Janus‐Structured Co‐Ti3C2 MXene Quantum Dots as a Schottky Catalyst for High‐Performance Photoelectrochemical Water Oxidation

MXene materials have attracted increasing attention in electrochemical energy‐storage applications while MXene also becomes photo‐active at the quantum dot scale, making it an alternative for solar‐energy‐conversion devices. A Janus‐structured cobalt‐nanoparticle‐coupled Ti₃C₂ MXene quantum dot (Co‐MQD) Schottky catalyst with tunable cobalt‐loading content serving as a photoelectrochemical water oxidation photoanode is demonstrated. The introduction of cobalt triggers concomitant surface‐plasmon effects and acts as a water oxidation center, enabling visible‐light harvesting capability and improving surface reaction kinetics. Most importantly, due to the rectifying effects of Co‐MQD Schottky junctions, photogenerated carrier separation/injection efficiency can be fundamentally facilitated. Specifically, Co‐MQD‐48 exhibits both superior photoelectrocatalysis (2.99 mA cm^?2 at 1.23 V vs RHE) and charge migration performance (87.56%), which corresponds to 194% and 236% improvement compared with MQD. Furthermore, excellent photostability can be achieved with less than 6.6% loss for 10 h cycling reaction. This fills in gaps in MXene material research in photoelectrocatalysis and allows for the extension of MXene into optical‐related fields.     

应用纵向分区彩虹全息术合成断层图像的三维消色像

报道了应用纵向分割多狭缝曝光彩虹全息术合成多幅断层图像为三维消色像的方法及其实验结果。通过将主全息图记录狭缝按纵向分割并结合使用循环分割和色散补偿光栅 ,实现了在较高的分辨率和较低色模糊的多幅断层像的白光三维消色像的合成 ,并提高了再现像的视觉亮度、视场和立体感。     

Toward High‐Performance Hybrid Zn‐Based Batteries via Deeply Understanding Their Mechanism and Using Electrolyte Additive

Aqueous hybrid Zn‐based batteries (ZIBs), as a highly promising alternative to lithium‐ion batteries for grid application, have made considerable progress recently. However, few studies have been reported that investigate their working mechanism in detail. Here, the operando synchrotron X‐ray diffraction is employed to thoroughly investigate the operational mechanism of a hybrid LiFePO₄(LFP)/Zn battery, which indicates only Li⁺ extraction/insertion from/into cathode during cycling. Based on this system, a cheap electrolyte additive, sodium dodecyl benzene sulfonate, is proposed to effectively enhance its electrochemical properties. The influence of the additive on the Zn anode and LFP cathode is comprehensively studied, respectively. The results show that the additive modifies the intrinsic deposit pattern of Zn²⁺ ions, rendering Zn plating/stripping highly reversible in an aqueous medium. On the other hand, the wettability of the LFP electrode is visibly a meliorated by introducing the surfactant additive, accelerating the Li‐ion diffusion at the LFP electrode/electrolyte interface, as indicated by the overpotential measurements. Benefiting from these effects, the Zn/LFP batteries deliver high rate capability and cycling stability in both coin cells and pouch cells.     

基于数据挖掘的电力云资源规划调度

随着虚拟化技术的应用,数据中心的资源利用率已经得到一定程度的提高,但是云资源通常还是根据用户提出的需求预先分配,资源利用率仍然有待提高.为了进一步改进资源利用率,云中心的实际资源需求可分为“周期资源”及“峰期资源”.“周期资源”可以通过历史规律,利用递阶成分负载模型进行分析,预测出数据中心大部分时间的资源需求;“峰期资源”主要是满足短时间内的各种高峰资源需求,这种需求应用了排队论及随机均衡算法模型并根据实际应用的需要动态启用、分配和收回资源.通过使用资源收集与分配守护进程对云中心资源需求进行规划调度实验,效果明显,从而为云中心资源利用率的提升及节能减排提供了一种有效途径.     

TD-SCDMA网络重要性浅谈

在国内4G快速发展的背景下,3G网络逐步被取代以承载移动宽带用户的数据流量,因而国内涌现了很多认为3G网络如TD-SCDMA已过时的观点,本文通过对中国移动现网用户的数据承载、自主知识产权技术积累、国内外通信体制的博弈、国内4G的发展和人才培养等方面进行分析,显示了TD-SCDMA仍发挥着重要的作用。     

Tungsten‐Based Materials for Lithium‐Ion Batteries

Lithium‐ion batteries are widely used as reliable electrochemical energy storage devices due to their high energy density and excellent cycling performance. The search for anode materials with excellent electrochemical performances remains critical to the further development of lithium‐ion batteries. Tungsten‐based materials are receiving considerable attention as promising anode materials for lithium‐ion batteries owing to their high intrinsic density and rich framework diversity. This review describes the advances of exploratory research on tungsten‐based materials (tungsten oxide, tungsten sulfide, tungsten diselenide, and their composites) in lithium‐ion batteries, including synthesis methods, microstructures, and electrochemical performance. Some personal prospects for the further development of this field are also proposed.     

无线传感网络中的动态集群密钥管理方案

Wireless sensor networks are open architectures, so any potential threat can easily intercept, wiretap and counterfeit the information. Therefore, the safety of WSN is very important. Since any single key system cannot guarantee the security of the wireless sensor network for communications, this paper introduces a hierarchical key management scheme based on the different abilities of different sensor nodes in the clustered wireless sensor network. In this scheme, the nodes are distributed into several clusters, and a cluster head must be elected for each cluster. Private communication between cluster heads is realized through the encryption system based on the identity of each head while private communication between cluster nodes in a same cluster head is achieved through the random key preliminary distribution system. Considering the characteristics of WSN, we adopt dynamic means called dynamic cluster key management scheme to deal with master key, so master key will be updated according to the changed dynamic network topology. For cluster head node plays a pivotal role in this scheme, a trust manage-ment system should be introduced into the election of the cluster head which will exclude the malicious node from outside the cluster, thus improve the whole network security.     

刻纹光纤传感器的原理及灵敏度分析

介绍了一种新型的光纤传感器，采用热刻-酸蚀法在光纤上形成一些周期性刻纹结构，使得感受应变量的部分成为光纤本身的固有结构。这种光纤传感器具有线性、可重复的输入、输出响应且没有滞后效应，与其它传感器相比其最大的优点是灵敏度高、外形尺寸小。     

一种新型基于石英的热光型光开关

一种采用基于石英的平面光波回路技术（PLC）制造的热光型光开关正越来越引起关注，它具有低耦合损耗、高稳定性及适于大规模集成等优点。首先描述了采用热光相移器构成马赫-曾德于涉仪（MZI）结构的热光型光开关，然后讨论2×2MZI热光型开关的工作原理及基本特性，最后介绍了由2×2MZI热光型开关单元构成的大规模光开关阵列以及一种采用悬梁式结构热光相移器的低功率消耗的光开关。     

无线数据通信网发展趋势

无线数据通信具有两大发展趋势，即低速的广域移动数据网及高速的局域无线数据网。本文介绍了其技术特点、应用情况和市场前景，分析了无线数据通信传输技术、网络结构和媒质接入控制等问题。