多种测井曲线校正方法在塔中顺9井区的应用

针对顺9井区柯坪塔格组声波时差和密度曲线失真严重的问题。首先建立了工区的区域岩石物理模板判断测井曲线的失真段,然后使用了经验公式法、多元线性拟合法和岩石物理建模法对声波时差和密度曲线进行了校正。对比发现,经验公式法和多元线性拟合法适用于井眼垮塌较小的井段,而岩石物理建模更适用于井眼垮塌较严重的井段。最后利用区域岩石物理模板和合成地震记录标定约束并检验了曲线校正的结果。结果表明这三种曲线校正方法在顺9井区的应用是有效的、可行的。     

Ultrahigh molecular weight polyethylene with improved crosslink density,oxidation stability,and microbial inhibition by chemical crosslinking and tea polyphenols for total joint replacements

Highly crosslinked ultrahigh molecular weight polyethylene (UHMWPE) stabilized by vitamin E (VE) is widely applied in artificial joints as the bearings. Despite the approval, there is a discord that VE lowers the crosslinking efficiency, limiting its use at high concentration. In this work, we aim to obtain highly crosslinked and oxidation resistant UHMWPE through the conjunction of tea polyphenol and chemical crosslinking. We hypothesized that highly incorporated tea polyphenol with multiple reactive sites can ameliorate crosslinking efficiency of chemical crosslinked UHMWPE in comparison to VE. Epigallocatechin gallate (EGCG) as representative tea polyphenol was incorporated into UHMWPE at high concentration (2–8 wt%), followed by chemical crosslinking with 2 wt% organic peroxide. Unlike VE/UHMWPE blends as the control, chemical crosslinking achieved an increasing trend in crosslink density of EGCG/UHMWPE blends with increasing antioxidant concentration. High concentration of EGCG also enhanced the oxidation stability of UHMWPE. Intriguingly, EGCG endowed UHMWPE with an excellent antimicrobial property, which was inefficient in VE/UHMWPE. Cell viability was hardly affected by the high loaded antioxidant and peroxide. The chemically crosslinked UHMWPE blended with EGCG is proved to be a reasonable, cost effective and realistic alternative for use in artificial joints.     

聚酯型聚氨酯乳液的合成及性能

以异佛尔酮二异氰酸酯（ IPDI）、六亚甲基二异氰酸酯（HDI）和聚己二酸 1,4-丁二醇酯二醇（ PBA）为主要原料制备系列水性聚氨酯乳液（ WPU）。采用红外光谱仪、差式扫描量热仪、 X-射线衍射仪、电子拉力机等对 WPU进行结构表征;为了从聚集状态上对聚氨酯结晶性有更深层次的探究,对 WPU进行了定伸情况下的测试。结果显示：随着硬段含量的增加,硬段 -软段间的氢键相互作用减小,微相分离程度增加,结晶性能降低;随着伸长率的增加,氢键相互作用和结晶性能都表现出先减小后增大的趋势。当硬段含量为 14. 73%时,聚氨酯胶膜拉伸强度达到 40. 11 MPa,剥离强度为 93. 7 N/（25 mm）。     

输出并联型双有源全桥变换器控制技术研究综述

输出并联型双有源全桥(dual-active-bridge,DAB)DC-DC变换器具备电气隔离、模块化扩展简单、高变比升降压及功率双向传输等优势,近年来得到国内外专家学者的广泛关注。首先,分析和归纳该类变换器功率平衡的典型控制方案,并从动态特性、模块化程度、传感器数量等方面,对不同控制方案下的研究策略进行多方面对比分析;然后,基于DAB变换器效率和动态性能优化方法,从多模块角度出发,分析组合系统功率平衡与DAB变换器性能优化相结合的一些典型混合控制策略,并从工程角度给出混合控制其他衍生思路及控制策略选取时,需考虑的实际因素;最后,从开关、桥臂、模块和拓扑等方向,对输出并联DAB变换器的容错控制方案进行详细概述并总结全文。     

