全文获取类型
收费全文 | 113209篇 |
免费 | 11135篇 |
国内免费 | 5587篇 |
专业分类
电工技术 | 8131篇 |
技术理论 | 15篇 |
综合类 | 8042篇 |
化学工业 | 18013篇 |
金属工艺 | 6669篇 |
机械仪表 | 7401篇 |
建筑科学 | 9030篇 |
矿业工程 | 3933篇 |
能源动力 | 3399篇 |
轻工业 | 6821篇 |
水利工程 | 2358篇 |
石油天然气 | 7025篇 |
武器工业 | 1218篇 |
无线电 | 12889篇 |
一般工业技术 | 12821篇 |
冶金工业 | 5070篇 |
原子能技术 | 1377篇 |
自动化技术 | 15719篇 |
出版年
2024年 | 478篇 |
2023年 | 2032篇 |
2022年 | 3905篇 |
2021年 | 5418篇 |
2020年 | 4084篇 |
2019年 | 3234篇 |
2018年 | 3710篇 |
2017年 | 4017篇 |
2016年 | 3664篇 |
2015年 | 5123篇 |
2014年 | 6187篇 |
2013年 | 7421篇 |
2012年 | 8061篇 |
2011年 | 8735篇 |
2010年 | 7394篇 |
2009年 | 6987篇 |
2008年 | 6921篇 |
2007年 | 6283篇 |
2006年 | 6145篇 |
2005年 | 5196篇 |
2004年 | 3398篇 |
2003年 | 2764篇 |
2002年 | 2518篇 |
2001年 | 2137篇 |
2000年 | 2203篇 |
1999年 | 2309篇 |
1998年 | 1798篇 |
1997年 | 1473篇 |
1996年 | 1394篇 |
1995年 | 1149篇 |
1994年 | 950篇 |
1993年 | 699篇 |
1992年 | 557篇 |
1991年 | 371篇 |
1990年 | 314篇 |
1989年 | 225篇 |
1988年 | 205篇 |
1987年 | 124篇 |
1986年 | 88篇 |
1985年 | 56篇 |
1984年 | 38篇 |
1983年 | 37篇 |
1982年 | 36篇 |
1981年 | 24篇 |
1980年 | 21篇 |
1979年 | 11篇 |
1976年 | 9篇 |
1975年 | 3篇 |
1959年 | 9篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
52.
Donghai Xu Peng Feng Yang Wang Wanpeng Yang Yu Wang Shaoyan Sun 《American Institute of Chemical Engineers》2022,68(2):e17472
Corrosion and salt deposition problems severely restrict the industrialization of supercritical water oxidation. Transpiring wall reactor can effectively weaken these two problems by a protective water film. In this work, methanol was selected as organic matter, and the influences of vital structural parameters on water film properties and organic matter removal were studied via numerical simulation. The results indicate that higher than 99% of methanol conversion could be obtained and hardly affected by transpiration water layer, transpiring wall porosity and inner diameter. Increasing layer and porosity reduced reactor center temperature, but inner diameter's influence was lower relatively. Water film temperature reduced but coverage rate raised as layer, porosity, and inner diameter increased. Notably, the whole reactor was in supercritical state and coverage rate was only approximately 85% in the case of one layer. Increasing reactor length affected slightly the volume of the upper supercritical zone but enlarged the subcritical zone. 相似文献
53.
The capture of particles by charged droplets was simulated by considering the electrostatic interactions of droplet-droplet and droplet-particle. The results indicate that the electrostatic repulsion between droplets leads to a dynamic accumulation mode of particles. However, the droplet spacing has an insignificant effect on the capture efficiency when the electrostatic deposition predominates. The increase of droplet charge remarkably improves the capture efficiency, in which the capture of fine particles accounts for the largest proportion. Compared to the droplet charge, the droplet size shows a limited improvement in the capture efficiency. Reducing the droplet velocity prolongs the capture time instead of enhancing the capture capacity per unit time, thereby improving capture efficiency. 相似文献
54.
For rechargeable wireless sensor networks, limited energy storage capacity, dynamic energy supply, low and dynamic duty cycles cause that it is unpractical to maintain a fixed routing path for packets delivery permanently from a source to destination in a distributed scenario. Therefore, before data delivery, a sensor has to update its waking schedule continuously and share them to its neighbors, which lead to high energy expenditure for reestablishing path links frequently and low efficiency of energy utilization for collecting packets. In this work, we propose the maximum data generation rate routing protocol based on data flow controlling technology. For a sensor, it does not share its waking schedule to its neighbors and cache any waking schedules of other sensors. Hence, the energy consumption for time synchronization, location information and waking schedule shared will be reduced significantly. The saving energy can be used for improving data collection rate. Simulation shows our scheme is efficient to improve packets generation rate in rechargeable wireless sensor networks. 相似文献
55.
