The morphology and degradation behavior of electrospun poly(3‐hydroxybutyrate)/Magnetite and poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate)/Magnetite composites

Electrospinning of biodegradable poly(3‐hydroxybutyrate) (PHB)/magnetite and poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate) (PHBV)/magnetite composites in 2,2,2‐trifluoroethanol (TFE) and chloroform are investigated to develop nonwoven nanofibrous structure. Ultrafine PHB/magnetite fibers are obtained and the resulting fiber diameters are in the range of 690–710 nm and 8.0–8.4 µm for the polymer dissolved in TFE and chloroform. The surface of PHB composites fiber fabricated in chloroform contains porous structures, which are not observed for the sample of PHB composites fiber dissolved in TFE. The fiber diameters for PHBV5/magnetite composites are in the range of 500–540 nm and 2.3–2.5 µm, depending on the use of TFE and chloroform. The average diameters of PHBV5/magnetite composite fibers are smaller than those of PHB/magnetite composites fiber. All electrospun PHB/magnetite and composite fibers are superparamagnetic. The degradation behaviors of PHB/magnetite and PHBV5/magnetite composite fibers were investigated using Caldimonas manganoxidans. For the fabricated composite fibers, it is found that the degradation rate increased with the increasing loading of magnetite nanoparticles. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41070.     

自平衡井下安全阀动态平衡响应分析

针对现有自平衡井下安全阀的自平衡时间和中心管下移时间匹配与协调的问题,建立自平衡安全阀振动力学模型,确定其输出的响应函数,推导了自平衡式井下安全阀开阀时自平衡响应时间与平衡阀的几何尺寸及位置之间的函数关系。通过实例分析了FVL型井下安全阀开启时的自平衡响应时间,为自平衡井下安全阀分段加压提供了指导,有效地改善了井下安全阀工作可靠性,也为自平衡井下安全阀的结构优化设计提供了参考。     

Site‐specific accumulation and dynamic change of flavonoids in Apocyni Veneti Folium

Site‐specific accumulation of flavonoids in Apocyni Veneti Folium was determined by laser scanning confocal microscope (LSCM) and the localization of catechins also was observed via vanillin‐HCl staining under the conventional optical microscope. The contents of five flavonoids in Apocyni Veneti Folium from different harvest times and growth parts were measured using HPLC method. LSCM observation showed that flavonoids are accumulated in cuticle of epidermal cells and vessel walls, especially in protoplasts and nucleolus of the collenchyma cells and the epidermal cells. Catechins are localized in the palisade parenchyma cells and vessel walls, particularly in the laticifers found in the phloem. On the basis of the difference of the maximal emission wavelength between quercetin and kaempferol derivatives which have fluorescence behavior by appropriate treatment, kaempferol and its derivatives are localized exclusively in the cuticle. Results showed that the content of astragalin in Apocyni Veneti Folium from different parts revealed the decreasing trend, while hyperin and isoquercitrin were higher in June and July analyzed by HPLC. In summary, the site‐specific accumulation of flavonoids in Apocyni Veneti Folium can be determined by LSCM and vanillin‐HCl staining. The contents of flavonoids in Apocyni Veneti Folium are correlated with harvest times and growth parts.     

ABA triblock copolymers from poly(p‐dioxanone) and poly(ethylene glycol)

Poly(p‐dioxanone)–poly(ethylene glycol)–poly(p‐dioxanone) ABA triblock copolymers (PEDO) were synthesized by ring‐opening polymerization from p‐dioxanone using poly(ethylene glycol) (PEG) with different molecular weights as macroinitiators in N₂ atmosphere. The copolymer was characterized by ¹H NMR spectroscope. The thermal behavior, crystallization, and thermal stability of these copolymers were investigated by differential scanning calorimetry and thermogravimetric measurements. The water absorption of these copolymers was also measured. The results indicated that the content and length of PEG chain have a greater effect on the properties of copolymers. This kind of biodegradable copolymer will find a potential application in biomedical materials. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102:1092–1097, 2006     

白光LED用钼酸盐体系红色荧光粉的研究进展

详细介绍目前白光LED用钼酸盐体系红色荧光粉的研究现状,重点介绍近几年来钼酸盐荧光粉在制备合成方面的最新进展,最后展望了LED用钼酸盐红色荧光粉的发展前景.     

外插齿刀变位系数设计与计算程序

变位系数计算是插齿刀设计的重要工作。文章讨论了插齿刀变位系数选取原则以及应当满足不产生齿顶变尖、被切齿轮齿根过渡曲线干涉、根切和顶切等四个约束条件,给出了新刀设计的最大变位系数和根据刃磨到最后刀齿仍有必要强度所允许的最小变位系数计算公式,编制了插齿刀变位系数计算机辅助运算流程,使插齿刀设计简单快速且便于判断设计的可行性。     

管式高速离心机吊轴的安全性分析

在管式离心机受力分析的基础上,建立了管式离心机吊轴的力学计算模型,并对吊轴的弯扭组合下的疲劳与断裂安全性作了分析计算。     

车辆四轮转向控制平台研究

针对机-电-液复合结构的四轮转向平台具有非线性、快时变的特点，提出了模糊自适应PID控制策略。将模糊自适应补偿器与PID控制器并联，提高系统的鲁棒性和抗干扰能力。使用PID控制器稳定系统的线性标称部分，应用模糊自适应补偿器调节PID参数来补偿系统参数摄动、非线性和外界扰动对系统控制性能的影响。仿真和外加扰动实验结果验证了提出的控制策略对四轮转向平台的控制具有快速性、准确性、稳定性和鲁棒性。     

基于VC的连续梁校核CAD系统的开发

以VC为开发工具设计了对钢结构中连续梁进行内力计算校核的CAD系统,该系统能够实现连续梁建立力学模型,应力、内力计算以及内力图的绘制.介绍连续梁进行内力计算的核心算法,给出系统应用实例.