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Ran Huo Guangyu Bao Zixin He Xuan Li Zhenwei Ma Zhen Yang Roozbeh Moakhar Shuaibing Jiang Christopher Chung-Tze-Cheong Alexander Nottegar Changhong Cao Sara Mahshid Jianyu Li 《Advanced functional materials》2023,33(20):2213677
Emerging soft ionotronics better match the human body mechanically and electrically compared to conventional rigid electronics. They hold great potential for human-machine interfaces, wearable and implantable devices, and soft machines. Among various ionotronic devices, ionic junctions play critical roles in rectifying currents as electrical p–n junctions. Existing ionic junctions, however, are limited in electrical and mechanical performance, and are difficult to fabricate and degrade. Herein, the design, fabrication, and characterization of tough transient ionic junctions fabricated via 3D ionic microgel printing is reported. The 3D printing method demonstrates excellent printability and allows one to fabricate ionic junctions of various configurations with high fidelity. By combining ionic microgels, degradable networks, and highly charged biopolymers, the ionic junctions feature high stretchability (stretch limit 27), high fracture energy (>1000 Jm−2), excellent electrical performance (current rectification ratio >100), and transient stability (degrade in 1 week). A variety of ionotronic devices, including ionic diodes, ionic bipolar junction transistors, ionic full-wave rectifiers, and ionic touchpads are further demonstrated. This study merges ionotronics, 3D printing, and degradable hydrogels, and will motivate the future development of high-performance transient ionotronics. 相似文献
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Bing Zheng Yuchen Yue Jianling Ni Xucong Zhou Yongrui He Xiaoman Gui Han Shen Yanan Jing Jince Zhao Jianqi Zhang Yuan Zhang Jingxia Wang Lei Jiang Lijun Huo 《Advanced functional materials》2023,33(28):2300981
With the development of organic solar cells (OSCs), the high-performance and stable batch variance are becoming a new challenge for designing polymer donors. To obtain high photovoltaic performance, adopting polymers with high molecular weight as donors is an ordinary strategy. However, the high molecular weight need to subtly control the reaction time and state, inevitably caused batch-to-batch variations. Herein, a strategy of steric effect is applied to benzodifuran (BDF)-based polymer by introducing different positions of Cl atom, producing two polymers PBDFCl-1 and PBDFCl-2. The more twisted side chains conformation not only achieve the control of moderate molecular weight for PBDFCl-2, but also easily form molecular stacking through adopting BDF unit and maintain sufficient polymeric crystallinity. Due to the optimized stacking mode and good blend miscibility, PBDFCl-2-based device exhibitsa more elegant power conversion efficiency (PCE) of 17.00% compared to PBDFCl-1-based device. This is the highest efficiency record for BDF-based binary OSCs. Meanwhile, the PCE device variation of the different molecular weights for PBDFCl-2 is little, indicating the reduction of the batch variation. Therefore, smartly using steric effect of Cl atom in strong crystalline BDF unit can form efficient molecular stacking regulations and realize the coordination of high-performance and stable batch variance. 相似文献
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Rongjie Luo Qifei Guo Zihuan Tang Miaomiao Zhang Xingxing Li Biao Gao Xuming Zhang Kaifu Huo Yang Zheng 《Advanced functional materials》2023,33(48):2306115
The serious shuttle effect and sluggish reaction kinetics intrinsically handicap the practical application of Li-S batteries. Herein, a unique 3D hierarchically porous Mott–Schottky electrocatalyst composed of W2C quantum dots (QD) spatially confined in nitrogen-doped graphene microspheres (NGM) is proposed for regulating the kinetics of sulfur electrochemistry. Experimental and theoretical results disclose a spontaneous charge rearrangement and induce built-in electric field across the W2C QD/NGM heterojunction interface, contributing to reduced energy barrier for both polysulfides reduction and Li2S oxidation during entitle discharge/charge processes. Furthermore, the ultrasmall W2C QD with high electrocatalytic activity and superior conductivity can promote the conversion of S species, while the hierarchically porous microspheres assembled from wrinkled graphene nanosheets not only can efficiently inhibit the polysulfides shuttling via multiple spatial confinement, but also provide abundant inner space for stable reservation of active S, highly conductive networks, and maintain the structural integrity of cathode during consecutive cycling. Consequently, Li-S batteries employed with the designed W2C QD/NGM-based cathode exhibit outstanding electrochemical properties even at a high sulfur loading. The superior performance combined with the simplicity of the synthesis process represents a promising strategy for the rational design of advanced electrocatalyst for energy applications. 相似文献
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非接触红外辐射测温具有响应速度快、准确、便捷等优势。为实现中低温(50~400℃)物体温度的精确测量,根据双波段比色测温原理,搭建了双波段比色测温试验系统。首先对试验系统所用的试验器件进行精确标定,得到拟合曲线,用多种插值算法对曲线进行校正。然后,用设定温度的面源黑体作为试验目标来进行试验温度数据采集。实验结果表明:搭建的双波段试验系统不需要知道目标发射率,也能较为精确地得到中低温物体的真实温度。当系统标定置信度为0.95 时,物体的标准偏差在3℃以内。验证了搭建测温系统的正确性,实验装置的搭建对中低温物体真实温度的精确测量具有重要的研究意义。 相似文献
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Frequency resource allocation strategy with QoS support in hybrid cellular and Device‐to‐Device networks 下载免费PDF全文
Zhibo Wang Hui Tian Kun Yang Ziqiang Liu 《International Journal of Communication Systems》2015,28(7):1201-1218
Hybrid networks, comprising a conventional cellular network overlaid with Device‐to‐Device (D2D), offer efficient way to improve system throughput. In this paper, a novel orthogonal frequency‐division multiple access channel‐assignment method is proposed for hybrid network. The proposed approach is optimal in terms of throughput and is subjected to a sensible QoS requirement, which guarantees that macrocell and D2D achieve a prescribed data rate and outage probability, respectively. Our solution consists of two phases. In the first phase, the minimum sub‐channels are allocated to the macrocell to satisfy their data rate requirements. This problem is mapped to the 0‐1 Knapsack Problem and solved by integer programming based Lagrange dual approach. In the second phase, the redundant sub‐channels are allocated to D2D pairs to maximize the throughput of D2D networks. An interference management scheme is proposed to guarantee the outage probability of D2D communications. A cluster is taken as the unit for frequency reuse among D2D pairs. The problem of clustering is mapped to the MAX k‐CUT problem in graph theory and is solved by graph‐based heuristic algorithm. Extensive simulations demonstrate the superior performance of the proposed solution compared with the existing scheme. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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