A Composite Formation Route to Well‐Crystalline Manganese Oxide Nanocrystals: High Catalytic Activity of Manganate–Alumina Nanocomposites

Manganese oxide nanocrystals are combined with aluminum oxide nanocrystals to improve their crystallinity via calcination without a significant increase of crystal size. A nanocomposite, consisting of two metal oxides, can be synthesized by the reaction between permanganate anions and aluminum oxyhydroxide keggin cations. The as‐prepared manganese oxide–aluminum oxide nanocomposite is X‐ray amorphous whereas heat‐treatment gives rise to the crystallization of an α‐MnO₂ phase at 600 °C and Mn₃O₄/Mn₂O₃ and γ‐Al₂O₃ phases at 800 °C. Electron microscopy and N₂ adsorption‐desorption‐isotherm analysis clearly demonstrate that the as‐prepared nanocomposite is composed of a porous assembly of monodisperse primary particles with a size of ～20 nm and a surface area of >410 m² g^?1. Of particular interest is that the small particle size of the as‐prepared nanocomposite is well‐maintained up to 600 °C, a result of the prevention of the growth of manganate grains through nanoscale mixing with alumina grains. The calcined nanocomposite shows very‐high catalytic activity for the oxidation of cyclohexene with an extremely high conversion efficiency of >95% within 15 min. The present results show that the improvement of the crystallinity without significant crystal growth is very crucial for optimizing the catalytic activity of manganese oxide nanocrystals.     

6σ管理在炼钢质量管理中的实践与应用

介绍了6σ管理的特征、DMAIC改进模式,6σ管理在莱钢炼钢厂钢水成分、氧含量等质量控制中的应用及取得的效果。     

电子变压器的技术发展趋势

为适应电子设备的小型化,电子变压器的一个主要发展方向,是从立体结构向平面结构、片式结构、薄膜结构发展,从而形成一代又一代的新型电子变压器:平面变压器、片式变压器、薄膜变压器。文章综述了R型变压器、印刷电路(PCB)型平面变压器、压电变压器、薄膜PCB平面变压器的原理、结构、性能和应用。     

Contactless magnetic transmission system: vibration control and resonance compensation

This work addresses the vibration control of a contactless magnetic transmission system. A learning controller is utilized in this work due to limited actuator bandwidth and uncertainties in the resonant frequencies. Performance of the controller is evaluated under self-resonance, forced oscillation, and transient response. Self-resonance is completely eliminated; while for forced oscillation, the disturbance is attenuated. Stabilization time of the transient response is also significantly reduced, thereby confirming the vibration suppression capabilities of the controller.     

Taming Charge Transport in Semiconducting Polymers with Branched Alkyl Side Chains

The solid‐state packing and polymer orientation relative to the substrate are key properties to control in order to achieve high charge carrier mobilities in organic field effect transistors (OFET). Intuitively, shorter side chains are expected to yield higher charge carrier mobilities because of a denser solid state packing motif and a higher ratio of charge transport moieties. However our findings suggest that the polymer chain orientation plays a crucial role in high‐performing diketopyrrolopyrrole‐based polymers. By synthesizing a series of DPP‐based polymers with different branched alkyl side chain lengths, it is shown that the polymer orientation depends on the branched alkyl chain lengths and that the highest carrier mobilities are obtained only if the polymer adopts a mixed face‐on/edge‐on orientation, which allows the formation of 3D carrier channels in an otherwise edge‐on‐oriented polymer chain network. Time‐of‐flight measurements performed on the various polymer films support this hypothesis by showing higher out‐of‐plane carrier mobilities for the partially face‐on‐oriented polymers. Additionally, a favorable morphology is mimicked by blending a face‐on polymer into an exclusively edge‐on oriented polymer, resulting in higher charge carrier mobilities and opening up a new avenue for the fabrication of high performing OFET devices.     

Singular systems of partial difference equations

Sufficient conditions for the existence and uniqueness of solutions of singular systems of 2-D difference equations with constant coefficients are formulated. Linear transformation of the matrix coefficients leads to recursive forms of such systems of equations. The results are applied to standard 2-D state-space models of discrete systems and sufficient conditions of BIBO stability of these singular systems are obtained.     

