钴酸镍空心球的合成及其抗坏血酸电化学敏感性能

本文以氧化亚铜小球为模板,采用简单温和的化学方法成功刻蚀制备出了钴酸镍空心球。通过多种表征手段对样品的形貌及组成进行了表征,结果表明,钴酸镍为空心结构并保持了氧化亚铜的形貌,粒径约为350nm,具有多晶的特征。将该材料修饰的电极应用到抗坏血酸电化学传感器中,测试结果表明,其对抗坏血酸的检测极限为3×10-7 M(S/N=3),线性相关系数为0.9993,线性检测范围为0.1~3mM,灵敏度高达1148.7μA·mM-1·cm-2,并具有良好的选择性。     

Electrochemical corrosion behavior of 2A02 Al alloy under an accelerated simulation marine atmospheric environment

The corrosion behavior of 2A02 Al alloy under simulated marine atmospheric environment has been studied using mass-gain, scanning electron microscope/energy dispersive spectroscopy (SEM/EDS), laser scanning confocal microscopy, X-ray diffraction spectroscopy and localized electrochemical methods. The results demonstrate that the relationship between the corrosion induced mass-gain and the corrosion time is in accordance with the power rule. The mass-gain increases gradually during the corrosion time, while the corrosion rate decreases. With ongoing of the corrosion, corrosion products film changed from a porous to a compact structure. The various spectroscopic data show that the corrosion products films composed mainly of Al(OH)₃, Al₂O₃ and AlCl₃. The electrochemical corrosion behavior of the 2A02 Al alloy was studied by electrochemical impedance spectroscopy (EIS).     

Magnetic and magnetotransport properties of single-crystalline R_2PdGe_6(R = Pr,Gd and Tb)

Single crystals of R_2PdGe_6(R = Pr, Gd and Tb) compounds were grown by the Bi-flux method. Pr_2PdGe_6 is an antiferromagnetic compound with Néel temperature T_N= 15 K, in which a field-induced magnetic transition(spin flip) occurs when a magnetic field is applied along either a or b axis; a small magnetization and hysteresis loop were observed when a field is applied along c axis. Gd_2PdGe_6 is a collinear antiferromagnetic compound with T_N= 37 K along b axis. Tb_2PdGe_6 is an antiferromagnetic compound with T_N= 48 K and its hard magnetization direction is along b axis. The temperature dependences of the resistance of the entire three compounds present inflection points at the respective T_N. A large resistance(as well as magnetoresistance) change can be found at the spin flip transition of Pr_2PdGe_6, but the change is not obvious at the spin flop transition of Gd_2PdGe_6.     

Surface energy-mediated fibronectin adsorption and osteoblast responses on nanostructured diamond

Nanostructured diamond have potential applications in many biomedical related fields and demonstrated extraordinary capacity to influence cellular responses. Studying the surface property of nanodiamond and its influence to protein adsorption and subsequent cellular responses along with the mechanism behind such capacity becomes more important. Here the role of surface energy associated with nanostructured diamond in modulating fibronectin and osteoblast(OB, bone forming cells) responses was investigated. Nanocrystalline diamond(NCD) and submicron crystalline diamond(SMCD) films with controllable surface energy were prepared by microwave-enhanced plasma chemical vapor deposition(MPCVD) techniques. Fibronectin adsorption on the diamond films with varied surface energy values was measured via the enzyme-linked immunosorbent assay(ELISA) and the relationship between the surface energy and fibronectin adsorption was studied. The result indicated that fibronectin adsorption on nanostructured surfaces was closely related to both surface energy and material microstructures. The spreading and migration of OB aggregates(each containing 30–50 cells) on the NCD with varied surface energy values were also studied. The result indicates a correlation between the cell spreading and migration on nanodiamond and the surface energy of nanostructured surface.     

Numerical and experimental investigations of laser shock forming aluminum alloy sheet with mold

Laser shock forming (LSF) technology employs shock waves to form sheet metal into three-dimensional complex parts, and has application potential in manufacturing sheet metal parts. In this paper, the forming of 2024 aluminum alloy sheet with LSF was investigated through numerical and experimental methods. The numerical model was established with the commercial code ABAQUS/Explicit. The formed conical cup was obtained from the simulation, and validated by the experiment. With the verified numerical model, the deformation behaviors, including deformation velocity, sheet thickness variation and strain distribution, were studied. In addition, the influence of different shock wave pressures on the forming precision was also investigated. The experimental and numerical results show that the metal sheet loaded by shock wave can take the shape of the mold, and the non-uniform thickness is distributed in the formed cup. The investigations also display that there exists reverse deformation at the central region of deforming sheet owing to severe collision during LSF. In order to obtain formed part with better quality, an appropriate pressure of applied shock waves is required.     

