氨氮废水的处理技术及发展

综述了当前氨氮废水处理技术的原理和各自的优缺点, 介绍了国内外氨氮废水处理的研究现状, 同时对氨氮废水处理前景进行了展望, 并提出了今后应着重考虑的几个问题。     

Influence of the copper ion on aging rate of oil-paper insulation in a power transformer

To identify the influence of copper ion on the aging rate of oil-paper insulation, accelerated thermal aging experiments on oil-paper insulation were designed and performed at two significant temperatures. A set of characteristic parameters, including dissolved gases, degree of polymerisation, furfural content, water content and acid number of oil, was tested. The experiments- results reveal that copper ion has a different influence on insulation paper and oil during the aging process of the insulation system. On the one hand, it delays the degradation of insulation paper, reducing the ratio of CO₂/CO by about 11% at 80%C and by more than 50% at 130%C. On the other hand, copper ion promotes the oxidation of oil and thus accelerates the aging rate.     

Preparation and properties of a novel bone repair composite: nano-hydroxyapatite/chitosan/carboxymethyl cellulose

Nano-hydroxyapatite/chitosan/carboxymethyl cellulose (n-HA/CS/CMC) composites with weight ratios of 70/10/20, 70/15/15 and 70/20/10 were prepared through a co-solution method. The properties of the composites were characterized by means of burn-out test, IR, XRD, TEM and universal material testing machine. The degradation and bioactivity were also investigated by in vitro test in a simulated body fluid (SBF) for 8 weeks. The results showed that n-HA particles were dispersed uniformly in organic phase, and strong chemical interactions formed among the three phases. Moreover, the composites were similar to natural bone in morphology and size. In addition, the compressive strength was improved compared with n-HA/CS composite. The biodegradation rate was controllable by altering weight ratio of the CS/CMC. Meanwhile, the composites could induce apatite particles to deposit in SBF. All the above results indicate that the novel composites of n-HA/CS/CMC have a promising prospect used for bone repair materials in view of the good mechanical property, adjustable biodegradation rate and bioactivity in SBF. Additionally, the study would provide a good guide to exploit clinical application of natural cellulose.     

Modulating lateral strain in GaN-based epitaxial layers by patterning sapphire substrates with aligned carbon nanotube films

A novel carbon nanotube-patterned sapphire substrate (CPSS) has been utilized for the growth of GaN material and fabrication of a InGaN/GaN light emitting diode (LED) by metal-organic vapor phase epitaxy. Different lateral strain distributions and stress reductions were observed in a GaN thin film on CPSS compared with those on a conventional sapphire substrate. Nanoheteroepitaxy induced by small size nucleation islands of about 50 nm is ascribed to this significant strain modulation. The crystalline quality of the GaN thin film was also improved, as illustrated by X-ray diffraction. Performances of 1 mm × 1 mm LEDs on CPSS were also enhanced, with an operational power increase of 37.5% and higher saturation current.      

天然气超声流量计健康状态评价方法初探

目的天然气计量用超声流量计性能诊断主要采用设定参数阈值的诊断方法,为降低误报、漏报等情况,建立了基于生成对抗神经网络(generated adjoint neural network,GAN)和高维非线性无监督学习的超声流量计健康状态系统诊断方法。 方法采用GAN对原始数据进行学习、生成和扩充,保障超声流量计健康状态诊断建模的数据基础,提取超声流量计在运行过程中的健康状态参数并对其进行时序分析,采用高维非线性无监督聚类学习方法,结合超声流量计失效模式分析,对超声流量计设备进行在线的健康状态诊断。 结果结合超声流量计工作原理和现场实际采集数据,对生成的故障数据集进行了验证。 结论能够准确识别超声流量计当前状态,显著解决传统阈值法误报率、漏报率高的问题,为超声流量计健康诊断的统一管理与开发给予支撑。      

用不对称醚作调节剂合成苯乙烯-异戊二烯-丁二烯橡胶的反应动力学

以苯乙烯(St)、异戊二烯(Ip)和丁二烯(Bd)为单体,正丁基锂(n-BuLi)为引发荆,乙基乙二醇叔丁基醚(BET)为结构调节剂,合成了线型无规结构的苯乙烯-异戊二烯-丁二烯橡胶(SIBR),进行了聚合反应动力学研究,并与以四氢呋喃(THF)为结构调节剂的体系进行了比较.结果表明,BET的加入提高了聚合反应速率;随反应温度的升高和BET/n-BuLi(摩尔比)的增大,聚合反应速率加快,尤其是St的反应速率提高显著;BET调节聚合速率的能力明显高于THF.