Simultaneous spectrophotometric determination of copper(II), lead(II) and cadrnium(II)

The full spectrum technique in the fourier domain was studied for simultaneous determination of Cu(II), Pb(II) and Cd(II) with 4-(2-pyridylazo) resorcinol (PAR). A program called SPGRFSQ. was designed to perform the calculations. Seven error functions were calculated for deducing the number of factors. Data reduction was performed using principal component analysis (PCA) algorithm. Experimental results showed the method to be successful even where there was severe overlap of spectra.     

Oxidation behavior and mechanism of aluminum oxynitride (AlON) at elevated temperatures

The oxidation behavior and mechanism of aluminum oxynitride (AlON) powder exposed to air at elevated temperatures between 800°C and 1300°C was investigated by X-ray diffractometry (XRD), scanning electron microscope (SEM), electron spin resonance (ESR), nuclear magnetic resonance (NMR), and simultaneous thermogravimetry, differential thermal analysis, and mass spectrometry techniques (TG-DTA-MS). The weight of AlON gradually increases to a maximum value at 1150°C and then decreases with further heating. Meanwhile, AlON powder undergoes chemical changes, as evidenced by lattice expansion, and turns eventually into alumina. ESR spectra reveal the occurrence of lone pair electrons in the oxidized products and the intensity of corresponding resonance signal increases before disappearing with the increase in temperature. Combined with the results of NMR and TG-DTA-MS, the measured data suggest that Al-N in [AlO₃N] tetrahedron and [AlO₅N] octahedron are gradually oxidized into Al-O-N group with lone pair electrons, which causes continuous weight gain and lattice expansion. Further oxidation at higher temperatures results in alumina and N₂.     

Engineering all-aromatic polyamide surface from hydrophilic to superhydrophobic and the accelerated strategy

Being a new kind of nanomaterials, aromatic polyamide nanofibers (ANF) have been much highlighted in recent studies. We here demonstrate an isopropyl alcohol (IPA) accelerated chemical cleavage on poly (p-phenylene terephthalamide) chopped fibers, which provides an efficient preparation method of ANF. The comprehensive study on the processes accelerated by different alcohols revealed that the preparation time of ANF in the mixed medium of dimethyl sulfoxide (DMSO)-alcohol (20:1 in volume) was shorten to 45 min and 75 min for methanol (ethanol) and isopropanol, respectively. However, the nanofibers prepared in DMSO-IPA exhibited the minimum in axial and radial dimensions, providing the finest and most uniform diameter of 16 nm. The corresponding ANF films through vacuum assisted filtration also showed the highest tensile strength of 150 MPa, in comparison with those of the ANF films prepared using other alcohols, which were about 110 MPa. Furthermore, ANF/silicon hybrid films were prepared by the ionic ring-opening reaction followed by the alkoxysilane condensation and nanoparticle fabrication. By changing the organo functional groups in the alkoxysilane, the surface of the films were adjustable in a wide contact angle range from 56° (hydrophilic) to 150° (superhydrophobic), suggesting the amendable interfacial properties potential applicable to composite fabrication with most of the resin matrix.     

Self-Diffusion of Iron in Molten Fe-C Alloys

Self-diffusion coefficients of iron in molten Fe-C alloys have been measured by using the capillary method. In addition, the samples have been autoradiographed and sectioned to insure that no significant convection has occurred during the diffusion. The results can be represented by the equation D = 4.3×10^?3 exp (—12.200/RT) for carbon = 4.6 pct and T = 1513° to 1633°K; and D = 1.0×10^?2 exp (—15,700/RT) for carbon = 2.5 pct and T = 1613° to 1673°K. The D values are higher and the heat of activation for diffusion lower in alloys containing more carbon. Calculation based on the Einstein-Stokes equation indicates that the diffusing species is iron ion.     

纳米金刚石的应用

纳米金刚石不仅具有金刚石所固有优异特性，而且还具有纳米材料所拥有的奇异性能。正是这些综合技术特性，使得它在传统的和新的技术领域中得到应用，并初见成效，本文从超精抛光、润滑、复合镀、磁性录音系统和医疗等方面的应用做了扼要的叙述，指出，纳米金刚石颗粒具有球形和准球形的特点，使得摩擦表面形成滚珠轴承效应，而表现出良好的润滑性，从而避免于摩现象的发生，而对一些主要因接触疲劳或高温磨损而失效的工件，纳米金刚石金属的复合涂层，则具有明显的优越性。     

硬质合金磨削温度的实验研究

采用半人工和人工热电偶法，对硬质合金YG6和YT30平面磨削的磨削温度进行了实验研究。并对磨削参数与磨削温度的关系，进行了理论分析及实验验证。结果表明：磨削深度和工作台速度增加，磨削温度升高，但工作台速度的改变，对磨削温度的影响较小．     

基于Word文档的数据隐藏方法

在分析当前数据隐藏与恢复相关技术研究基础上,参照微软官方最新公布的复合文档存储规范,从利用载体Word文档现有空间中未真正使用部分和适度扩展新空间两条思路出发,设计一种利用Word文档作载体隐藏秘密信息的解决方案,包括在文字、各种嵌入式对象及其相应控制结构数据中隐藏信息。实践表明,隐藏数据后的载体文档可以被正常拷贝和使用电子邮件传送,根据需要隐藏的信息随机选择使用该方案,被隐藏信息更不容易被侦测出来,被二次编辑后被隐藏信息一般不会被破坏,鲁棒性不错,具有一定的实用价值。     

利用曲线拟合对触觉数据的压缩

为减轻离线触觉数据压缩带来的失真变形,提出利用曲线拟合的压缩方法.在假定触觉数据所对应原触觉信号能用分段二次参数曲线表示的前提下,通过反向采样过程来构造触觉数据拟合曲线,该曲线由分段二次曲线组成,在连接处达到切线连续,且每段二次曲线对原触觉信号具有二次多项式逼近精度.为避免保存拟合曲线的所有系数以进一步提高数据减少率,对拟合曲线系数进行了迭代求解,从而只需编码保存部分系数即可解码.实验结果表明,该方法在保持高数据减少率的前提下减轻了压缩失真变形.     

Strong Convergence Analysis of Batch Gradient-Based Learning Algorithm for Training Pi-Sigma Network Based on TSK Fuzzy Models

By combining of the benefits of high-order network and TSK (Tagaki-Sugeno-Kang) inference system, Pi-Sigma network is capable to dispose with the nonlinear problems much more effectively, which means it has a compacter construction, and quicker computational speed. The aim of this paper is to present a gradient-based learning method for Pi-Sigma network to train TSK fuzzy inference system. Moreover, some strong convergence results are established based on the weak convergence outcomes, which indicates that the sequence of weighted fuzzy parameters gets to a fixed point. Simulation results show the modified learning algorithm is effective to support the theoretical results.