The role of conductive pathways in the conductivity and rheological behavior of poly(methyl methacrylate)–graphite composites

Up to now, research on the dynamic process of conductive network formation has tended to focus on composite particles with one‐dimensional geometry, such as carbon black and carbon nanotubes. However, studies on this subject based on fillers with two‐dimensional structure, such as graphite, are rare in the literature. In this work, the dynamic percolation and rheological properties of poly(methyl methacrylate) (PMMA)–graphite composites under an electric field were investigated. The activation energies of conductive network formation and polymer matrix mobility were calculated from the temperature dependence of the percolation time and the zero‐shear viscosity. It was found that the activation energy calculated from the zero‐shear viscosity was not influenced by the electric field in the concentration range investigated, but the electric field had an effect on the activation energy calculated from the percolation time. This finding emphasizes that the electrical and rheological properties have different physical origins. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43810.     

Structural and Electrical Characteristics of (1−x)Pb(Lu1/2Nb1/2)O3–xPbTiO3 Ceramics with Low PbTiO3

A solid solution of (1?x)Pb(Lu_1/2Nb_1/2)O₃–xPbTiO₃ with composition of 0.01 ≤ x ≤ 0.08 have been prepared successfully. XRD analysis indicates the crystal structure adopts an orthorhombic (O) phase in 0.01 ≤ x ≤ 0.06 interval and becomes the coexistence of O and rhombohedral (R) phase at x = 0.07, then turns into R phase mostly at x = 0.08. In addition, two sets of superlattice reflections due to B‐site ordering and antiparallel cation displacement are distinguished by XRD and the superstructures which arise from antiparallel cation displacement disappear gradually with the increasing x. The grain size increases gradually with the increasing x, and then becomes the bimodal microstructure at x ≥ 0.06 due to the coexistence of O and R phase. The dielectric spectra exhibit Curie temperature decreases from 248°C to 147°C with increasing x from 0.01 to 0.08. As 0.01 ≤ x ≤ 0.04, the samples display typical double hysteresis loops, suggesting antiferroelectric nature, then turn into ferroelectric gradually at x = 0.05. Finally, it exhibit typical ferroelectric hysteresis loops in 0.06 ≤ x ≤ 0.08 interval.     

Gas‐liquid mass transfer behavior in a surface‐aerated vessel stirred by a novel long‐short blades agitator

For a recently developed long‐short blades (LSB) agitator, its critical rotational speed for the onset of gas entrainment, power number, and gas‐liquid mass transfer behavior in the case of surface aeration is investigated. The effect of the LSB configurations and the liquid level on the agitator performance has been studied in details. The obtained results clearly show several advantages of the LSB agitator in gas‐liquid mass transfer with respect to the agitators in the literature. It is found that its gas‐liquid volumetric mass‐transfer coefficient at a given specific power can be several times larger than those shown in the literature. It can also avoid decrease in the gas‐liquid mass transfer rate as the liquid level increases. In addition, the bubble distribution in the system is more uniform with respect to conventional agitators, resulting from better distribution of the dissipated energy for the LSB agitator. © 2015 American Institute of Chemical Engineers AIChE J, 62: 1322–1330, 2016     

Thermoplastic polyvinyl alcohol/multiwalled carbon nanotube composites: Preparation,mechanical properties,thermal properties,and electromagnetic shielding effectiveness

This study uses the solution mixing method to combine plasticized polyvinyl alcohol (PVA) as a matrix, and multiwalled carbon nanotubes (MWCNTs) as reinforcement to form PVA/MWCNTs films. The films are then laminated and hot pressed to create PVA/MWCNTs composites. The control group of PVA/MWCNTs composites is made by incorporating the melt compounding method. Diverse properties of PVA/MWCNTs composites are then evaluated. For the experimental group, the incorporation of MWCNTs improves the glass transition temperature (T_g), crystallization temperature, T_c), and thermal stability of the composites. In addition, the test results indicate that composites containing 1.5 wt % of MWCNTs have the maximum tensile strength of 51.1 MPa, whereas composites containing 2 wt % MWCNTs have the optimal electrical conductivity of 2.4 S/cm, and electromagnetic shielding effectiveness (EMI SE) of ?31.41 dB. This study proves that the solution mixing method outperforms the melt compounding method in terms of mechanical properties, dispersion, melting and crystallization behaviors, thermal stability, and EMI SE. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43474.     

