Self-assembled monolayers of C60-perylenetetracarboxylic diimide-C60 triad on indium tin oxide surface

Indium tin oxide (ITO) electrodes modified chemically with self-assembled monolayers (SAMs) of C₆₀-perylenetetracarboxylic diimide-C₆₀ triad have been designed for the first time to act as an efficient light-to-current converter in molecular devices. The monolayers were characterized using UV-Vis, X-ray photoelectron spectroscopy and atomic force microscopy. Photoelectrochemical measurement of the SAMs of C₆₀-Perylenetetracarboxylic diimide-C₆₀/ITO indicated prompt, steady, and reproducible photocurrent generation when irradiated by white light.     

不同尺寸下再生骨料混凝土直剪性能及其损伤本构

以再生粗骨料取代率、试件尺寸为变化参数,设计并制作了45个再生骨料混凝土试件。通过直剪试验,观察了不同尺寸下再生骨料混凝土的破坏形态,分析了取代率和试件尺寸对再生骨料混凝土直剪性能和损伤本构的影响情况,建立了不同尺寸下再生骨料混凝土的损伤本构模型。结果表明:峰值变形、延性系数均具有明显的尺寸效应,普通混凝土损伤发展速度变慢,再生骨料混凝土损伤发展变快;随取代率的增加,峰值变形先减小后增大,延性系数先增大后减小,损伤发展规律与取代率不成线性关系。采用的本构模型能较好地反映不同尺寸再生骨料混凝土的剪切荷载–变形关系以及损伤演化过程。     

Metastatic Voyage of Ovarian Cancer Cells in Ascites with the Assistance of Various Cellular Components

Epithelial ovarian cancer (EOC) is the most lethal gynecologic malignancy and has a unique metastatic route using ascites, known as the transcoelomic root. However, studies on ascites and contained cellular components have not yet been sufficiently clarified. In this review, we focus on the significance of accumulating ascites, contained EOC cells in the form of spheroids, and interaction with non-malignant host cells. To become resistant against anoikis, EOC cells form spheroids in ascites, where epithelial-to-mesenchymal transition stimulated by transforming growth factor-β can be a key pathway. As spheroids form, EOC cells are also gaining the ability to attach and invade the peritoneum to induce intraperitoneal metastasis, as well as resistance to conventional chemotherapy. Recently, accumulating evidence suggests that EOC spheroids in ascites are composed of not only cancer cells, but also non-malignant cells existing with higher abundance than EOC cells in ascites, including macrophages, mesothelial cells, and lymphocytes. Moreover, hetero-cellular spheroids are demonstrated to form more aggregated spheroids and have higher adhesion ability for the mesothelial layer. To improve the poor prognosis, we need to elucidate the mechanisms of spheroid formation and interactions with non-malignant cells in ascites that are a unique tumor microenvironment for EOC.     

光催化-生物杂合系统设计优化用于燃料和化学品绿色合成

光催化-生物杂合系统耦合了光催化对光能的高收集效率和广谱吸收性能,以及生物催化温和、高效且高特异性转化的优势,可实现多种高值化学品和燃料分子的绿色、可持续合成,符合“碳中和”发展大方向。按照生物催化载体的不同,光催化-生物杂合系统可分为：光催化-生物酶杂合系统和光催化-微生物杂合系统两大类。光催化-生物酶杂合系统根据作用机制细分为：辅因子介导的间接反应体系、直接电子传递的反应体系以及混合型光催化-生物酶杂合系统;光催化-微生物杂合系统分为：直接电子传递的胞外供能模式、化学物质介导的胞外供能模式以及胞内的能量供给模式。对这些模式的具体作用机制,以及存在的优缺点和关键问题做出了综合评述,并对该领域提出了未来展望。     

英国国家公园内住宅建设管控政策研究

住宅是社区管理的重要物质载体,住宅建设管控是国家自然保护地体系建设的重要部分,英国国家公园内住宅建设管控的经验能为我国自然保护地社区管理带来新思路,有助于解决我国自然保护地人口聚居的问题.梳理英国国家公园内住宅建设管控背景,引介英国国家公园内住宅建设管控政策,借鉴强制管制结合柔性引导的管控经验,丰富我国自然保护地体系建设中住宅建设管控的思路.     

电力系统运行课程信息化教学设计实践

针对高职院校电气相关专业的电力系统运行这门专业核心课程,结合信息化手段设计教学过程注重过程化考核,解决了课程理论性较强,学生学不懂、兴趣低、不积极等问题.教学实践证明,该教学设计具有合理性、有效性及可推广性.     

Electrospinning induced ferroelectricity in poly(vinylidene fluoride) fibers

Poly(vinylidene fluoride) (PVDF) fibers with diameters ranging from 70 to 400 nm are produced by electrospinning and the effect of fiber size on the ferroelectric β-crystalline phase is determined. Domain switching and associated ferro-/piezo-electric properties of the electrospun PVDF fibers were also determined. The fibers showed well-defined ferroelectric and piezoelectric properties.     

Extension‐induced mechanical reinforcement in melt‐spun fibers of polyamide 66/multiwalled carbon nanotube composites

In this work, polyamide 66 (PA66) and its composites with multiwalled carbon nanotubes (MWNTs) were melt spun into fibers at different draw ratios. PA66 fibers at high draw ratio demonstrate a 40% increase in tensile strength, 66% increase in modulus and a considerable increase in toughness. It is demonstrated that this reinforcement can be mainly attributed to high‐draw‐ratio‐induced good dispersion and orientation of MWNTs, particularly the enhanced interfacial adhesion between MWNT and matrix thanks to interfacial crystallization. Our work provides a simple but efficient method to achieve good dispersion and strong interfacial interaction through melt spinning. Copyright © 2011 Society of Chemical Industry     

Elevated temperature nanoindentation behaviour of polyamide 6

It has been found, in this study, that there is no close correlation between the tensile and nanoindentation moduli of polyamide 6 (PA6) at high temperatures. It is demonstrated that heat modifies the surface of PA6 specimens, but its effect on the nanomechanical properties is minor. The main spurious factor which affects the nanoindentation results is adhesion, especially at low indentation depths. The overestimation in the measured indentation moduli can be corrected by performing indentations with loads high enough so that the modulus is independent of the applied load. It is concluded that the lack of strict correlations between the tensile and indentation moduli (after corrections of adhesion) is caused by the shift in the glass transition temperature of PA6 owing to the hydrostatic stress imposed by the indenter. Further proof is given with two examples on hydrostatic pressure‐dependent polymers: polytetrafluoroethylene and polycarbonate. Copyright © 2011 Society of Chemical Industry     

PW/MCM-41光催化性能研究

以浸渍法制备了负载型光催化剂PW/MCM-41,并对催化剂进行了表征,考察了催化剂在光催化模拟染料废水亚甲基蓝(MB)溶液降解反应中的催化活性.实验结果表明:催化剂负载量为30％、催化剂投加质量浓度为3.0g/L、MB溶液的初始质量浓度为10 mg/L、pH=5、光照时间100 min时,对亚甲基蓝降解率可达91％以上...