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71.
Mei Xuan Xu Wen Guang Liu Yun Lin Guan Zuo Peng Bi Kang De Yao 《Polymer International》1995,38(2):205-209
The phase behavior of a hybrid polymer network (HPN) composed of poly[(propylene glycol maleate)-co-(propylene glycol phthalate)] crosslinked with styrene and polyester–urethane crosslinked with methylene-bis-ortho-chloroaniline was examined. The correlation between phase separation and impact strength of the HPNs is discussed. The composition of HPNs has an effect on their properties. 相似文献
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锝化学研究 Ⅸ.脑显像剂Tc~(Ⅴ)ON_2S_2类配合物结构稳定性和价态的研究 总被引:1,自引:0,他引:1
采用改进的CNDO/2法模拟了BAT类脑显像剂Tc(Ⅴ)O配合物价态的转换过程,发现N2S2类配体与Tc(Ⅴ)O核配位时,可能存在配位平衡离子X。在溶液中由于X离子的优先解络,瞬间存在+1价对称性99Tcm配合物,并且,它又自动向相对稳定的0价不对称性99Tcm配合物转换,在动态转换过程中,将导致仅有一个配位N原子保留一个质子,这与实验结果一致。采用键级削弱百分数概念,表征配位过程的二个配位N原子上保留程度,解释了Tc(Ⅴ)O核、Tc(Ⅴ)≡N核N2S2类配合物两个N-H键上质子保留程度不同的原因,为今后设计不同价态锝配合物结构提供理论依据。 相似文献
74.
Spontaneous mutation for a quantitative trait in Drosophila melanogaster. II. Distribution of mutant effects on the trait and fitness 总被引:7,自引:0,他引:7
Exposure of the Chinese hamster ovarian AuxB1 cell line in vitro to fractionated X-irradiation generated sublines designated DXR-10, which proved resistant to multiple drugs and overexpressed P-glycoprotein (Pgp), as judged by Western blotting using the C219 monoclonal antibody. Further characterization of these irradiated DXR-10 sublines has provided evidence for: (i) the expression of cross-resistance to gramacidin D, taxol, puromycin and Navelbine, but not to daunomycin or mitoxantrone; (ii) overexpression of the class I Pgp, as judged by Western blotting using the C494 monoclonal antibody; (iii) decreased accumulation of 3H-vincristine, which could be enhanced by verapamil addition; (iv) unaltered accumulation and subcellular distribution of adriamycin; (v) significantly increased rhodamine 123 accumulation in the presence of verapamil; (vi) plasma-membrane ultrastructural modifications resulting in a significantly increased surface area; (vii) numerous clonal karyotypic alterations, with abnormalities involving the long arm of chromosome 1 being consistently identified; (viii) a lack of overexpression of sorcin; (ix) increased total glutathione levels and overexpression of glutathione S-transferase pi. The fact that only certain of these features are considered characteristic of the 'classic' multidrug-resistant CHRC5 cell line supports our earlier proposal that exposure to fractionated X-irradiation results in the expression of a unique drug-resistance phenotype. 相似文献
75.
Surface area and porosity of pellets containing alumina/carbon powder mixtures during reduction and nitridation were determined. The experimental results indicated that surface area and porosity of solid samples were decreased by increasing the reaction temperature, grain size, forming pressure and the amount of catalyst. Increasing the molar ratio of C/Al2O3 and gas flow rate could decrease the surface area and increase the porosity of the solid sample. 相似文献
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The finite strip method based on the higher-order plate theory is developed for determining the natural frequencies of laminated plates. This method can accurately predict the through thickness effect of transverse shear deformation. Furthermore, only a few degress of freedom are required in the finite strip method. Some numerical results for various span-to-thickness ratios, material properties and stack sequences are presented for illustrative purposes. The present model provides a better way to obtain more accurate natural frequency results. 相似文献