直纺长丝工艺中聚酯熔体端羧基值控制的工业研究

本文从工业生产的实践出发对杜邦聚酯技术直接纺工艺中端羧基控制进行了研究。通过对熔体端羧基值对无油长丝端羧基、粘度及纺丝加工影响的分析 ,阐明了聚酯端羧基控制范围 ;通过摸索三个反应釜工艺条件对端羧基值的影响 ,找出了端羧基工业控制的有效途径 ,为同类技术装置生产提供了依据     

Electrochemical performance of nanocrystalline Li3V2(PO4)3/carbon composite material synthesized by a novel sol–gel method

A novel sol–gel method based on V₂O₅·nH₂O hydro-gel was developed to synthesize nanocrystalline Li₃V₂(PO₄)₃/carbon composite material. In this route, V₂O₅·nH₂O hydro-gel, NH₄H₂PO₄, Li₂CO₃ and high-surface-area carbon were used as starting materials to prepare precursor, and the Li₃V₂(PO₄)₃/carbon was obtained by sintering precursor at 750 °C for 4 h in flowing argon. The sol–gel synthesis ensures homogeneity of the precursors and improved reactivity. The sample was characterized by XRD, SEM and TEM. X-ray diffraction results show Li₃V₂(PO₄)₃ sample is monoclinic structure with the space group of P2₁/n. The TEM image indicates that the Li₃V₂(PO₄)₃ particles modified by conductive carbon are about 70 nm in diameter. The Li₃V₂(PO₄)₃/carbon system showed that the discharge capacities in the first and 50th cycle are about 155.3 and 143.6 mAh/g, respectively, in the range of 3.0–4.8 V. The sol–gel method is fit for the preparation of Li₃V₂(PO₄)₃/carbon composite material which may offer some favorable properties for commercial application.     

Dynamic output feedback control of a flexible air-breathing hypersonic vehicle via T–S fuzzy approach

By utilising Takagi–Sugeno (T–S) fuzzy set approach, this paper addresses the robust H_∞ dynamic output feedback control for the non-linear longitudinal model of flexible air-breathing hypersonic vehicles (FAHVs). The flight control of FAHVs is highly challenging due to the unique dynamic characteristics, and the intricate couplings between the engine and fight dynamics and external disturbance. Because of the dynamics’ enormous complexity, currently, only the longitudinal dynamics models of FAHVs have been used for controller design. In this work, T–S fuzzy modelling technique is utilised to approach the non-linear dynamics of FAHVs, then a fuzzy model is developed for the output tracking problem of FAHVs. The fuzzy model contains parameter uncertainties and disturbance, which can approach the non-linear dynamics of FAHVs more exactly. The flexible models of FAHVs are difficult to measure because of the complex dynamics and the strong couplings, thus a full-order dynamic output feedback controller is designed for the fuzzy model. A robust H_∞ controller is designed for the obtained closed-loop system. By utilising the Lyapunov functional approach, sufficient solvability conditions for such controllers are established in terms of linear matrix inequalities. Finally, the effectiveness of the proposed T–S fuzzy dynamic output feedback control method is demonstrated by numerical simulations.     

加压下二氧化碳在二甲基甲酰胺中的溶解度研究

本文报道了二氧化碳在二甲基甲酰胺中的溶解度,实验温度分别为15、20、25、30、35、40、45℃,实验压力为207.21—1684.02kPa.并且提出一个考虑了过量熵的、用溶度参数表示的活度系数方程.     

涤纶短纤维生产现状及发展趋势

对目前国内外涤纶短纤维生产的企业规模和工艺技术现状进行了分析比较，并论述了涤纶短纤维生产的经济规模和今后的发展趋势。     

To accelerate shot boundary detection by reducing detection region and scope

Video Shot Boundary Detection (SBD) is the fundamental process towards video summarization and retrieval. A fast and efficient SBD algorithm is necessary for real-time video processing applications. Extensive work has focused on accurate shot boundary detection at the expense of demanding computational costs. In this paper, we propose a fast SBD approach that reduces the computation pixel-wise and frame-wise while still giving satisfactory accuracy. The proposed approach substantially speeds up the computation through reducing both detection region and scope. Color histogram and mutual information are used together to measure the difference between frames. Corner distribution of frames is utilized to exclude most of false boundaries. We conduct extensive experiments to evaluate the proposed approach, and the results show that our approach can not only speed up SBD, but also detect shot boundaries with high accuracy in both Cut (CUT) and Gradual Transition (GT) boundaries.     

Fabrication and optical characterization of poly(2,5‐di‐n‐butoxyphenylene) nanofibril arrays

Anodic aluminum oxide (AAO) membrane can be used as template for the synthesized nanostructures. In this article, we have prepared the AAO membrane by using electrooxidation of aluminum substrate in phosphoric acid, and fabricated poly(2,5‐di‐n‐butoxyphenylene) (BuO–PPP) nanofibril arrays by oxidative coupling polymerization of 1,4‐di‐n‐butoxybenzene (DBB) within the pores of the AAO template membrane. The detailed molecular structure of the polymer nanofibrils was characterized by using infrared and ¹H nuclear magnetic resonance spectra, and estimated to consist of almost equal fractions of 1,4‐ and 1,3‐ linkages. We have used transmission electron microscopy, scanning electron microscopy, and atom force microscopy to confirm the morphologies and images of the AAO template membrane and the fabricated nanometer scale of BuO–PPP nanofibril arrays. The experimental results demonstrated that the pores of the AAO membrane were regular and uniform, and parallel each other, and the BuO–PPP chains in the narrowest template‐synthesized nanofibrils were oriented parallel to the porous axes of the AAO membrane and perpendicular to the surface of the aluminum substrate. The polymer chain orientation was partially responsible for the enhanced conductivity. The ultraviolet absorption spectrum of the BuO–PPP nanofibril arrays shown that the polymer contains a better extended π‐conjugation system along poly‐(p‐phenylene) backbone, which resulted in longer wavelength shift of the absorption band, the absorption maxima were located at 258 nm (E₁ absorption band) and 332 nm (E₂ absorption band), respectively. Photoluminescence spectrum of the BuO–PPP nanofibril arrays exhibited a blue emission. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 425–430, 2004     

浅谈中职计算机课程中如何创设问题情境

在教学中,创设问题情境是一种科学有效的教学手段。通过对一堂计算机基础课《PPT动画路径》的分析,探究如何在中职计算机课程中创设问题情境,提高课堂教学实效性,并对容易出现的问题进行简单的阐述。     

加快结构调整，促进经济发展方式转变

加快结构调整、促进经济发展方式转变是关系国民经济全局紧迫而重大的战略任务。本文以严谨的逻辑和充分的事实依据的基础,对成都市加快结构调整,促进经济发展方式转变的意义,方向和路径等进行了阐述。     

Simultaneous spectrophotometric determination of copper(II), lead(II) and cadrnium(II)

The full spectrum technique in the fourier domain was studied for simultaneous determination of Cu(II), Pb(II) and Cd(II) with 4-(2-pyridylazo) resorcinol (PAR). A program called SPGRFSQ. was designed to perform the calculations. Seven error functions were calculated for deducing the number of factors. Data reduction was performed using principal component analysis (PCA) algorithm. Experimental results showed the method to be successful even where there was severe overlap of spectra.