Graphene oxide-decorated Fe<Subscript>2</Subscript>(MoO<Subscript>4</Subscript>)<Subscript>3</Subscript> microflowers as a promising anode for lithium and sodium storage

Mixed transition metal oxides (MTMOs) have received intensive attention as promising anode materials for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). In this work, we demonstrate a facile one-step water-bath method for the preparation of graphene oxide (GO) decorated Fe₂(MoO₄)₃ (FMO) microflower composite (FMO/GO), in which the FMO is constructed by numerous nanosheets. The resulting FMO/GO exhibits excellent electrochemical performances in both LIBs and SIBs. As the anode material for LIBs, the FMO/GO delivers a high capacity of 1,220 mAh·g^–1 at 200 mA·g^–1 after 50 cycles and a capacity of 685 mAh·g^–1 at a high current density of 10 A·g^–1. As the anode material for SIBs, the FMO/GO shows an initial discharge capacity of 571 mAh·g^–1 at 100 mA·g^–1, maintaining a discharge capacity of 307 mAh·g^–1 after 100 cycles. The promising performance is attributed to the good electrical transport from the intimate contact between FMO and graphene oxide. This work indicates that the FMO/GO composite is a promising anode for high-performance lithium and sodium storage.

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Emergence of photoluminescence on bulk MoS<Subscript>2</Subscript> by laser thinning and gold particle decoration

We demonstrate a facile and effective approach to significantly improve the photoluminescence of bulk MoS₂ via laser thinning followed by gold particle decoration. Upon laser thinning of exfoliated bulk MoS₂, photoluminescence emerges from the laser-thinned region. After further treatment with an AuCl₃ solution, gold particles self-assemble on the laser-thinned region and thick edges, further increasing the fluorescence of bulk MoS₂ 28 times and the Raman response 3 times. Such fluorescence enhancement can be attributed to both surface plasmon resonance and p-type doping induced by gold particles. The combination of laser thinning and AuCl₃ treatment enables the functionalization of bulk MoS₂ for optoelectronic applications. It can also provide a viable strategy for mask-free and area-selective p-type doping on single MoS₂ flakes.

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Entrapping multifunctional dendritic nanoparticles into a hydrogel for local therapeutic delivery and synergetic immunochemotherapy

Nano Research - Developing multifunctional nanoparticles to support new therapy models is a promising and challenging task to address the current dilemma on antitumor treatment. Herein, we...     

仿人智能协调控制在循环流化床锅炉燃烧控制系统中的应用

针对循环流化床锅炉燃烧系统中主蒸汽压力和床体温度的强耦合问题,提出了基于仿人智能协调控制,并在此基础上与仿人智能模糊控制相结合的解耦控制策略,并将此控制策略应用于燃烧系统进行仿真;仿真结果表明,该策略有效地解决了循环流化床锅炉燃烧系统的非线性、大滞后和强耦合问题,实现了燃烧系统中主蒸汽压力和床体温度的解耦控制,并且在施加扰动后,体现出了一定的抗干扰能力,能收到良好的控制效果。     

新一代B/S结构DCS火电控制系统设计与实现

传统的C/S结构DCS火电控制系统设计方法,上位机与服务器通信中,服务器需要与多个操作员站通信,造成负荷过高;为解决这一问题,以和利时第五代DCS为基础,设计新一代基于B/S模式的DCS数据监控系统,以点对点模式完成通信;新一代系统中,服务器相对于每个操作员站都是独立的,克服当前系统同时通信高负荷的弊端;给出了关键的底层控制站信息采集模块和DP总线信息传递模块的详细设计方案以及相关的软件设计方案,并给出了关键的B/S结构的详细设计方案;实验结果表明,以B/S结构为基础的DCS数据监控系统测量结果误差小,上位机通信的时长不超过1s,服务器冗余重启切换不超过1.2s,优化效果较为明显。