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51.
52.
以Al粉和Ni粉为主要原料,采用自蔓延高温合成技术,制备Ni—Al基金属间化合物。绘制了热爆反应曲线、描述了热爆反应的过程,分析了热爆反应机理及产物的显微组织特征,研究了热爆反应的边界条件以及各种反应参数对热爆反应的影响。研究结果表明,升温速率和颗粒尺寸对热爆反应均有不同程度的影响。提高升温速率、减小颗粒尺寸均可缩短热爆反应的起始时间,降低热爆反应的起始温度。初步确定了反应起始温度低于Ni—Al系的最低共晶温度(640℃),Ni—A1系的热爆反应是由固一固扩散反应引发的,Ni-32Al的反应产物为单相、均一的NiAl相。 相似文献
53.
研究了保温电磁搅拌和间断性电磁搅拌对ZA27合金组织的影响,在保温凝固过程中进行电磁搅拌时,晶粒细化效果更明显。保湿搅拌温度存在搅拌效果最理想的临界值Tc。间断性电磁搅拌使得枝晶显著粒化,晶粒分布更加均匀。 相似文献
54.
文章就数控小孔冲床加工纺织烘干设备中帘子网眼平板产生波浪纹缺陷的原因,进行了全面、详细的理论分析.在排除机床、模具精度影响的基础上,针对压料机构运动误差产生的机理和不利影响,详细分析了网眼冲孔加工产生波浪纹缺陷的根本原因,提出了相应的改进措施,在实践中具有良好的实用效果. 相似文献
55.
Patricia Muñoz-Escalona Shreyes Melkote Kai Liu 《Journal of Materials Engineering and Performance》2005,14(5):582-590
In recent years, the finite element method (FEM) has become the main tool for simulating the metal cutting process because
research based on trial and error is time consuming and requires high investment. Early studies were done by different investigators.
In this research AISI 52100, hardened steel (62 HRC) was selected for an orthogonal machining process as well as metal cutting
simulation using the software DEFORM-2D. This software is based on a forging process and has been adapted to an orthogonal
machining process. The results of simulated cutting forces were compared with experimental cutting force data to validate
the orthogonal cut simulation. Also, the surface roughness was measured, and the influence of the stress, strain, and temperature
on the surface roughness was studied. 相似文献
56.
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58.
Lawrence K. Wang Richard P. Leonard Dennis W. Goupil Mu Hao Wang 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1975,25(7):491-502
Industrial effluents usually include multicomponent organic solutes. The optimum pH for adsorption of a specific industrial effluent on activated carbon should be determined experimentally because, in general, more than one mechanism is involved. A series of experiments was conducted to establish the influence of the initial hydrogen ion concentration on carbon adsorption of organic solutes. For these studies, powdered activated carbon was used, and the water systems studied included both single component pure organic compounds as well as multicomponent organic wastes. Results indicate that the pH effect upon the effectiveness of carbon adsorption mainly depends upon the nature of the adsorbed substance. In general, the degree of ionisation is the controlling factor for adsorption of ionic organic solutes on activated carbon. Adsorption reaches a maximum at the point of least ionisation of the adsorbate. As the organic compounds become more complex (i.e. longer hydrocarbon chains, higher molecular weights, increased branching), the electrical adsorption forces between activated carbon and ionic organic solutes will govern. Anionic surfactants meet with decreased electronegative repulsive forces at low pH levels, which increase the effectiveness of carbon adsorption. However, the adsorption of a cationic surfactant is increased by an increase in the electronegative carbon surface at high pH levels. When ionic organic solutes become much more complex, like a polymer, the effects of both ionisation and electrical adsorption forces become less important. Instead, the adsorption rate will be controlled by the extent of hydrolysis caused by the pH adjustment. For non-ionic organic solutes, chemical reaction(s) between the adsorbate and the added chemical (acid or base) for pH adjustment is an important controlling factor. Again, hydrolysis is responsible for the breakdown of larger size molecules to smaller sizes. Then an increase in adsorption rate with decreasing molecular weight of adsorbate is expected. 相似文献
59.
塑料在包装领域有着广泛的应用,其中聚酯(PET)性能优良,应用领域不断扩大。介绍了塑料包装不断通现的新技术,以及塑料包装环保问题的几点思路。 相似文献
60.
Anders?Falk?VikbjergEmail author Lifeng?Peng Huiling?Mu Xuebing?Xu 《Journal of the American Oil Chemists' Society》2005,82(4):237-242
The possibilities of producing structured phospholipids between soybean phospholipids and caprylic acid by lipase-catalyzed
acidolysis were examined in continuous packedbed enzyme reactors. Acidolysis reactions were performed in both a solvent system
and a solvent-free system with the commercially immobilized lipase from Thermomyces lanuginosa (Lipozyme TL IM) as catalyst. In the packed bed reactors, different parameters for the lipase-catalyzed acidolysis were elucidated,
such as solvent ratio (solvent system), temperature, substrate ratio, residence time, water content, and operation stability.
The water content was observed to be very crucial for the acidolysis reaction in packed bed reactors. If no water was added
to the substrate during reactions under the solvent-free system, very low incorporation corporation of caprylic acid was observed.
In both solvent and solvent-free systems, acyl incorporation was favored by a high substrate ratio between acyl donor and
phospholipids, a longer residence time, and a higher reaction temperature. Under certain conditions, the incorporation of
around 30% caprylic acid can be obtained in continuous operation with hexane as the solvent.
Presented at the 95th American Oil Chemists' Society Annual Meeting and Expo in Cincinnati, Ohio, May 10, 2004. 相似文献