贮氢合金表面处理改善吸放氢性能研究

研究表面改性对La系合金贮氢性能的影响,采用化学镀的方法,对LaNi5和LaNi4.7Al0.3合金进行了镀Pd的表面处理实验.在p-C-T测试系统上研究了镀Pd前后,LaNi5和LaNi4.7Al0.3合金的抗CO毒化性能,进行了动力学性能测试、循环次数测试等.实验结果表明,化学镀Pd后的贮氢合金与未镀Pd的合金相比,吸氢性能得到改善,表现为 平台区域相对变平,吸氢孕育期缩短、循环次数增加,抗CO毒化性能提高.     

喷射成形时雾化压力与静压头对雾化熔滴尺寸影响的理论分析

本文建立了静压头、雾化压力与雾化熔滴尺寸的模型关系。雾化压力一定，雾化熔滴质量中值直径随静压头的减小而减小；静压头一定。雾化熔滴尺寸随着雾化压力的增加而减小。通过模型，调节雾化压力以适应静压头变化引起的金属液体质量流率变化，以期得到具有合适尺寸的雾化熔滴，优化沉积坯组织。     

Fe-Si机械合金化过程的研究

采用高能行星球磨的方法研究了原子配比3：1的Fe、Si混合粉末的机械合金化过程。用XRD、TEM、SEM及EPMA对球磨不同时间粉末的结构、组织、形貌、截面进行了分析。结果表明：Fe75Si25混合粉末在球磨的过程中出现两种形态变化，一种是Fe与Si形成层状形态，另一种为Si及Fe—Si合金包覆Fe形成包覆形态；球磨至30h，合金化基本完成；球磨产物为α—Fe（Si）固溶体，颗粒粒径约为1～20μm。利用一个简单的模型来对Fe75Si25混合粉末合金化过程进行了描述。     

Nb-Ti微合金化汽车用钢QStE340～460TM的开发研究

基于对珠钢EAF-CSP流程Nb微合金化技术的系统研究,有效地解决了混晶问题,并利用Nb-Ti复合微合金化技术成功地开发了汽车用钢QStE340～460TM.分析结果表明,开发的含Nb-Ti钢带具有优异的韧性、冷成形性能和良好的焊接性能,完全满足汽车、半挂车用钢的要求.     

时间分解光谱技术在钢铁分析中的应用

研究了单火花光谱在不同采样时间段分析灵敏度与窗口的关系,P、S、Al、Ni、Ti、B、Mg、Sb、Pb、As、Bi、Ta、Sn应用TRS技术检出限明显降低,而C、Si、Mn、Cr、Mo、V、W、Co、Nb则不显著;合适的采样窗口能提高Sb的分析准确度,Mg则可减少背景波动带来的影响,Cu可扩大分析线性范围;采用TRS技术在诸有效元素中分析灵敏度可提高1.36～5.00倍,能更好地满足品种钢的研究开发与生产检验的需求.     

低碳贝氏体钢PC80Q钢工艺探讨

贝氏体结构及其相变机制一直是人们研究的重点。贝氏体钢是为了获得某种物理、化学或力学特性而有意添加了一定量的合金元素Cr、Nb、Mo、Ti、B等元素，并对杂质和有害元素加以控制的特殊性能钢。我厂进行过一炉低碳贝氏体钢PC80Q试制生产，存在的问题主要是该钢的冲击韧性值很低，为此笔者从冶炼、轧制及热处理整个工艺过程中的关键点进行了研究改进，以求使其性能得到提高。     

基于C／S模式的设备综合管理信息系统的开发及应用

根据某汽车零部件公司的需求,研发了基于C/S模式的设备综合管理信息系统。介绍了该系统的组成结构及其特点,分析了各模块的主要功能。试用结果表明,该系统提供统计数据及时、准确,缩短了工作时间,提高了工作效率,降低了成本。     

Hydrothermal preparation and crystal habit of X-zeolite powder

The preparation of X-zeolite powder was investigatedin hydrothermal system, the crystal growth process of X-zeolite in hydrothermal condition was characterized by means of X-ray diffraction, scanning electron microscope and infrared ray. The results show that X-zeolite powder with uniform granularity and intact crystal shape can be obtained in hydrothermal system of acid-treated stellerite-NaOH-NaAl(OH)4-H2O; the crystallite size is in the range of 2 - 3μm. The best reaction time of hydrothermal preparation is 6 h. The formation phases of X-zeolite crystal are as follows: dissolution of feedstocks → formation of [SiO4]4- and [AlO4]5- tetrahedron, many-membered ring,β cage → formation of crystal nucleus and nano-particle → aggregation growth of nano-particle → coalescence growth of crystallite. The crystal habits of X-zeolite are intimately related with crystallization orientation ofβ cage in crystal and with its coupling stability on every crystal face family.     

Dynamic grey model of verification cycle and lifecycle of measuring instrument and its application

Two dynamic grey models DGM (1, 1) for the verification cycle and the lifecycle of measuring instrument based on time sequence and frequency sequence were set up, according to the statistical feature of examination data and weighting method. By a specific case, i. e. vernier caliper, it is proved that the fit precision and forecast precision of the models are much higher, the cycles are obviously different under different working conditions, and the forecast result of the frequency sequence model is better than that of the time sequence model. Combining dynamic grey model and auto-manufacturing case the controlling and information subsystems of verification cycle and the lifecycle based on information integration, multi-sensor controlling and management controlling were given. The models can be used in production process to help enterprise reduce error, cost and flaw. Foundation item: Project (70272032) supported by the National Natural Science Foundation of China     

Preparation, optical properties and cell staining of water soluble amine-terminated PAMAM G 2.0-Au nanocomposites

The solution chemical and optical characteristics of formation of amine-terminated polyamidoamine dendrimer G2.0(NH₂-PAMAM G2.0)-Au nanocomposites in the aqueous solution of NH₂-PAMAM G2.0 at various mole ratios of Au(III) to NH₂-PAMAM G2.0 were studied by both UV-visible spectrometry and fluorospectrometry. The NH₂-PAMAM G2.0-Au nanocomposites, with a type of structure in which one Au nanoparticle is surrounded by several NH₂-PAMAM G2.0 dendrimers, emit strong bluish violet fluorescence, and are uniform, water soluble and biocompatible as well as very stable in frozen conditions. The size of gold nanoparticles in the nanocomposites is about 2.5 nm and decreases with the increase of NH₂-PAMAM G2.0 concentration. The NH₂-PAMAM G2. 0 plays an important role in acting as host or micro-reactor for Au(III) before Au(III) reduction and acting as dispersant and stabilizer for gold nanoparticles after Au(III) reduction. Preliminary experiments of cells staining to human embryonic lung fibroblast cell lines show that the NH₂-PAMAM G2.0-Au nanocomposites can be used as optical imaging markers for bioanalyses and medical diagnoses.