硝酸废热锅炉的腐蚀与防腐

结合本厂硝酸装置的实际，分析废热锅炉的腐蚀机理，介绍硝酸废热锅炉的防腐措施。     

Tungsten Oxide Nanorods Array and Nanobundle Prepared by Using Chemical Vapor Deposition Technique

Tungsten oxide (WO₃) nanorods array prepared using chemical vapor deposition techniques was studied. The influence of oxygen gas concentration on the nanoscale tungsten oxide structure was observed; it was responsible for the stoichiometric and morphology variation from nanoscale particle to nanorods array. Experimental results also indicated that the deposition temperature was highly related to the morphology; the chemical structure, however, was stable. The evolution of the crystalline structure and surface morphology was analyzed by scanning electron microscopy, Raman spectra and X-ray diffraction approaches. The stoichiometric variation was indicated by energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy.     

Lattice-based key exchange on small integer solution problem

In this paper, we propose a new hard problem, called bilateral inhomogeneous small integer solution （Bi-ISIS）, which can be seen as an extension of the small integer solution problem on lattices. The main idea is that, instead of choosing a rectangle matrix, we choose a square matrix with small rank to generate Bi-ISIS problem without affecting the hardness of the underlying SIS problem. Based on this new problem, we present two new hardness problems： computational Bi-ISIS and decisional problems. As a direct application of these problems, we construct a new lattice-based key exchange （KE） protocol, which is analogous to the classic Diffie- Hellman KE protocol. We prove the security of this protocol and show that it provides better security in case of worst-case hardness of lattice problems, relatively efficient implementations, and great simplicity.     

Probabilistic and interval reliability design of the composite pressure vessel

Considering the randomness or interval character of physical parameters and applied loads of composite pressure vessels (COPV), the COPV reliability-analyzing model is built. And then the computational expressions for the mean value, standard deviation and deviation of fiber stress are deduced by the random factor method. The probabilistic and interval reliability designs on COPV are implemented by utilizing the probabilistic method and interval method combined with the improved particle swarm optimization (PSO) algorithm, respectively. The influence of fluctuation of structure uncertain parameters on COPV design thickness is inspected. Finally, examples are given to demonstrate that both probabilistic and interval reliability methods can satisfy the safety requirement and both are of higher rationality than the traditional safety factor method. And probabilistic method has a lower relative error but a higher computational complexity contrasted with the interval method.     

基于社会和文化可持续性的城市设计价值观重塑

可持续发展是环境、社会、经济和文化可持续性四个支柱之间的平衡发展.其中,无论是理论研究还是政策分析,社会可持续性和文化可持续性作为可持续发展的重要支柱一直受到忽视,城市设计领域也不例外.我们从社会可持续性和文化可持续性两个维度探讨了城市设计价值观的重塑问题.从社会可持续性视角看,城市设计需要建构以公平的空间资源分配为核心的价值观,具体表现在两个方面,即和谐宜居观与环境正义观.基于文化可持续性的城市设计价值观,核心是尊重城市文化多样性,它是城市保持活力的命脉以及城市可持续发展的源泉.     

Optimization of uncertain acoustic metamaterial with Helmholtz resonators based on interval model

Uncertainties existing in the acoustic metamaterial may strongly affect its unusual properties. Aiming at this actuality, the interval model is introduced to treat with uncertainties existing in the acoustic metamaterial with Helmholtz resonators. Frequency intervals in which the sound intensity transmission coefficients are certainly less than the required value and the effective bulk moduli are certainly negative are defined as conservative approximations. Frequency intervals in which the sound intensity transmission coefficients may be less than the required value and the effective bulk moduli may be negative are defined as unsafe approximations. The proportion of the conservative approximation and the unsafe approximation is defined as an approximate precision. Based on the quantification of uncertainties of the sound intensity transmission coefficients and the negative effective bulk moduli, an optimization model for the interval acoustic metamaterial with Helmholtz resonators is constructed. Numerical results showed that even suffering from effects of interval parameters, unusual properties of the optimized acoustic metamaterial (such as the bandgap of the sound transmission and the negative effective bulk modulus) could be improved.     

频率响应法研究噻吩在CeY分子筛上的吸附行为

以NaY、液相Ce离子交换改性的Y型分子筛(L-CeY)为研究对象,运用N2吸附、XRD、NH3-TPD和Py-FTIR等实验方法表征两种Y型分子筛的物化性能。采用频率响应技术(FR)和智能重量分析仪(IGA)研究噻吩在两种分子筛上的吸附行为,并考察噻吩在稀土离子改性Y型分子筛上的不同吸附作用模式。结果表明,频率响应技术能够有效识别分子筛孔道内发生的不同传质过程。噻吩在NaY分子筛上的吸附行为较为简单,存在孔道吸附和π电子相互作用两种吸附过程;而在L-CeY分子筛上吸附行为较为复杂,同时存在孔道吸附和"S-M"吸附等多种吸附过程,另外,在高温条件下,还存在复杂的催化反应过程。     

南通高职院校学生创业状况研究

探讨了当前普及的大学生创业教育的成功与不足之处.采取发放问卷、走访创业机构和校园随访等方式综合获得南通地区高职生创业状况的调研结果,根据结果提出了相应对策,以期真正提升高职学生创业素养,提高他们的创业成功率.     

当前网络政治参与中存在的问题与对策

针对我国当前网络政治参与中存在着非法参与行为多、政务信息不公开致使公众政治参与缺乏信息基础、政府对公众网络政治参与的行为与观点缺乏回应等问题,本文提出了采取完善政治参与和网络政治参与的法治化机制,建立健全网络参政相关法规,保障公民网络参政议政权益,规范和打击非法政治参与行为;修改政府信息公开的法律法规,加大政府信息公开力度与规范网络监督机制;建立政府对公民网络政治参与的回应制度,以解决公民网络政治参与的相关问题,推动法治文明.     

Preparation and characterization of TiO2 photoelectrode codoped with aluminum and boron and its application in dye-sensitized solar cell

Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%.