汉白玉废料制备球形纳米碳酸钙的研究

将汉白玉废料通过高温煅烧分解得到氧化钙,再用氯化铵循环液溶解氧化钙制得碱性氯化钙溶液,除去其中的Mg、Fe等杂质得到氯化钙精制溶液,利用化学方法合成得到碳酸钙粉体.用X射线衍射(XRD)、扫描电镜(SEM)及激光粒度分析仪、白度仪对碳酸钙产品的晶相组成、形貌、粒度分布、白度及化学组成进行了分析,所得产品为纯度达98.5%以上、白度达97%以上、平均粒度为80nm左右的球形纳米级碳酸钙.并对碳化反应速率及合成球形纳米碳酸钙的影响因素进行了分析.实验中循环使用NH4Cl,氨的排放量小,减少了环境污染.     

百色水利枢纽表孔弧门液压启闭机设计

介绍百色水利枢纽工程溢流坝表孔弧形工作闸门的液压启闭机的结构布置特点以及设计中采用的新方法、新材料.     

YAG：Ce Phosphors for WLED via Nano-Pesudoboehmite Sol-Gel Route

The sub-micron sized YAG ： Ce phosphors were synthesized via a modified sol-gel method by peptizing nano-pesudoboehmite particulate. It is found that YAG phase from the dried gel powders appears at 1000 ℃ then the pure YAG phase exists at a relatively lower sintering temperature of 1400 ℃. The smaller sizes of phosphors in the ranges of 1 - 3 μm are obtained due to the contribution of seeding effects of nano-sized alumina particles to strengthen each step of the processes. Both the excitation and emission spectra of photoluminescence of the phosphor obtained at 1400 ℃ meet well with the spectroscopic requirements of the WLED phosphors.     

3.5代通信中链路自适应技术的研究和仿真

3.5代移动通信中的链路自适应技术使用自适应调制编码和快速混合重传技术替代了3代中使用的功率控制技术。仿真结果比较了这两种新技术与功率控制技术的性能,证明了这两个新技术显著地提高了网络平均的吞吐量。     

ANALYSIS AND PROCESSING OF LMF－COSTAS STEPPED FREQUENCY RADAR SIGNAL

Linear Modulated Frequency (LMF) Costas Stepped Frequency Radar (SFR) signal is introduced. Its ambiguity function is derived and analyzed in detail and its feasibility is validated in theory. The scheme of the proposed signal processing is also presented. The results of theoretic analysis and simulation show that, by using the proposed signal and increasing the bandwidth of the total stepped frequency, the ambiguity sidelobe is well suppressed and the range-velocity coupling in the stepped frequency radar is also greatly weakened.     

长江口北支水道水沙特性分析

从实测资料出发,结合水流数值计算成果,对长江口北支水道的水流、泥沙和含盐度等资料进行分析,得出了北支水道的水沙特性,并分析了水沙变化与河床变化的相互关系.北支水道在1958年南通河段河势控制后,径流分流比逐年下降,并渐趋稳定于3%左右.北支水道受径流影响越来越小,主要受潮流作用.随着水沙特性的逐年变化,北支水道0 m以下槽蓄容量逐年减小,并渐趋稳定,北支上段为逐年淤积最快的区域.由此反过来影响了水沙条件的进一步变化,使北支上段平均潮差增加,北支的会潮点由崇头附近下移至青龙港附近.     

Bioprocess applications of model-based estimation techniques

The last decade has seen the development of a number of approaches for estimating those variables which are difficult to measure on-line in industrial process situations. Whilst a range of techniques is available, a common element is the use of process knowledge in the form of a system model. In the case of bioprocess systems, although a large range of models has been presented in the literature, their use in estimation schemes on an industrial scale has been limited. A number of reasons can be identified for their low level of utilisation. Of particular significance is the uncertainty which exists in quantifying system performance and the process-model mismatch which inevitably results. The level of ‘pre-defined model’ uncertainty, together with the knowledge gained during the course of the fermentation, serves to dictate estimator structure. The paper considers a range of estimation strategies and contrasts, through industrial applications, their performance characteristics and utility.     

Using thermally stimulated currents to find defective capacitors

BaTiO₃ multilayer capacitors with a nominal capacitance of 3.5nF have been carefully measured using the thermally stimulated current (TSC) technique. When a 300V polarization voltage is applied at room temperature, a new TSC peak appeared in defective sample A after it has been immersed in water. No new peak was found in good-quality sample B after a similar treatment. The accelerated life test shows that sample A hasa much shorter life than sample B in terms of insulation resistance.     

Effects of α‐form or β‐form nuclei on polymorphic crystalline morphology of poly(butylene adipate)

The effects of α‐form and β‐form nuclei on polymorphic morphology of poly(butylene adipate) (PBA) upon recrystallization from the molten state up to various T_max values were examined by differential scanning calorimetry (DSC), wide‐angle X‐ray diffraction (WAXD) and polarized light microscopy (PLM). In this study, PBA with complex melting and polymorphism behaviour was used as a model for examining different types and extents of residual nuclei. As the PBA initially containing the sole α‐crystal was brought to a molten state of various T_max, the extents of trace α‐form crystal nuclei varied and were dependent on T_max. Furthermore, it did not matter whether, initially, the PBA contained α‐ or β‐form crystals (or both) because only a single type of α‐nuclei could be left upon treatment to the molten liquid state at T_max. Therefore, only the α‐crystal in PBA had ‘memory capacity’ in the molten liquid state while the β‐crystal did not. This was so because the latter had been completely transformed into the solid state prior to being heated into a liquid. PBA crystallized before α‐nuclei could be packed into α‐crystal, regardless of the crystallization temperature (T_c). For recrystallization from molten PBA without any nuclei, the crystalline polymorphism was correspondingly influenced by T_c. Copyright © 2005 Society of Chemical Industry     

浅析硫磺回收装置中的自动控制设计

大规模高含硫原油的炼制工艺必须配套设置脱硫和硫磺回收装置。笔者针对硫磺回收装置的特点,为确保装置的安全平稳运行,提出了该装置自动控制设计中需要严格监控的工艺参数及重点部位,叙述了仪表选型原则和精确测量与控制的原理和方法。