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991.
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寻求合适的方法及参数来描述染污复合绝缘子的弱憎水性状态,对弱憎水性状态给出明确的定义,并对当前已有的7个憎水等级进一步细化。通过10μL靛蓝溶液在染污高温硫化硅橡胶试片表面的垂直投影面积,来反映污层的憎水性状况,并尝试将液滴面积与染污绝缘芯棒的污闪电压建立联系,以揭示弱憎水性阶段憎水性能改变对绝缘子污闪特性的影响。结合液滴在污层表面的形态以及试品的污闪特性,在人工污秽试验的基础上将当前憎水等级HC7进一步细化为四个阶段,分别是HC7A、HC7B、HC7C及HC7D。比较液滴面积、液滴接触角以及喷水分级试验结果,将新憎水等级HC7B定义为弱憎水性状态。试验研究认为:液滴面积法弥补了液滴接触角法在染污试品呈弱憎水性状态下的不足,可以用于弱憎水性阶段的憎水特性研究;而憎水性较强时,面积法对憎水性的辨识能力有限,选用接触角法更适合此阶段的研究。 相似文献
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Wei Zhao Songhong Zhang Meizhen Lu Shaochuan Shen Junxian Yun Kejian Yao Linhong Xu Dong-Qiang Lin Yi-Xin Guan Shan-Jing Yao 《Chemical Engineering Research and Design》2014
The microchannel liquid-flow focusing and cryo-polymerization is an efficient method for the preparation of cryogel beads with a narrow diameter distribution. In order to prepare cryogel beads with expected diameters, it is necessary to get insights in the liquid–liquid immiscible flow characteristics of the flow-focusing fluid and the monomer solution in microchannels. In this work, the slug flow behaviors of two immiscible liquids regarding the preparation of poly(2-hydroxyethylmethacrylate) (pHEMA) cryogel beads in a rectangular cross-junction microchannel were investigated experimentally by the high-speed imaging method. Correlations of the immiscible liquid–liquid slug flow parameters like the aqueous slug velocity and length, the aqueous slug nose and tail lengths, the water-immiscible slug length as well as the aqueous droplet size were obtained. The pHEMA cryogel beads were prepared under certain flow conditions and the bead sizes were measured by laser particle size analyzer. The obtained correlations were then employed to estimate the bead sizes and compared with those obtained experimentally. The results showed that the present correlations gave reasonable estimations of the mean bead diameters at various conditions and thus, could be useful and helpful in the preparation of cryogel beads with expected size distributions in rectangular microchannels. 相似文献
996.
With the purpose of enhancing the photochemical water splitting performance, GZO film has been used to increase the charge transfer of the ZnO@GZO films. The characterization of ZnO film, GZO film and ZnO@GZO films was carried out by X-ray diffraction (XRD), atomic force microscope, DRUV-vis spectra (DRUV-vis), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) and photochemical water splitting. All samples show a related highly c-axis peak (002) from XRD patterns. DRUV-vis results show that the formed GZO film with wide band gap but low resistivity, would not affect the band gap of the ZnO@GZO films. PL results reveal that the decreased recombination of electron and hole, via the increased charge transfer by GZO film. XPS results hint that the obvious change of chemisorbed oxygen species on the surface of ZnO and GZO, and Ga atoms mainly substitute into Zn sites in the ZnO matrix. Compared with that of ZnO film, the ZnO@GZO films even with lower specific surface area, could efficiently enhance the photochemical water splitting performance via the charge-transfer effect of the GZO film. 相似文献
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998.
Interfacial modification mechanism of nanocellulose as a compatibilizer for immiscible binary poly(vinyl alcohol)/poly(ethylene oxide) blends 下载免费PDF全文
We undertook this study to understand reinforcement mechanism of short cellulose nanocrystals (CNCs) and long cellulose nanofibrils (CNFs) as compatibility agents for improving the interfacial miscibility of poly(vinyl alcohol) (PVA) and poly(ethylene oxide) (PEO) blends. The effects of the two cellulose nanofibers on the morphological, mechanical, and thermal properties of the polymer blends were compared systematically. The light transparency, scanning electron microscopy, and Fourier transform infrared results show that nanocellulose between PVA and PEO eliminated the negative effects generated by the immiscible interface through increased hydrogen bonding. Thermogravimetric analysis and differential scanning calorimetry results show that crystalline region reorganization around the interface facilitated the shift of the polymer blends from multiple phases to a homogeneous phase. According to the Halpin‐Kardos and Quali models, we assumed that the potential for repairing the immiscible interface would have a larger effect than the potential of reinforcement. At the same concentration, polymer blends with CNCs showed greater light transparency, strength, modulus, and crystal structure than with those with CNFs. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45896. 相似文献
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