高校有线电视宽带综合信息网的建设研究

近年来,全球宽带综合信息网的建设突飞猛进、日新月异。站在科技发展前沿的高等学校应认清形势,抓住机遇,把校园网改造作为学校一项重要的基础设施建设,从而推进高校的现代化步伐。本文介绍了宽带综合信息网的发展趋势,以及有线电视网在宽带接入手段中的优势,并对高校宽带综合信息网的建设与发展提出了几点设想。     

Switching on Fluorescent Emission by Molecular Recognition and Aggregation Dissociation

A generic and effective approach to “switch on” and enhance the two‐photon fluorescence (TPF) emission of quenched TPF molecules, i.e., fluorene derivatives, is reported in terms of molecular recognition with a decoupling medium. Such a medium, in this case Bombyx mori silk, can recognize TPF molecules and inhibit the aggregation of the TPF molecules. The designed TPF molecules are 2,7‐bis[2‐(4‐nitrophenyl)ethenyl]‐9,9‐dibutylfluorene ( 4NF ) and 2,7‐bis[2‐(4‐nitrophenyl)ethenyl]‐9,9‐dioctylfluorene ( 8NF ), which exhibit suppressed TPF emission owing to molecular‐stacking‐led aggregation in the solid form. Due to the specific recognition between –NO₂ in the quenched fluorescent molecules and –NH groups in silk fibroin molecules, the aggregated molecules of 4NF / 8NF molecules are decoupled. This decoupling gives rise to a significant increase in TPF quantum yields. The mechanism is further confirmed by replacing the terminal group –NO₂ in 8NF with –CH₃ (in 2,7‐bis[2‐(4‐methylphenyl)ethenyl]‐9,9‐dioctylfluorene; 8MF ) to eliminate the possibility of molecular recognition. As predicted, in the case of 8MF the switching‐on effect is eliminated. Completely new TPF silk fibers can additionally be applied in real‐time 3D high‐resolution TPF scaffold bioimaging.     

基于种子光特性优化的光纤放大器理论分析

种子光特性直接影响放大脉冲的特性,为获得高质量放大脉冲输出,文章对基于SESAM被动锁模光纤放大器中种子光的特性进行优化模拟。理论分析了锁模光纤激光器的单模光纤长度、增益光纤长度、滤波器带宽以及输出耦合比的变化对种子光特性的影响,以及种子光携带的啁啾对放大脉冲的影响。综合色散和非线性效应等对种子光的影响,得到各项参数的最优值,并进行两级放大模拟,最终获得脉冲宽度为1353 ps、光谱宽度为115nm、平均功率为61W的高质量放大脉冲。     

5-氨基酮戊酸光动力疗法联合CO2激光治疗尖锐湿疣疗效的系统评价

目的：系统评价5-氨基酮戊酸光动力疗法（ALA-PDT）联合CO2激光与CO2激光单用比较治疗尖锐湿疣的疗效和安全性。方法：计算机检索CNKI、VIP、Google学术收索引擎和万方数据知识服务平台（2001至2011.11）,按照拟定的纳入及排除标准选择文献、提取资料和进行质量评价,采用RevMan 5.0软件对纳入文献进行Meta分析。结果：共纳入10个随机对照实验,合计841例患者。Meta分析结果表明,5-氨基酮戊酸光动力疗法联合CO2激光治疗复发率低于CO2激光治疗〔OR=0.15,95%CI（0.10,0.22）,P〈0.00001〕;治疗组治愈率高于对照组〔OR=6.93,95%C1（4.18,11.49）,P〈0.00001〕两种治疗方案产生的不良反应相当,差异无统计学意义〔OR=1.22,95%C1（0.42,3.59）,P=0.71〕。结论：5-氨基酮戊酸光动力疗法联合CO2激光治疗尖锐湿疣能有效降低复发率,提高临床治愈率。但由于纳入研究质量普遍较低,期待更多合理设计的随机对照实验提供高质量的证据。