放电等离子烧结Fe3B／（Pr,Tb）2Fe14B块体纳米晶双相复合永磁体的性能

采用放电等离子烧结技术将非晶Pr4.2Tb0.3Fe78B17.5薄带制备成块状纳米晶复合磁体。研究了烧结条件对磁体密度、微观结构和磁性能的影响。结果表明，烧结温度的升高可使磁体得到高致密度，但同时由于其晶粒长大，结果导致磁性能的恶化。在最佳烧结条件下得到磁体的磁性能为Br=1．02T，JHc=220kA／m。磁体具有较好的微观结构，平均晶粒尺寸为20nm。     

Corrosion of Three Commercial Steels Under ZnCl2 –KCl Deposits in a Reducing Atmosphere Containing HCl and H2S at 400–500°C

The corrosion of three commercial steels in a reducing atmosphere containing HCl plus H₂S in the presence of ZnCl₂–KCl deposits has been investigated at 400–500°C and compared with the corrosion of the same materials in a similar gas mixture free from H₂S. The presence of H₂S in the gas accelerated the corrosion of the three commercial steels beneath ZnCl₂–KCl deposits. All materials suffered from severe corrosion with partial detachment and spalling of the external scales. Degradation of the steels resulted from the penetration of chlorine-containing species through the scale formed initially down to the metal matrix, because chorine-rich species were detected close to the alloy/scale interface. Although the corrosion resistance generally increased with increasing Cr content, even the high-Cr stainless steel SS304 is still unable to provide good corrosion resistance against the ZnCl₂–KCl deposits in the presence of H₂S due to the bad adherence of the scales to the alloy. The mechanisms of attack are discussed on the basis of thermodynamic considerations and of the active-oxidation model.     

P型Sr0．5Co4-xFexSb12化合物的制备及高温热电性能

采用熔融法结合放电等离子烧结（SPS）技术合成了P型填充方钴矿化合物Sr0．5Co4-xFexSb12，并研究了Fe掺杂对该化合物高温热电性能的影响。采用X．射线衍射（XRD）及电子探针（EPMA）表征了化合物的物相及化学成分，在300～850K温度范围内测试了化合物的电导率、赛贝克系数和热导率，采用Vande Pauw方法测试了化合物的室温载流子浓度。实验结果表明，化合物的主要相组成为Sr0．5Co4-xFexSb12方钴矿相，同时含有少量FeSb2和CoSb2杂质相。化合物的赛贝克系数均为正值，表明为空穴导电。随着Fe掺杂量的增加，化合物的载流子浓度及电导率增加，赛贝克系数降低，晶格热导率降低，最小室温晶格热导率为1．97 Wm^-1K^-2。对于化合物Sr0．5Co2.32Fe1.68Sb12在850K时获得的最大热电性能指数ZT约为0．60。     

对Al-Cu合金中α-Al及Al2Cu生长行为的探讨

研究了Al-Cu合金中α-Al和Al2Cu的生长行为,分析了初生α-Al及初生Al2Cu作为共晶核心形核的能力.结果发现,在过共晶组织中,初生相Al2Cu形貌大部分有明显的拐角,观察其平面有的呈矩形,呈现小面生长特性.而α-Al与Al2Cu共晶生长时,Al2Cu择优生长特征削弱,与α-Al耦合生长呈现非小面-非小面生长,表明Al2Cu在不同的生长阶段表现出的生长行为不同.在亚共晶组织中,初生相α-Al周围形成离异共晶的Al2Cu,而过共晶组织中初生相Al2Cu周围没有离异共晶的α-Al,表明初生相Al2Cu作为共晶层片核心的能力比初生相α-Al作为共晶层片核心的能力强.     

An analysis of the internal oxidation of binary M-Nb alloys under low oxygen pressures at 600–800°C

The corrosion of M–Nb alloys based on iron, cobalt, and nickel and containing 15 and 30 wt% Nb has been studied at 600–800°C under low oxygen pressures (10^–24 atm at 600°C and 10^–20 atm at 700–800°C). Except for the Co–Nb and Ni–Nb alloys corroded at 800°C, which formed external scales of niobium oxides, corrosion under low O₂ pressures produced an internal oxidation of niobium. This attack was much faster than expected on the basis of the classical theory. Furthermore, the distribution of the internal oxide in the alloys containing two metal phases was very close to that of the Nb-rich phase in the original alloys. These kinetic, microstructural, and thermodynamic aspects are examined by taking into account the effects of the limited solubility of niobium in the various base metals and of the two-phase nature of the alloys.     

Vogel—Fulcher定律与玻璃转变温度的关系

通过在不同加热速度，不同坩埚材料和不同样品质量条件下测定Ｉｎ，Ｚｎ，Ｓｎ，Ｐｂ等元素的熔点，校正了加热速度对差示扫描量热仪显示温度的影响。根据对仪器温度校正的结果，研究了Ｎｉ３３Ｚｒ６７，Ｚｒ６５Ａｌ７．５Ｎｉ１０Ｃｕ１５Ｃｏ２．５，Ｐｔ６９．０Ｎｉ９．６Ｐ２１．４，聚醚砜和聚苯乙烯等材料的玻璃转变的动力学特征。     

The oxidation of two Fe−Nb alloys under low oxygen pressures at 600–800°C

The oxidation of two Fe–Nb alloys containing 15 and 30 wt.% Nb has been studied at 600–800°C under low oxygen pressures, similar to those prevailing in environments of the coal-gasification type. The reaction produced only an internal oxidation of niobium to form two niobium oxides (NbO₂ and Nb₂O₅) and in some cases a double Fe–Nb oxide. The kinetics of this reaction were very slow at 600°C but rather fast at 700 and 800°C. A peculiar feature of the internal oxidation of these alloys is that the distribution of the internal oxides follows closely that of the Nb-rich phase in the original two-phase alloys. This behavior, as well as the lack of formation of external scales of niobium oxides, is mainly a result of the limited solubility of niobium in iron and of the consequent presence of two metal phases in the alloys.     

Fe—Cr—Ni—Mo—C阀座材料的时效硬化及时效过程中的相转变

Fe-18.2Cr-6.9Ni-2.5Mo-1.5C材料铸态组成相为奥氏体和M7C_3型碳化物,在随后加热时可产生时效硬化现象,最佳时效温度为650℃。时效过程中可产生α-铁索体和M_23C_6型碳化物两个新相。     

金刚石修整滚轮CAD/CAPP集成技术研究

金刚石修整滚轮是目前最为有效的高效、高精砂轮成形修整工具，迎合了磨削技术高精、高速和高效发展趋势，内电镀高精度修整滚轮制造工艺复杂、工序多，影响制造精度因素较多，修整参数选择、滚轮图纸设计和工艺编制是生产中的关键环节。本文从分析金刚石修整滚轮设计制造的特点人手，应用CAD／CAPP集成技术实现了金刚石修整滚轮设计、工艺规程编制和技术文件管理的自动化，提高了滚轮制造工艺水平和对产品质量的控制能力，较好地解决了一些设计和工艺过程相对简单、变化较小的定型产品的CAD／CAPP集成化的问题。     

用胶粘代替点焊工艺

采用点焊工艺生产拖拉机机罩，点焊压痕影响了外观质量，通过对几种方案的探讨和大量的胶粘试验，确定了一种用结构胶粘结代替点焊的工艺，该工艺使制件的外观质量得以大幅度提高，而生产成本则明显降低。