“Water-in-Deep Eutectic Solvent” Electrolytes for High-Performance Aqueous Zn-Ion Batteries

Aqueous Zn-ion batteries have been considered as promising alternatives to Li-ion batteries due to their abundant reserves, low price, and high safety. However, Zn anode shows poor reversibility and cycling stability in most conventional aqueous electrolytes. Here, a new type of aqueous Zn-ion electrolyte based on ZnCl₂–acetamide deep eutectic solvent with both environmental and economic friendliness has been prepared. The water molecule introduced in the “water-in-deep eutectic solvent” electrolyte could reduce the Zn²⁺ desolvation energy barrier by regulating Zn²⁺ solvation structure to promote uniform Zn nucleation. Zn anode shows improved electrochemical performance (≈98% Coulombic efficiency over 1000 cycles) in the electrolyte whose molar ratio of ZnCl₂:acetamide:H₂O is 1:3:1. The assembled full battery composed of phenazine cathode and Zn anode could stably cycle over 10 000 cycles with a high capacity retention of 85.7%. Overall, this work offers new insights into exploring new green electrolyte systems for Zn-ion batteries.     

变温LPCVD沉积氮化硅薄膜的均匀性优化

以低压化学气相沉积(LPCVD)热壁立式炉为实验平台,由二氯硅烷和氨通过LPCVD工艺合成氮化硅薄膜,利用降温成膜提高氮化硅薄膜的膜厚均匀度.基于气体碰撞理论建立了氮化硅薄膜沉积速率与反应气体浓度的关系式.分析比较了LPCVD炉内不同升温速率沉积氮化硅薄膜的表面性能.发现在变温沉积阶段,选择合适的降温速率是实现薄膜沉积...     

Fluorinated and Alkylthiolated Polymeric Donors Enable both Efficient Fullerene and Nonfullerene Polymer Solar Cells

In this work, four donor (D)–acceptor (A) copolymers based on benzodithiophene (BDT) and benzothiadiazole (BT) with different alkylthiolated and/or fluorinated side chains are developed for efficient fullerene and nonfullerene polymer solar cells (PSCs). The synergistic effect of sulfuration and fluorination on the optical absorption, energy level, crystallinity, carrier mobility, blend morphology, and photovoltaic performance is investigated systematically. By incorporating sulfur atoms onto the side chains, a little blueshifted but significantly increased absorption can be obtained for PBDTS‐FBT compared to PBDT‐FBT . On the other side, a little more blueshifted but much stronger absorption and much lower‐lying highest occupied molecular orbital (HOMO) level can be realized for PBDTF‐FBT when introducing fluorine atoms instead of sulfur atoms. With the combination of both fluorination and sulfuration strategies, PBDTS‐FBT exhibits the best absorption ability, lowest HOMO energy level, and highest crystallinity, which make PBDTSF‐FBT devices show the highest power conversion efficiency (PCE) of 10.69% in fullerene PSCs and 11.66% in nonfullerene PSCs. The PCE of 11.66% is the best value for PSCs based on BT‐containing copolymer donors reported so far. The results indicate that fluorination and sulfuration have a synergistically positive effect on the performance of D–A photovoltaic copolymers and their solar cell devices.     

Delay Constrained Relay Node Placement in Wireless Sensor Networks: A Subtree-and-Mergence-based Approach

Wireless Sensor Networks (WSNs) are applied in many time-critical applications, e.g., industrial automation and smart grid. This highlights the importance of Delay Constrained Relay Node Placement (DCRNP) problem that builds a path fulfilling a specified delay constraint between each sensor and the sink by using a minimum number of relays. Due to the NP-hardness of the DCRNP problem, in this paper, a polynomial time Subtree-and-Mergence-based Algorithm (SMA) is proposed to approximately solve the DCRNP problem. First, a shortest path tree rooted at the sink and connecting all sensors is built to check the feasibility of the DCRNP problem. If the DCRNP problem is feasible, then the paths of this tree are progressively merged at some relays, which are not limited to those relays lying in the originally the originally built shortest path tree, to save deployed relays while maintaining the obedience of delay constraints. With the repetition of this mergence, the number of deployed relays is gradually reduced. Furthermore, the approximation ratio and the time complexity of the proposed SMA are elaborately analyzed. Finally, extensive simulations are conducted to demonstrate the effectiveness of this work. Simulation results show that SMA can significantly save deployed relays comparing with existing algorithms.     

“向导-主体”网络教学模式探索

基于在校大学生的封闭式网络教学学习体验调查结果,网络教学易导致学习氛围差、注意力不集中、任务多、不适应等问题。结合教学理论和教学实践,提出封闭式网络教学应采取以教师为向导、学生为主体的"向导-主体"教学模式。教师需在教学中录制或选择优质的授课视频激发和维持学生的内部学习动机,设置合理的日常学习评价体系激发和维持学生的外部学习动机,精简教学资源、绘制课程学习导图以提高学习效率,倾听学生的反馈,及时调整教学安排。学生借助多媒体和网络技术进行学习,成为学习的主体。     

多尺度特征融合的膨胀卷积残差网络高分一号影像道路提取

针对全卷积神经网络多次下采样操作导致的道路边缘细节信息损失和道路提取不准确的问题,本文提出了多尺度特征融合的膨胀卷积残差网络高分一号影像道路提取方法.首先,通过目视解译的方法制作大量的道路提取标签数据;其次,在残差网络ResNet-101的各个残差块中引入膨胀卷积和多尺度特征感知模块,扩大特征点的感受野,避免特征图分辨...     

超晶格界面的电子反向及引起的光电流特性

测量了GaAs/AlGaAs超晶格在T＝77K时的光电流谱,发现在波数～↑υ=1589cm^-1存在一个强电流峰,理论分析认为,该电流峰与超晶格界面的电子反射有关,据此算出的电流峰位置与实验观测结果一致。     

GPRS中网络结构与信令研究

本文首先介绍了GPRS网络的总体逻辑结构,然后重点介绍了在GPRS网络中各个接口上的信令协议过程。     

无水石膏AⅢ对β半水石膏性能的影响及作用机理

以磷石膏为原料生产β半水石膏粉,研究了可溶性无水AⅢ对半水石膏粉的影响,采用常规分析方法、TG-DSC、XRD和扫描电镜等方法对磷石膏原料,β半水石膏粉和石膏产品进行分析和表征。差热分析结果表明：磷石膏低温脱水出现两个DSC吸热峰,峰值仅相差6 ℃并存在重叠现象,说明脱水反应分两步进行,发生了不同反应,熟石膏粉中存在不同相混合物。半水石膏粉煅烧最佳工艺：焙烧温度在170±5 ℃内,焙烧时间2 h,熟石膏新粉结晶水含量约3.0%,通过陈化,控制结晶水含量4.8%~5.2%,有利于提高熟石膏粉质量。半水石膏水化热效应结果表明：AⅢ活性高,水化速度快,导致添加减水剂时几乎未见减水增强效果,说明AⅢ影响熟石膏粉质量。陈化粉添加减水剂能提高石膏制品强度,聚羧酸系HC掺量0.7%时,绝干强度达到15.0 MPa,强度提高近64.84%; 奈系FDN掺量0.7%时,绝干强度达到14.8 MPa,强度提高近62.64%;木质素减水剂掺量0.7%时,绝干强度达到13.9 MPa,强度提高近52.75%。