First-principle high-throughput calculations of carrier effective masses of two-dimensional transition metal dichalcogenides

Two-dimensional group-VIB transition metal dichalcogenides (with the formula of MX2) emerge as a family of intensely investigated semiconductors that are promising for both electronic (because of their reasonable carrier mobility) and optoelectronic (because of their direct band gap at monolayer thickness) applications.Effective mass is a crucial physical quantity determining carriers transport,and thus the performance of these applications.Here we present based on first-principles high-throughput calculations a computational study of carrier effective masses of the two-dimensional MX2 materials.Both electron and hole effective masses of different MX2 (M =Mo,W and X =S,Se,Te),including in-layer/out-of-layer components,thickness dependence,and magnitude variation in heterostructures,are systemically calculated.The numerical results,chemical trends,and the insights gained provide useful guidance for understanding the key factors controlling carrier effective masses in the MX2 system and further engineering the mass values to improve device performance.     

Theoretical and Experimental Insight into the Mechanism for Spontaneous Vertical Growth of ReS2 Nanosheets

Rhenium disulfide (ReS₂) differs fundamentally from other group‐VI transition metal dichalcogenides (TMDs) due to its low structural symmetry, which results in its optical and electrical anisotropy. Although vertical growth is observed in some TMDs under special growth conditions, vertical growth in ReS₂ is very different in that it is highly spontaneous and substrate‐independent. In this study, the mechanism that underpins the thermodynamically favorable vertical growth mode of ReS₂ is uncovered. It is found that the governing mechanism for ReS₂ growth involves two distinct stages. In the first stage, ReS₂ grows parallel to the growth substrate, consistent with conventional TMD growth. However, subsequent vertical growth is nucleated at points on the lattice where Re atoms are “pinched” together. At such sites, an additional Re atom binds with the cluster of pinched Re atoms, leaving an under‐coordinated S atom protruding out of the ReS₂ plane. This under‐coordinated S is “reactive” and binds to free Re and S atoms, initiating growth in a direction perpendicular to the ReS₂ surface. The utility of such vertical ReS₂ arrays in applications where high surface‐to‐volume ratio and electric‐field enhancement are essential, such as surface enhanced Raman spectroscopy, field emission, and solar‐based disinfection of bacteria, is demonstrated.     

Hybrid 2D Dual‐Metal–Organic Frameworks for Enhanced Water Oxidation Catalysis

Metal–organic frameworks (MOFs) and MOF‐derived nanostructures are recently emerging as promising catalysts for electrocatalysis applications. Herein, 2D MOFs nanosheets decorated with Fe‐MOF nanoparticles are synthesized and evaluated as the catalysts for water oxidation catalysis in alkaline medium. A dramatic enhancement of the catalytic activity is demonstrated by introduction of electrochemically inert Fe‐MOF nanoparticles onto active 2D MOFs nanosheets. In the case of active Ni‐MOF nanosheets (Ni‐MOF@Fe‐MOF), the overpotential is 265 mV to reach a current density of 10 mA cm^?2 in 1 m KOH, which is lowered by ≈100 mV after hybridization due to the 2D nanosheet morphology and the synergistic effect between Ni active centers and Fe species. Similar performance improvement is also successfully demonstrated in the active NiCo‐MOF nanosheets. More importantly, the real catalytic active species in the hybrid Ni‐MOF@Fe‐MOF catalyst are unraveled. It is found that, NiO nanograins (≈5 nm) are formed in situ during oxygen evolution reaction (OER) process and act as OER active centers as well as building blocks of the porous nanosheet catalysts. These findings provide new insights into understanding MOF‐based catalysts for water oxidation catalysis, and also shed light on designing highly efficient MOF‐derived nanostructures for electrocatalysis.     

