AlN陶瓷表面钛金属化沉积的动力学研究

利用融盐热歧化反应进行了氮化铝陶瓷表面钛金属化沉积的动力学研究.结果表明,氮化铝陶瓷表面钛膜的厚度随着反应温度和反应时间的增加而增加,膜的厚度与反应时间成很好的线性关系,沉积速率与融盐中K2TiF6的起始浓度成线性关系,沉积过程是受融盐与氮化铝陶瓷基体之间的界面反应控制.其沉积过程的活化能为130kJ/mol.     

Synthesis and structure study of copolymers from thiadiazole fused indolocarbazole and dithienosilole

We report synthesis and characterization of two D-A polymers (PSDT-C12 and PSDT-EH) with different side chains. Both polymers are based on alternate 12,13-dioctyl-indolo[2,3-a][1,2,5]thiadiazolo[3,4-c]carbazole (TDZIC) and dithienosilole derivative units in polymer main chain. We used TDZIC to enlarge the 2D conjugated plane of acceptor monomers by fusing benzothiadiazole (BT) unit with an indole unit having alkyl groups. PSDT-C12 exhibited 10 nm redshift compared to PSDT-EH in solid films, while their absorption spectra were almost identical in solutions. Since the backbone and side chains on the indolocarbazole group are the same, the redshift on PSDT-C12 could be resulted from the dodecyl (C12) side chain on the dithienosilole unit and different molecular weight between these two polymers. PSDT-C12 has a larger molecular weight than PSDT-EH. Therefore possibly both side chains and molecular weight contributed to the difference in the absorption spectra in solid films. The straight C-12 side chain has less steric hindrance than the branched EH side chain in solid films. PSDT-C12 has a longer main chain (larger molecule weight) than PSDT-EH, which can favour a more extended main chain interaction. The vibronic peak at 519 nm and shoulder at 563 nm in the PSDT-C12 film further confirmed stronger main chain interaction. Geometry optimization showed that head–tail (HT)-PSDT had a more twisting conjugated backbone with larger dihedral angle between dithienosilole unit and thiadiazole-fused ring compared to head–head/tail–tail (HH/TT)-PSDT.     

高动态高码速率全数字化解扩接收机的设计

为了解决在高动态环境下进行扩频通信时高处理增益和短初捕时间之间的矛盾,对高动态环境下的伪码快捕跟踪算法和载波跟踪技术进行了研究。研究了串并组合的伪码快捕方法和FLL与PLL相结合的动态载波跟踪技术;在此基础上,设计完成了一种高集成度的全数字化解扩接收机。     

利用波面水泥熟料冷却器回收能量

对波面水泥熟料冷却器的设计参数和经济指标进行了评价,论证了它用于能量回收的可行性,为水泥熟料冷却能量的回收提供了一条途径。     

Cr、Ni/γ-Al_2O_3-SiO_2催化聚合α-烯烃制润滑油基础油

研究了新型α-烯烃聚合制润滑油基础油的催化剂。在最佳实验条件下考察了活性组分负载量、磷酸含量、水蒸气处理时间及H_2还原时间的不同对催化性能的影响。结果表明,当活性组分Ni、Cr质量比为4时,产品运动粘度(20℃)最大,向载体中添加酸性组分,增强了其对Cr、Ni/r-Al_2O_3-SiO_2催化剂的调变作用,当酸体积分数为7％时催化剂活性最高。水蒸气处理时间不同时催化剂活性影响不同,但与未处理的催化剂性能相比较,活性有了显著提高,当水蒸气处理时间为40h时,产品的运动粘度达到最大。氢气还原处理可将催化剂中负载的金属还原为较低价态,增强了催化剂的活性,同时该催化剂再生性能较好,再生后催化剂的稳定性及寿命均优于新鲜催化剂。     

Analysis on improvement of dynamic slot assignment for wireless ATM network

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Dynamic movement-based location update in LEO networks

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高频超声降解对硫磷的反应动力学及机理

研究了高频超声降解水溶液中对硫磷的反应动力学以及机理.引入拟一级反应动力学模型以及响应面方法对对硫磷初始浓度、超声功率以及频率对对硫磷降解效果的影响进行评估.经过响应面实验设计和实验以及对拟合的二次模型分析发现,拟合模型显著(P=0.000 2),且拟合不足不显著(P=0.113 6),相关系数平方R2=0.973 3,表明模型具有较好的回归性.对于对硫磷降解拟一级动力学表观速率系数具有显著性影响的一次项为超声功率值以及对硫磷的初始浓度值,二次项为超声频率值,交互项均不显著.在实验研究的超声功率、频率以及对硫磷初始浓度范围内,对硫磷降解拟一级动力学表观速率系数随超声功率的增大而减小,随初始浓度的增大而减小,并且存在一个最优的降解频率.     

覆盖特定区域的中轨卫星移动通信系统常规星座优化设计

通过综合分析卫星移动通信系统星座设计方法 ,结合具体问题 (覆盖东径 75～ 10 5° ,北纬 3～ 5 4°区域 ) ,分别根据区域性覆盖、地带性覆盖和全球性覆盖星座设计思想 ,利用圆极轨道和倾斜圆轨道进行了分析与设计 ,从中得出覆盖指定区域的中轨道全天候持续覆盖常规卫星星座的优化设计结果 ,并证明了考虑轨道间卫星相位关系的地带性星座设计方法的优越性