高电压磷酸钴锂正极材料性能调控研究

高性能、高安全储能电池的迫切需求加速了橄榄石型高电压正极材料的研究步伐。为了改善高电压磷酸钴锂(LiCoPO₄)的综合电化学性能,采用溶剂热法研究了溶剂比、过渡元素(Fe、Mn)单掺杂和双掺杂(掺杂元素总量占10%)对正极材料形貌、尺寸、反位缺陷和电化学性能的影响。结果表明,当溶剂比为2.3时,未掺杂LiCoPO₄在0.1C下表现出163.1 mAh·g^-1的最高理论比容量;双掺杂LiCo_0.9Mn_0.05Fe_0.05PO₄正极材料具有突出的循环性能,在0.5C电流密度下,循环100圈后的容量保持率为78.9%,循环稳定性得到明显改善。     

Microstructure characterization of reinforcements in in-situ synthesized composites of Al-Zr-O system

A novel in-situ reaction system Al-Zr-O was developed. In-situ Al3Zr and Al2O3 particulates reinforced aluminum matrix composites were fabricated by the direct melt reaction technique in the Al-Zr-O system. Microstructures of the composites and crystal morphology of in-situ formed Al3Zr and Al2O3 particulates were analyzed by scanning electron microscope (SEM) and transmission electron microscope (TEM). Results indicate that in-situ formed Al3 Zr and Al2O3 particles are finer and well distributed in aluminum matrix. Al3Zr particulates with a tetragonal structure are mainly in the shape of polyhedron. A few of them are in the form of rectangle. The length/width ratio of the rectangular Al3Zr is less than 2.0 and the maximum size is 2μm. In addition, a certain number of Al2O3 submicro particles with a hexagonal structure are also generated in this system. Furthermore, it is found that Al3Zr crystal grows by the mechanism of twinning. The twin plane is (114). The twinning direction is [221]. The tensile tests show that the composites synthesized in the Al-Zr-O system exhibits high strength and ductility. There are a lot of ripples with fine particles on the fracture. The principal strengthening mechanisms for (Al3Zr Al2O3 )p/Al composites may include Orowan strengthening, grain-refining strengthening, solid-solution strengthening and dislocation strengthening.     

高温预析出对Al-Zn-Mg-Cu铝合金显微组织、强度和应力腐蚀抗力的影响

通过改变固溶条件 ,对Al Zn Mg Cu高强铝合金采用先高温后低温的两步固溶处理 (高温预析出 )来改善晶内和晶界的析出状态 ,研究了高温预析出对Al Zn Mg Cu铝合金的金相组织、强度和应力腐蚀性能的影响。结果表明 ,4 6 5℃高温预析出在保持较高强度和塑性的同时 ,可以改善合金的抗应力腐蚀性能     

THE ETCH-PITS FEATURE OF BCC METALS AND ANALYTICAL TECHNIQUE FOR QUANTITATIVE DETERMINATION OF THEIR GRAIN ORIENTATION

借助于金相显微镜和扫描电镜,探讨了bcc金属中蚀坑形状和晶粒位向的关系。晶粒的位向采用扫描电镜电子通道花样技术确定,实验结果表示在单位赤面投影三角形中。 采用矢量分析和坐标变换方法,推导了一组描述蚀坑形状和晶粒位向的关系式,并用理论计算数据制成图表。应用这些图表,可以迅速地确定晶粒位向。 因为蚀坑形状是以方位角(θ,φ)的连续函数来描述,故晶粒位向的分析结果可直接表示在单位赤面投影三角形中,且易于确定晶界的变换矩阵。 应用本文的蚀坑分析技术,曾对一些冶金问题进行了探讨。     

管接头类冲压件模具调整过程中有关问题的解决

以出水管接头为例，说明了管接头类冲压件在多次拉深过程中的工艺特点，并提出了模具调试过程中拉深颈缩、法兰平面度超差等问题的解决措施。     

高铬铸铁筛板研究

对高铬铸铁合金化和热处理工艺的研究结果表明，选用Ｃｒ／Ｃ比为７左右的Ｃｒ２０型高铬铸铁，在添加适量的Ｍｏ、Ｃｕ、Ｍｎ，并经合适的热处理后，可获得在马氏体基体上分布着较为均匀的Ｍ７Ｃ３型碳化物，使材料达到良好的强韧性配合，耐磨性明显提高，使用寿命明显高于原用筛板，达到与进口筛板相当的寿命，具有明显的经济效益。