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21.
Wenwei He Wuping Liao Weiwei Wang Deqian Li Chunji Niu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(9):1314-1320
BACKGROUND: Thermodynamics and kinetics data are both important to explain the extraction property. In order to develop a novel separation technology superior to current extraction systems, many promising extractants have been developed including calixarene carboxylic acids. The extraction thermodynamics behavior of calix[4]arene carboxylic acids has been reported extensively. In this study, the mass transfer kinetics of neodymium(III) and the interfacial behavior of calix[4]arene carboxylic acid were investigated. RESULTS: The rate constant (Kao) becomes constant when the stirring speed was controlled between 250 rpm and 400 rpm. The activation energy (Ea) was calculated to be 21·41 kJ mol?1 or 88·17 kJ mol?1 (dependent on temperature) from the slope of log Kao against 1000/T. The linear relationship between the specific area and the extraction rate is the characteristic of an interfacial reaction control. The minimum bulk concentration of the extractant necessary to saturate the interface (Cmin) is lower than 4·19 × 10?4 mol L?1. CONCLUSION: The effect of stirring speed, temperature, and species concentration on the extraction rate demonstrates that the extraction regime depends on the extraction conditions. The chemical reaction control governs the extraction regime at temperatures below 303 K and a mixed control regime occurs when the temperature is between 303 K and 318 K. The probable locale for the chemical reaction is at the liquid–liquid interface and the rate equation is deduced to be: ? d[Nd3+](a)/dt = kf[Nd3+](a)[H4A](o)0·727[H+](a)?0·978. The rate‐controlling step was suggested by the analysis of the experimental results. Copyright © 2008 Society of Chemical Industry 相似文献
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合成2,4-二叔丁基苯酚工业试验 总被引:2,自引:0,他引:2
以离子交换树脂为催化剂,苯酚和甲基叔丁基醚为原料合成2,4-二叔丁基苯酚(简称2,4酚),合成产物经过滤再经间歇真空精馏精制提纯,得到高纯度的2,4酚成品。成品精馏后釜中残液在酸性白土催化剂的作用下通过歧化反应生成对叔丁基苯酚,再经精馏提纯得到成品对叔丁基苯酚。通过工艺优化,使2,4酚、对叔丁基苯酚形成联产生产工艺,降低了生产原料消耗和成本。 相似文献
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Xiaofeng Liao Xueming Li Jun Pen Guanrong Chen 《International Journal of Communication Systems》2004,17(5):437-445
In this paper, a simple image secure communication scheme based on the chaotic Chebyshev map and chaos synchronization is proposed. The scheme relies on the excellent correlation property of chaotic sequences, which is very desirable for secure image communication. The results obtained by computer simulation indicate that the transmitted source image can be correctly and reliably recovered using the proposed scheme, even through a noisy channel. Notably, the scheme possesses relatively high security and can be easily implemented. Moreover, the quality of the recovered image is satisfactory, quantified by such common criteria as the bit‐error rate performance. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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Thirty six patients of pulmonary or nasopharyngeal carcinoma were treated with Xilixin granule (XLXG) combined with radiotherapy and compared their efficacy with that of 31 patients treated by Zhenqi Fuzheng granule combined with radiotherapy for control. Results showed that the symptoms of Yin Deficiency syndrome in treated group were obviously improved, the leucocyte decreased by 5.6%, while in control group it reached 25.8%, the 3 year survival rate was significantly higher in treated group (75.0%) than that in control group (51.6%). Animal experiment revealed that XLXG had the effects of tumor inhibition, it could increase white blood cells, platelets and hemoglobin of patients, especially in using large dosage. These results suggested that XLXG have some protective effect against radiotherapeutic damage in patients with malignant tumor. 相似文献
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The excited state phosphorescence lifetime of alexandrite crystals is used to monitor temperature in the physiological range from 15-45°C with precision and accuracy of 0.2°C. A 500-μm cubic alexandrite crystal bounded to the distal end of an optical fiber of similar core dimensions is excited with pulsed Ne-He laser light. This apparatus uses a sampler for data acquisition and frequency domain methods for data fitting. The instrument amplifies the AC components of the detector output and band limits the signal to 12.5 kHz. The fundamental frequency of the excitation is set to 195.13 Hz to obtain 64 harmonics. This band limited signal is sampled and averaged over few hundred cycles in the time domain. The frequency domain representation of the data is obtained by employing fast Fourier transform algorithms. The phase delay and the modulation ratio of each sampled harmonic are then computed. Five to 50 values of the phase and modulations are averaged before computing the sensor lifetime. The instrument is capable of measuring precise and accurate excited state lifetimes from subpicowatt luminescent signals in plastic optical fibers. A least squares fit yields the lifetimes of single exponentials. A component of zero lifetime is introduced to account for the backscatter excitation seen by the photodetector leaking through optical interference filters. The phosphorescence lifetimes measured reproducibly to about three parts in a thousand are used to monitor physiological temperature. Temperatures are computed employing empirical polynomials. The system drift is negligible over 15 h of continuous operation. The instrumentation and methods allow 1.3-s update times and 30-s full response times 相似文献
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The effects of hydrogen dilution on the bonding characteristics, composition, and properties of SiN films deposited from a SiH4/NH3 mixture by r.f. plasma enhanced chemical vapor deposition were studied. The addition of relatively small amounts of hydrogen increased the Si/N ratio resulting in a corresponding increase in the Si---H/N---H bonding ratio. At higher hydrogen dilutions, the Si/N ratio decreased towards stoichiometric with significant changes in the hydrogen bonding characteristics. Changes in the physical properties are discussed in terms of the measured changes in bonding structure. Changes normally associated with changes in bulk film density were found to be well correlated to the Si---N bond density. The effects of substrate temperature and NH3/SiH4 ratio on films deposited under conditions of high hydrogen dilution were similar to those widely reported in the literature for plasma-enhanced chemical vapor deposition films deposited without hydrogen. Films deposited by remote plasma using hydrogen as the excitation exhibited high Si---N bond densities and low hydrogen. Experiments are planned to clarify the mechanism responsible for the observed changes in film properties. 相似文献
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