Moisture-Induced Reversible Phase Conversion of Cesium Copper Iodine Nanocrystals Enables Advanced Anti-Counterfeiting

Hydrochromic materials have attracted widespread attention in the fields of anti-counterfeiting because of their ability of the reversible light absorption and/or emission properties in response to water. Here, for the first it is demonstrated that the ternary copper halides Cs₃Cu₂I₅ nanocrystals (NCs) possess excellent hydrochromic properties. The prepared Cs₃Cu₂I₅ NCs films can dynamically extract and insert CsI by exposing/removing water to realize the reversible conversion between blue-emissive Cs₃Cu₂I₅ and yellow-emissive CsCu₂I₃. Interestingly, polymethyl methacrylate (PMMA) coated Cs₃Cu₂I₅ can effectively avoid the extraction of CsI and maintain long-term stability in the water. Further, the hydrochromic Cs₃Cu₂I₅ and water-resistant Cs₃Cu₂I₅@PMMA are used as the inks to synergistically act on anti-counterfeiting information to achieve multiple encryption effects, which can clearly identify and authenticate the effective information after moisture decryption. Importantly, the pattern can be re-encrypted to the invalid pattern after water evaporation. In addition, the anti-counterfeiting pattern has excellent stability during repeated encryption/decryption conversion cycles, which can not only balance the accessibility of anti-counterfeiting information but also effectively improve the security of information. This new discovery may not only deepen the understanding of Cs₃Cu₂I₅ but also provide new options for the design of hydrochromic materials for anti-counterfeiting information.     

基于北斗卫星的车载移动站可靠通信链路设计

为建立可靠的车载移动站数据传输系统,设计了一种基于BDS短报文协议的可靠通信链路.针对BDS短报文通信的不可靠性和通信容量有限的缺陷,通过自定义通信协议,采用增强型数据握手机制加强数据传输的可靠性和多卡协同传输数据机制增大数据传输的效率.经实验表明,采用提出的可靠通信链路设计比传统方式的传输成功率平均提高了35％,能提...     

应用型本科高校“信息安全”课程教学改革研究

“信息安全”是计算机科学与技术专业需要学习的一门专业课,文章针对社会信息化需求,结合学校计算机专业的实际情况,主要从教学内容、教学实践、教学模式和考核机制4个方面对“信息安全”课程的教学进行改革。其中教学模式主要融合了CDIO与任务驱动法,旨在提高学生学习兴趣,锻炼学生专业实践能力,促进学生更加透彻地掌握专业知识,全面提高综合能力。     

非理想信道下Colpitts混沌电路的自适应同步研究

本文研究了Colpitts混沌电路在非理想信道条件下的自适应同步问题。引入自适应控制器对输入到响应部分（response system）的衰变混沌信号进行预处理，来补偿衰落信道对于同步性能的影响。给出了系统的数学模型，对恒定信道衰变和时变信道衰变两种非理想信道条件下的混沌ColpiRs电路的自适应同步进行了数值仿真研究。仿真结果表明，对于恒定或慢变化的时变信道衰变，自适应控制器可以有效的提高Colpitts电路响应部分和驱动部分（Drive system）的同步性能。     

SDH传输网络评估优化方法的应用

本文主要介绍中山移动本地传输网网络评估优化的实施过程和采用的一些方法,以及实施本次评估优化的体会和进一步改进的建议.     

基于部分位平面交替偏移的感兴趣区图像编码

提出一种基于部分位平面交替的感兴趣区（ROI）图像编码方式-PBAshift。采用4个策略提高编码效率：1）向上偏移最重要ROI位平面至最大背景（BG）位平面之上,保证最重要ROI位平面得到优先编码;2）将最重要的BG位平面与一般重要ROI位平面交替偏移;3）重要性一般的BG位平面与重要性最差的ROI位平面不偏移;4）向下偏移重要性最差的BG位平面。实验表明,PBAShift不仅支持元需ROI形状信息的单ROI编码,而且支持不同兴趣度下的多ROI编码,对今后医药与遥感图像压缩具有重要意义。     

一种新的弱小目标检测方法

基于对红外图像中目标和背景特性的分析,提出了一种新的基于标记信息和梯度信息相融合的弱小目标检测方法.在红外图像空间,根据目标的特性,利用双重窗进行可能目标的搜索,并进行标记;同时并行的对原始图像进行梯度计算.对标记信息和梯度信息进行融合,进行目标的初次确定.再利用自适应门限对融合后的图像进行目标分割.实验结果证明了该方法能有效的检测出弱小目标.