机械力化学湿法一步制备表面修饰磷酸锌微粉

以氧化锌和磷酸为原料,以硅烷偶联剂为改性剂,采用机械力化学湿法制备微细磷酸锌并进行表面改性.用XRD、润湿角、活化指数、沉降时间等手段对产物进行表征,用FT-IR对改性粉末的结构进行分析,初步探讨了偶联剂与磷酸锌的作用机理.结果表明产物为二水和四水磷酸锌混合物;在红外区域2 800～3 000 cm-1和1 400 cm-1有偶联剂的特征吸收峰,说明偶联剂与磷酸锌之间发生了化学反应;当硅烷偶联剂添加质量分数由0增加到2%,改性产品的活化指数由0增加到98.71%,对水的润湿角由0°增加到93.21°,沉降时间由0.5 h增加到176 h,在涂料中的分散性和贮存稳定性得到改进.     

Specially elaborated thermally induced phase separation to fabricate poly(L‐lactic acid) scaffolds with ultra large pores and good interconnectivity

Poly(L ‐lactic acid) (PLLA) scaffolds with pore diameters from several micrometers to ～300 μm were fabricated by a specially elaborated thermally induced phase separation technique. Two different coarsening protocols, i.e., normal coarsening and multi‐step coarsening were compared in consideration of phase separation and domain growth. A normal coarsening route produced scaffolds with pore size from several micrometers to 150 μm depending on the coarsening time after phase separation, accompanying with the emergence of isolated pores at long time coarsening. Scaffolds with large pores with size up to ～300 μm were fabricated by the two‐step coarsening technique, e.g., the PLLA‐solvent (dioxane/water) system was coarsened at a temperature after phase separation for a period, followed by coarsening at a lower temperature for another period. In parallel with formation of the large pores, the interconnectivity between pores was also improved, which was evidenced by scanning electron microscopy, gelatin solution pervasion, and collagen entrapment. The present technique provides the ability to produce scaffolds with high purity, controllable microstructures, and ease of modification, and hence can be widely used in tissue engineering field. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3336–3342, 2006     

磺酸型Gemini表面活性剂的合成及表面活性

以壬基酚、1,4-二溴丁烷和氯磺酸为主要原料,通过三步反应合成了新型的磺酸型Gemini表面活性剂9BA-4-9BA,讨论了合成反应时间、温度以及催化剂对产物纯度和产率等因素的影响,优化了反应过程。利用核磁共振谱和红外光谱表征了产物结构,并通过DCTA21表面/界面张力仪测试其水溶液中的表面张力。和传统表面活性剂相比,合成的Gemini表面活性剂9BA-4-9BA具有更高的表面活性,其临界胶束浓度和C20分别为6.2×10-4mol/L和1.1×10-5mol/L。     

中国古代陶瓷饮水杯盏形态演变的因素

在人类生存、发展的历史进程中,作为饮水用具的陶瓷杯盏经历了从无到有、由简单到复杂、由粗糙到精致的嬗变过程,而这一过程在很大程度上受到陶瓷生产技术、人们的饮水方式及审美情趣的变化等因素的影响。     

添加辣椒碱类化合物合成抗菌高吸水树脂

以过硫酸铵、亚硫酸氢钠作为引发剂，N，N’-亚甲基双丙烯酰胺作为交联剂，将木薯淀粉与丙烯酸、辣椒碱在水溶液中接枝共聚，合成了具有抗菌性的高吸水性树脂。文章主要考察了添加辣椒碱形式、反应温度、反应时间、引发剂用量、丙烯酸中和度、交联剂用量对合成产物吸水性能的影响。     

液氯气化工艺及安全

介绍了液氯气化的工艺过程及所采取的相应安全措施。     

Efficient multilevel image segmentation through fuzzy entropy maximization and graph cut optimization

The fuzzy c-partition entropy has been widely adopted as a global optimization technique for finding the optimized thresholds for multilevel image segmentation. However, it involves expensive computation as the number of thresholds increases and often yields noisy segmentation results since spatial coherence is not enforced. In this paper, an iterative calculation scheme is presented for reducing redundant computations in entropy evaluation. The efficiency of threshold selection is further improved through utilizing the artificial bee colony algorithm as the optimization technique. Finally, instead of performing thresholding for each pixel independently, the presented algorithm oversegments the input image into small regions and uses the probabilities of fuzzy events to define the costs of different label assignments for each region. The final segmentation results is computed using graph cut, which produces smooth segmentation results. The experimental results demonstrate the presented iterative calculation scheme can greatly reduce the running time and keep it stable as the number of required thresholds increases. Quantitative evaluations over 20 classic images also show that the presented algorithm outperforms existing multilevel segmentation approaches.     

烟气脱硫技术在浮法玻璃线上的应用

简介了烟气脱硫技术在浮法玻璃线上的应用情况,以工程实例详细介绍该技术在某浮法玻璃线上的设计、实施、应用情况以及重点、难点问题的处理,为该技术在浮法玻璃线的应用提供借鉴和参考.     

Detecting changes of the Yellow River Estuary via SAR images based on a local fit-search model and kernel-induced graph cuts

The Yellow River Estuary area of China is under great pressure from both human intervention and natural processes. For analysis of the changes in this area, this article presents a novel change-detection method based on a local fit-search model and kernel-induced graph cuts in multitemporal synthetic aperture radar images. Change detection involves assigning a label to every pixel. This task is naturally formulated in terms of energy minimization, which can be effectively solved by graph cuts. The difference image is transformed implicitly by a kernel function so that an alternative to complex modelling of the original data makes the piecewise constant model become applicable for graph cuts formulation. An issue is that graph cuts are sensitive to the initial estimate. The local fit-search model is proposed to approximate to the local histogram while selecting an optimal threshold for the initial labelling, which leads to an effective constraint for graph cuts and computational benefits as well. Visual and quantitative analyses obtained on the Yellow River Estuary data set confirm the effectiveness of the proposed method and that it outperforms the other state-of-the-art methods of change detection.     

对我国有机硅发展的一些想法

就国内外有机硅行业的现状以及发展提出了一些看法和建议。