不同形式电压下高压直流电缆试验终端电场与空间电荷分布计算

试验终端是高压直流电缆电气性能试验的重要组成部分,该文基于交流电缆水终端建立了直流电缆水油终端模型,并得到了直流电场下的电场和电荷分布.为研究不同形式电压下高压直流水油终端中电场强度及其电荷密度分布,首先建立了水油终端电场-空间电荷仿真模型,该模型考虑了空间电荷的注入以及空间电荷和电场的相互作用;接着将仿真结果与试验进行对比,以验证模型的正确性;随后,基于该仿真模型分析了直流电压及6种不同形式冲击电压下水油终端的电场强度、电荷密度分布规律,并与GB/T 31489.1规定的6种冲击电压下水油界面处的场强与电荷密度进行比较.结果 表明,雷电冲击电压在水油界面上产生的场强幅值最大,超过了水的击穿场强.因此水油终端不适用于雷电冲击试验.论文研究可为高压直流试验终端的研发提供参考.     

A “Three-in-One” Multifunctional Probe for Bcl-2/Mcl-1 Profiling and Visualizing in Situ

Bcl-2 and Mcl-1, the two arms of the anti-apoptotic Bcl-2 family proteins, have been identified as key regulators of apoptosis and effective therapeutic targets of cancer. However, no small-molecular probe is capable of profiling and visualizing both Bcl-2 and Mcl-1 simultaneously in situ. Herein, we report a multifunctional molecular probe (BnN₃-OPD-Alk) by a “three-in-one” molecular designing strategy, which integrated the Bcl-2/Mcl-1 binding ligand, fluorescent reporter group and photoreactive group azido into the same scaffold. BnN₃-OPD-Alk exhibited sub-micromolar affinities to Bcl-2/Mcl-1 and bright green self-fluorescence. It was then successfully applied for Bcl-2/Mcl-1 labeling, capturing, enriching, and bioimaging both in vitro and in cells. This strategy could facilitate the precise early diagnosis and effective therapy of dual Bcl-2/Mcl-1-related diseases.     

深冷处理与工模具的耐磨性

热处理后的金属材料再经低落曙处理，其力学能明显提高，尤其是高碳高合金工模具钢的耐磨性提高特别显著。本文着重研究了应用面较广的Ｗ６Ｍｏ５Ｃｒ４Ｖ２钢的处理工艺制度，组织性能及其磨损机理。     

Study on the flash butt welding of 400 MPa ultra-fine grain steel

A 400 MPa ultra-fine grain steel possesses high strength and toughness. Due to its fine grain size, the heat affect zone (HAZ) of the weld joint will soften during welding. The weldability of 400 MPa ultra-fine reinforced steel bar of flash butt welding is investigated by using the micro metallographical examination and macro-mechanical-property tests. The joint of flash butt welding has a superior mechanical property. The HAZ in the weld joint does not show apparent softening. There is only a localized softening spot inside the weld seam, which does not affect the property of the whole joint. Therefore, flash butt welding is appropriate for joining the 400 MPa ultra-fine grain reinforced steel bars. The resulting weld joint has excellent mechanical properties.     

定向凝固高铬铸铁Cr28的组织和腐蚀磨损性能

研究了定向凝固工艺制备的高铬铸铁Cr28的组织和性能,并将其与普通砂型铸造制备的高铬铸铁Cr28及Cr15Mo3进行比较。结果表明:本实验中所采用的简易定向凝固工艺能够实现高铬铸铁碳化物的定向排列,且与激冷面距离不同处,碳化物形态、分布和平均间距不同;在高温热强碱冲蚀磨损实验中,垂直于磨损面定向排列且分布较均匀的碳化物能使定向凝固高铬铸铁具有更好的耐磨蚀性能,碳化物平均间距λ在16~17μm之间时其耐磨蚀性能最佳;相对硬度而言,定向凝固得到的定向排列的碳化物对材料耐磨蚀性的影响更为突出。     

氧化铝增强无机硅酸锌涂层的电化学阻抗谱研究

无机硅酸锌涂层是一种广泛使用的钢铁重防腐涂层。采用在涂料填料中加入氧化铝的方法可以得到具有更好耐磨性能的富锌涂层。本实验研究利用电化学阻抗谱法(EIS)研究了氧化铝的加入对涂层腐蚀防护性能的影响,结果表明氧化铝颗粒的加入使涂层的腐蚀防护性能略有提高。     

Unique Dielectric Behavior of 0.6Pb(Ni1/2W1/2)O3·0.4PbTiO3 Derived from Mechanical Activation

0.6Pb(Ni_1/2W_1/2)O₃·0.4PbTiO₃(0.6PNW·0.4PT) of complex perovskite structure is successfully synthesized by mechanical activation of mixed oxide composition, followed by sintering at 950°C. It exhibits a considerably stable temperature dependence of dielectric constant over the wide temperature range of −120° to 20°C, although there occurs a dielectric peak at around 74°C. Raman spectroscopic studies show the coexistence of tetragonal and pseudocubic perovskite phases on sintering at 950°C, which are attributed to the inhomogeneous distribution of PbTiO₃ arising from mechanical activation. The dielectric behavior can be fine tuned by thermal annealing at 750°C, leading to phase redistribution in PNW-PT.     

新型阳离子紫外光引发剂碘锚盐的光谱表征及分析

采用紫外光谱法(UV)分析新型阳离子光引发剂二甲苯基碘六氟磷酸盐。系统研究了UV法测试条件,采用氯仿重结晶提纯样品、以无水乙醇为溶剂、在λmax=236 nm测吸光度,ε=1.8421×104L.mol-1.cm-1,线性范围为1~80 mg.L-1,加标回收率为99.0%。     

用转矩流变仪测量高分子材料的流变特性

哈尔滨理工大学研制的RM系列橡塑材料转矩流变仪是精选配方优化工艺的有力工具,该机采用先进的计算机测控技术,具有测控精度高,性能稳定,人机界面友好,文件处理功能丰富等特点,是工业企业及科研单位的理想的实验设备。研究了用RM2 0 0型转矩流变仪测量高分子材料PE、PVC的流变特性     

Synthesis,characterization, and thermal properties of phosphorus‐containing,wholly aromatic thermotropic copolyesters

A series of phosphorus‐containing, wholly aromatic thermotropic copolyesters from acetylated 2‐(6‐oxide‐6H‐dibenz〈c,e〉〈1,2〉oxa phosphorin‐6‐yl)‐1,4‐dihydroxy phenylene, p‐acetoxybenzoic acid, terephthalic acid, and isophthalic acid were prepared by melting polycondensation. The structure and basic properties of the polymers, such as the glass‐transition temperature (T_g), melting temperature (T_m), thermal stability, crystallinity, and liquid crystallinity, were investigated with Fourier transform infrared, elemental analysis, differential scanning calorimetry (DSC), thermogravimetric analysis, wide‐angle X‐ray diffraction, and hot‐stage polarizing optical microscopy. The copolyesters had relatively high T_g values ranging from 183 to 192°C. The T_m values obtained from DSC curves for samples P‐20 and P‐25 were 290 and 287°C, respectively (where the number in the sample name indicates the molar fraction of the phosphorus‐containing monomer in the reactants). The initial flow temperatures of other samples observed with hot‐stage polarizing microscopy were 271–290°C. The 5% degradation temperatures in nitrogen ranged from 431 to 462°C, and the char yields at 640°C were 41–52%. All the copolyesters, except P‐40, were thermotropic and nematic. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1278–1284, 2002