乘用车橡胶密封条气味研究

为找到密封条气味的来源,采用气相色谱-质谱联用仪对气味成分进行检测和分析,将气味的来源锁定在与成分相关的三元乙丙橡胶(EPDM)配方中的发泡剂、石蜡油、促进剂三种物质。通过进一步的对比实验,确认改进这三种物质的措施对降低气味是有效的:发泡剂的含量减少0.92份,气味等级平均值提升0.9级;若不使用发泡剂偶氮二甲酰胺ADCA,则气味等级提高0.3级;用闪点高、芳香烃含量低的石蜡油,气味等级平均值提升1.6级;使用无亚硝胺硫化体系,气味等级提高0.8级。这三种措施都能使气味等级达到标准要求的6级及以上。     

放样技术在承重瓦刮削中的应用

鲁碧公司的PEJ900×1200颚式破碎机传动主轴轴承内衬由巴氏合金制成,维修时刮研要求比较高。利用放样拉线法测量承载区域,阐述了该方法的主要实施步骤。效果表明,该方法简单有效,使检修作业效率提升显著,职工劳动强度大幅降低,提高了检修的精准度与可控性。     

Human-tracking strategies for a six-legged rescue robot based on distance and view

Human tracking is an important issue for intelligent robotic control and can be used in many scenarios, such as robotic services and human-robot cooperation. Most of current human-tracking methods are targeted for mobile/tracked robots, but few of them can be used for legged robots. Two novel human-tracking strategies, view priority strategy and distance priority strategy, are proposed specially for legged robots, which enable them to track humans in various complex terrains. View priority strategy focuses on keeping humans in its view angle arrange with priority, while its counterpart, distance priority strategy, focuses on keeping human at a reasonable distance with priority. To evaluate these strategies, two indexes(average and minimum tracking capability) are defined. With the help of these indexes, the view priority strategy shows advantages compared with distance priority strategy. The optimization is done in terms of these indexes, which let the robot has maximum tracking capability. The simulation results show that the robot can track humans with different curves like square, circular, sine and screw paths. Two novel control strategies are proposed which specially concerning legged robot characteristics to solve human tracking problems more efficiently in rescue circumstances.     

Nondestructive testing and characterization of residual stress field using an ultrasonic method

To address the difficulty in testing and calibrating the stress gradient in the depth direction of mechanical components, a new technology of nondestructive testing and characterization of the residual stress gradient field by ultrasonic method is proposed based on acoustoelasticity theory. By carrying out theoretical analysis, the sensitivity coefficients of different types of ultrasonic are obtained by taking the low carbon steel(12%C) as a research object. By fixing the interval distance between sending and receiving transducers, the mathematical expressions of the change of stress and the variation of time are established. To design one sending-one receiving and oblique incidence ultrasonic detection probes, according to Snell law, the critically refracted longitudinal wave (LCR wave) is excited at a certain depth of the fixed distance of the tested components. Then, the relationship between the depth of LCR wave detection and the center frequency of the probe in Q235 steel is obtained through experimental study. To detect the stress gradient in the depth direction, a stress gradient LCR wave detection model is established, through which the stress gradient formula is derived by the relationship between center frequency and detecting depth. A C-shaped stress specimen of Q235 steel is designedto conduct stress loading tests, and the stress is measured with the five group probes at different center frequencies. The accuracy of ultrasonic testing is verified by X-ray stress analyzer. The stress value of each specific depth is calculated using the stress gradient formula. Accordingly, the ultrasonic characterization of residual stress field is realized. Characterization results show that the stress gradient distribution is consistent with the simulation in ANSYS. The new technology can be widely applied in the detection of the residual stress gradient field caused by mechanical processing, such as welding and shot peening.     

超声电机直驱的电动物镜控制方法

针对超声电机直接驱动的显微镜物镜为满足系统整体结构紧凑、快速和准确定位的需求,采用小型光电耦合器设计了位置检测传感器,配合遮挡片实现了物镜位置和物镜转换器运动方向的检测。采用传统比例-积分-微分控制(proportion-integral-derivative control,简称PID)和模糊控制提出了并行切换控制策略,将两者结合建立了宏微相融合的预测控制方法,实现了物镜转换器的高精度、快速切换控制。在嵌入式控制系统中实现了所设计的控制算法和策略,并进行了物镜自动切换控制实验。实验结果显示,采用笔者提出的定位结构和控制方法,电动物镜转换器的重复定位误差小于0.015°,定位时间小于3s,满足自动显微镜系统中对电动物镜转换器重复定位精度的要求。