Enhanced semantic representation learning for implicit discourse relation classification

Applied Intelligence - Implicit discourse relation classification is one of the most challenging tasks in discourse parsing. Without connectives as linguistic clues, classifying discourse relations...     

Hollow Pd/MOF Nanosphere with Double Shells as Multifunctional Catalyst for Hydrogenation Reaction

A new type of hollow nanostructure featured double metal‐organic frameworks shells with metal nanoparticles (MNPs) is designed and fabricated by the methods of ship in a bottle and bottle around the ship. The nanostructure material, hereinafter denoted as Void@HKUST‐1/Pd@ZIF‐8, is confirmed by the analyses of photograph, transmission electron microscopy, scanning electron microscopy, powder X‐ray diffraction, inductively coupled plasma, and N₂ sorption. It possesses various multifunctionally structural characteristics such as hollow cavity which can improve mass transfer, the adjacent of the inner HKUST‐1 shell to the void which enables the matrix of the shell to host and well disperse MNPs, and an outer ZIF‐8 shell which acts as protective layer against the leaching of MNPs and a sieve to guarantee molecular‐size selectivity. This makes the material eligible candidates for the heterogeneous catalyst. As a proof of concept, the liquid‐phase hydrogenation of olefins with different molecular sizes as a model reaction is employed. It demonstrates the efficient catalytic activity and size‐selectivity of Void@HKUST‐1/Pd@ZIF‐8.     

基于Fluent的圆柱齿轮流量计的密封性仿真分析

通过对圆柱齿轮流量计进行二维简化建模,用Fluent仿真软件的ICEM CFD模块进行网格划分,利用Fluent仿真软件对圆柱齿轮流量计进行了计算和密封性的仿真分析,得出了其速度矢量分布图,并且给出了各泄漏量的计算公式和每种泄漏所占泄漏总量的百分比,即为以后的整个流量计的设计提供理论依据。,提高流量计的寿命具有重要意义。同时还省去了大量的人工计算过程,极大地加快了计算速度。     

Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions

The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction.     

Ultrafast measurement of transient electroosmotic flow in microfluidics

We present a non-intrusive molecular dye based method, i.e., laser-induced fluorescence photobleaching anemometer (LIFPA), to significantly increase temporal resolution (TR) for velocity measurement of fast transient electrokinetic flows. To our knowledge, the TR has been for the first time achieved to 5–10 μs, about 100 times better than that published from state-of-the-art micro particle image velocimetry (μPIV), which is currently the most widely used velocimetry in the microfluidics community. The new method provides us with new opportunities to study experimentally the fundamental phenomena of unsteady electrokinetics (EK) and to validate relevant theoretical models. One application of the new method is demonstrated by measuring the rise time of DC electroosmotic flows (EOFs) in a microcapillary of 10 μm in diameter.