时间段中任意两个话题的分布距离实现话题的关联。实验结果证明该方法不但可以描述同一个话题随时间的演化过程,还可以描述话题内容随时间的变化,反映了话题(或子话题)之间多对多的演化关系。     

基于DSDV的无线Mesh网络跨层路由设计

在DSDV协议的基础上,提出一种跨层路由设计的方法,选择一条具有合理长度和最小重传概率的路由进行测试。该链路质量机制可应用到基于IEEE802.11x的无线Mesh网络中,无须对现有的MAC层进行修改,即可作为一个单独模块加入到现有协议。在多跳网络中使用该跨层方案进行路由选择,能节省系统开销,优化系统的整体性能。     

Applying eco-visualisations of different interface formats to evoke sustainable behaviours towards household water saving

The shortage of water resources is a global issue. This study attempts to utilise eco-visualisation interface design to affect users’ water-usage behaviour. Three interface proposals were designed in this study: numeric, water droplet (abstract symbol), and swimming fish (animated image). These three different interface formats range from abstract to figurative and from neutral to affective. A total of 93 subjects were divided into three groups and randomly performed designated dishwashing tasks twice. One of the tasks was completed without the assistance of any interface, whereas the other involved applying one of the three interface formats with eco-visualisations. In this study, the Self-Assessment Manikin scales, the System Usability Scale, and the Questionnaires for User Interaction Satisfaction were used to measure the emotional dimensions and perceived usability and to record the differences in water usage volume. The results indicated that the emotional valence evoked by the animated image interface was significantly higher than that by the numeric interface. The effect of the numeric interface formats on the subjects focused on emotional arousal, whereas other interfaces emphasised emotional valence. With the aid of the eco-visualisations of interface design, the evoked emotional response and enhanced usability could help improve sustainable behaviours towards water saving.     

Visual topic discovering,tracking and summarization from social media streams

Multimedia Tools and Applications - Nowadays, microblogging has become popular, with hundreds of millions of short messages being posted and shared every minute on a variety of topics in social...     

Multi-objective and multi-case reliability-based design optimization for tailor rolled blank (TRB) structures

Structural and Multidisciplinary Optimization - Light weight and crashworthiness signify two main challenges facing in vehicle industry, which often conflict with each other. In order to achieve...