Crystallographic characteristics and microwave dielectric properties of Ni-modified MgTa2O6 ceramics
Liang Shi Xueying Wang Rui Peng Gang Wang Cheng Liu Xiaolei Shi Dainan Zhang Huaiwu Zhang 《Ceramics International》2021,47(16):22514-22521
Ni2+ modified MgTa2O6 ceramics with a trirutile phase and space group P42/mnm were obtained. The correlations between crystallographic characteristics and microwave dielectric performance of MgTa2O6 ceramics were systematically studied based on the chemistry bond theory (PVL theory) for the first time. The results indicate that the introduction of Ni2+ causes a change in polarizability and the Mg–O bond ionicity, which contributes to the variation of dielectric constant. Moreover, the lattice energy, and packing fraction, full width at half maximum of the Raman peak of Ta–O bond, as the quantitative characterization of crystallographic parameters, regulate the dielectric loss of MgTa2O6 ceramics in GHz frequency band. In addition, the study of sintering behavior shows that the densification and micromorphology are the crucial factors affecting the microwave dielectric performance. Typically, Ni2+ doping on the A-site of MgTa2O6 can effectively promote the Q × f values to 173,000 GHz (at 7.43 GHz), which ensures its applicability in 5G communication technology. 相似文献
56.
Liang Shi Dainan Zhang Rui Peng Cheng Liu Xiaolei Shi Xueying Wang Huaiwu Zhang 《Journal of the European Ceramic Society》2021,41(11):5526-5530
Mg(1-x)ZnxTa2O6 (x = 0.00?0.08) dielectric ceramics were synthesized via the traditional solid-state reaction method. We used XRD and Rietveld refinement to demonstrate that a pure Mg(1-x)ZnxTa2O6 phase with trirutile structure was formed. Zn2+ substitution helped to decrease the Raman full width at half width of the A1g mode at 703 cm?1, which resulted in an increase in the order and rigidity of the TaO6 octahedron, this in turn contributed to improving the Q×f values. Additionally, the introduction of Zn2+ significantly promoted grain growth and increased the dense, and the molecular polarizability, these factors lead to a higher permittivity. Moreover, enhanced Ta-O bond energy resulted in a more stable TaO6 octahedron in the Mg(1?x)ZnxTa2O6 system, which contributed to enhanced τf values via substitution of Zn2+ doped on the A-site. Correspondingly, the microwave dielectric properties were significantly improved for 0.04-doped samples, obtaining: εr = 27, Q × f = 185,000 GHz (at 7.47 GHz), τf =32 ppm/°C. 相似文献
57.
As haze intensifies in China, controlling haze emission has become the country's top priority for environmental protection. Because haze moves across different regions, it is necessary to develop a data envelopment analysis (DEA) model underpinned by both competition and cooperation to evaluate the haze emission efficiency in different provinces. This study innovatively adopts the spatial econometrics to construct the co-opetition matrices of Chinese provinces, then builds the co-opetition DEA model to evaluate the haze emission efficiency of them, and finally uses the haze data of 2015 as an example to assess the applicability of the model. The results of the study include the following: First, compared with the traditional CCR (A. Charnes & W. W. Cooper & E. Rhodes) model, this study constructs the co-opetition DEA cross-efficiency model that integrates haze's feature of cross-border moving; thus, it is more in line with the reality of haze emission and movement. Second, compared with the efficiency value gained from the CCR model, the haze emission efficiency values for Tianjin and Guangdong, two decision-making units, register greater variance when using the DEA model. The reason might lie in that they have a different spatial transportation relationship with their surrounding provinces. Third, the haze emission efficiency of provinces, according to the evaluation based on the co-opetition DEA method, varies greatly: Those with high efficiency are mostly inland provinces with slow economic growth and adverse climatic conditions, whereas many of the provinces with low efficiency are located in the relatively prosperous East China. The specific co-opetition DEA model constructed in this study enriches the research on the DEA model, which can be applied to the emission efficiency evaluation of similar pollutants around the world and can contribute empirical support to the haze reducing efforts of the government with its empirical results. 相似文献
58.
Wei LingNan Wang ZhenHua Zhang ZhiDong Liu Chieh-Wen Gao Xuan P. A. 《Nano Research》2020,13(5):1332-1338
Nano Research - We report the composition and back-gate voltage tuned transport properties of ternary compound Bi2(Te1−xSex)3 nanowires synthesized by chemical vapor deposition (CVD). It is... 相似文献
59.
Yue Gao Miao-miao Zhang Xiao-peng Guo Wen-jian Li Dong Lu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2020,95(5):1290-1297
Toxicity caused by the accumulation of butanol in fermentation media is an important factor limiting the concentration of butanol. There is currently no systematic research in place investigating the butanol tolerance mechanism of bacteria such as Clostridium acetobutylicum, which adapts to butanol stress and regulates its growth and metabolism. Here, research results related to the butanol tolerance of C. acetobutylicum are reviewed to understand the molecular basis of changes in butanol-tolerant strains. Organic solvent-tolerant bacteria play an important role in the fields of biofuel production, enzyme preparation and bioremediation. An analysis of limitations of the application of organic solvent-tolerant bacteria has revealed that future research should focus on combining the microbial tolerance phenotype with specific utilization to achieve an optimal balance between organic solvent tolerance and production. This review serves as a reference for the improvement and engineering of strains that tolerate organic solvents. © 2019 Society of Chemical Industry 相似文献
60.