基于Lotus Notes企业办公自动化系统

简要地介绍了Lotus Notes在办公自动化系统(OA)开发中的技术特点,结合一个企业办公自动化系统的开发,阐述了该系统的总体需求,设计方案和系统实现,并对系统实现过程中的如何控制公文流转、文件修改及痕迹保留、同关系数据库的数据交换、保证系统安全等技术问题给出了相应的解决方案和思路.     

PTA生产溶剂智能优化控制软件的开发与应用

在.Net开发环境下,利用C++语言开发PTA生产溶剂智能优化控制软件,并介绍了软件包的设计原理和基本框架.利用广义回归神经网络建立PTA过程模型,再采用粒子群智能优化法优化过程操作参数,软件系统操作简单、用户界面友好.该软件在精对苯二甲酸(PTA)生产装置的实用效果良好,降低了醋酸和蒸汽的消耗,并为优化各工艺操作条件提供了指导,产生了一定的经济效益,具有较好的推广价值.     

基于红外光纤多液层检测系统的研究与设计

低成本、高精度、结构简单,安全可靠的油水分离器对于提高化工生产的安全水平和效率具有重要意义;介绍了一种以微处理器AT89S52为核心、利用红外光吸收理论实时检测化工生产中多层液体的嵌入式系统;运用化工生产中各层液体浓度不同对红外光吸收程度不同的理论,设计了红外光纤传感器的信号调理电路,开发了以AT89S52为核心,包括A/D转换模块、数据存储模块、串口通讯模块在内的中央硬件处理平台;基于红外光纤液层检测系统与同类系统相比,具有成本低廉,传感检测探头本质安全,系统安全级别高,实时性好,便于大规模推广应用的特点,具有广阔的应用前景。     

一种分布式序列模式挖掘算法

针对分布式环境下的序列模式挖掘问题,提出了一种分布式序列模式挖掘(DSPM)算法。DSPM以PrefixSpan算法为基础,使用抽样检测技术平衡了任务负载,将挖掘任务分解后分配到多台计算机上以多进程、多线程并行执行。另外采用了伪投影技术来降低生成投影数据库的开销。实验结果表明,DSPM算法能够快速有效地挖掘分布式环境下的全局序列模式。     

Carbon Black-Supported Single-Atom Co?N?C as an Efficient Oxygen Reduction Electrocatalyst for H2O2 Production in Acidic Media and Microbial Fuel Cell in Neutral Media

Single metal atom isolated in nitrogen-doped carbon materials (M N C) are effective electrocatalysts for oxygen reduction reaction (ORR), which produces H₂O₂ or H₂O via 2-electron or 4-electron process. However, most of M N C catalysts can only present high selectivity for one product, and the selectivity is usually regulated by complicated structure design. Herein, a carbon black-supported Co N C catalyst (CB@Co N C) is synthesized. Tunable 2-electron/4-electron behavior is realized on CB@Co-N-C by utilizing its H₂O₂ yield dependence on electrolyte pH and catalyst loading. In acidic media with low catalyst loading, CB@Co N C presents excellent mass activity and high selectivity for H₂O₂ production. In flow cell with gas diffusion electrode, a H₂O₂ production rate of 5.04 mol h⁻¹ g⁻¹ is achieved by CB@Co N C on electrolyte circulation mode, and a long-term H₂O₂ production of 200 h is demonstrated on electrolyte non-circulation mode. Meanwhile, CB@Co N C exhibits a dominant 4-electron ORR pathway with high activity and durability in pH neutral media with high catalyst loading. The microbial fuel cell using CB@Co N C as the cathode catalyst shows a peak power density close to that of benchmark Pt/C catalyst.     

基于压电力显微镜的铌酸锂电畴稳定性研究

研究了Z切700 nm厚的单晶铌酸锂(LiNbO₃)薄膜电畴的调控方法。利用X射线衍射仪(XRD)和原子力显微镜(AFM)对单晶LiNbO₃薄膜的晶向和形貌进行了表征,并通过外加电场对单晶LiNbO₃薄膜电畴进行调控。研究结果表明,该LiNbO₃薄膜具有单一的(006)衍射峰,表面光滑、粗糙度低(均方根粗糙度小于1 nm)。通过外加电场和预设电畴图案对LiNbO₃电畴进行精准调控,并测试了电畴稳定性。测试结果显示,调控后的电畴在温度为25~150℃内处于稳定状态,且在30 d内保持稳定,未发生弛豫现象。该研究为LiNbO₃电畴工程器件的研发和应用提供了重要的技术支撑。     

流动温压成型黏结钕铁硼/锶铁氧体复合磁体的研究EI北大核心CSCD

采用流动温压成型工艺制备黏结钕铁硼/锶铁氧体复合磁体,研究温压工艺参数对钕铁硼/锶铁氧体复合磁体磁性能的影响。结果表明:随着温压温度、压制时间以及保压压力的提高,黏结复合磁体的磁性能呈现先增大后减小的趋势。流动温压成型参数的选择与黏结剂有关,采用酚醛环氧树脂BPANE8200为黏结剂时,流动温压成型的最佳工艺参数:77℃加载900MPa并保压8min,复合磁体的剩磁B_r、内禀矫顽力H_(cj)以及最大磁能积(BH)max均获得最大值,即Br=522mT,Hcj=740.48kA/m,(BH)max=39.82kJ/m^3。     

Nanostructured Li3V2(PO4)3 Cathodes

To further increase the energy and power densities of lithium‐ion batteries (LIBs), monoclinic Li₃V₂(PO₄)₃ attracts much attention. However, the intrinsic low electrical conductivity (2.4 × 10^?7 S cm^?1) and sluggish kinetics become major drawbacks that keep Li₃V₂(PO₄)₃ away from meeting its full potential in high rate performance. Recently, significant breakthroughs in electrochemical performance (e.g., rate capability and cycling stability) have been achieved by utilizing advanced nanotechnologies. The nanostructured Li₃V₂(PO₄)₃ hybrid cathodes not only improve the electrical conductivity, but also provide high electrode/electrolyte contact interfaces, favorable electron and Li⁺ transport properties, and good accommodation of strain upon Li⁺ insertion/extraction. In this Review, light is shed on recent developments in the application of 0D (nanoparticles), 1D (nanowires and nanobelts), 2D (nanoplates and nanosheets), and 3D (nanospheres) Li₃V₂(PO₄)₃ for high‐performance LIBs, especially highlighting their synthetic strategies and promising electrochemical properties. Finally, the future prospects of nanostructured Li₃V₂(PO₄)₃ cathodes are discussed.